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    • 2. 发明授权
    • Water-absorbing, expanded, crosslinked polymers, the production and use
thereof
    • 吸水膨胀交联聚合物的生产和使用
    • US6136873A
    • 2000-10-24
    • US68023
    • 1998-05-04
    • Hans-Joachim HahnleManfred WalterJurgen TropschGunnar SchornickThomas Anstock
    • Hans-Joachim HahnleManfred WalterJurgen TropschGunnar SchornickThomas Anstock
    • A61L15/00A61L15/42A61L15/60C08F2/16C08F220/06C08J9/30C08L33/02C08J9/28
    • C08F220/06A61L15/425A61L15/60
    • Water-absorbing, expanded, crosslinked polymers obtainable by(I) foaming a polymerizable aqueous mixture which comprises(a) monoethylenically unsaturated monomers which contain acidic groups and are at least 50 mol % neutralized,(b) with or without other monoethylenically unsaturated monomers,(c) crosslinkers,(d) initiators,(e) 0.1-20% by weight of at least one surfactant,(f) with or without at least one solubilizer and(g) with or without thickeners, foam stabilizers, polymerization regulators, fillers and/or cell nucleating agents,where the foaming takes place by dispersing fine bubbles of a gas which is inert to free radicals, and(II) polymerizing the foamed mixture to form an expanded hydrogel and adjusting the water content of the expanded polymer to 1-45% by weight, a process for their production and their use in hygiene articles employed to absorb body fluids and in dressing material for covering wounds.
    • PCT No.PCT / EP96 / 04644 Sec。 371日期:1998年5月4日 102(e)日期1998年5月4日PCT 1996年10月25日PCT公布。 公开号WO97 / 17397 日期1997年5月15日可通过(I)发泡可聚合水性混合物得到的吸水膨胀交联聚合物,其包含(a)含有酸性基团并且至少50摩尔%中和的单烯属不饱和单体,(b)有或没有其它 单烯属不饱和单体,(c)交联剂,(d)引发剂,(e)0.1-20重量%的至少一种表面活性剂,(f)有或没有至少一种增溶剂,和(g)有或没有增稠剂,泡沫稳定剂 ,聚合调节剂,填料和/或细胞成核剂,其中通过分散对自由基惰性的气体的细小气泡进行发泡,和(II)将发泡混合物聚合以形成膨胀的水凝胶并调节水分含量 膨胀聚合物为1-45重量%,其生产方法及其在用于吸收体液的卫生制品中的用途以及用于覆盖伤口的敷料材料。
    • 3. 发明申请
    • Foams made from water-absorbing, basic polymers, method for the production and utilization thereof
    • 由吸水性碱性聚合物制成的泡沫体,其生产和利用方法
    • US20050070616A1
    • 2005-03-31
    • US10502212
    • 2003-01-30
    • Samantha ChampHans-Joachim HahnleMartin BeckRudiger Funk
    • Samantha ChampHans-Joachim HahnleMartin BeckRudiger Funk
    • A61F13/53A61F13/00A61F13/15A61F13/49A61L15/00C08J9/12C08J9/28C08J9/30C08K3/00C08K5/00C08L101/14C08J9/00
    • C08J9/30C08J9/286C08J2201/0504C08J2205/022C08J2300/14
    • Foams composed of water-absorbing basic polymers, obtainable by (I) foaming a crosslinkable aqueous mixture including (a) at least one basic polymer whose basic groups have optionally been neutralized, (b) at least one crosslinker, (c) at least one surfactant, (d) optionally at least one solubilizer, (e) optionally thickeners, foam stabilizers, fillers, fibers and/or cell nucleators, and (f) optionally particulate water-absorbing acidic polymers, by dissolving a gas which is inert toward free radicals in the crosslinkable aqueous mixture under a pressure from 2 to 400 bar and subsequently decompressing the crosslinkable aqueous mixture to atmospheric or by dispersing fine bubbles of a gas which is inert toward free radicals, and (II) crosslinking the foamed mixture to form a hydrogel foam and if applicable adjusting the water content of the polymer foam to 1-60% by weight. Preparation of the foams by application of the abovementioned measures (I) and (II) and use of the thus obtainable foams in hygiene articles to absorb body fluids, in dressing material to cover wounds, as a sealing material, as a packaging material, as a soil improver, as a soil substitute, to dewater sludges, to absorb aqueous acidic wastes, to thicken waterborne paints or coatings in the course of disposing of residual quantities thereof, to dewater water-containing oils or hydrocarbons or as a material for filters in ventilation systems.
    • 由吸水性碱性聚合物组成的泡沫体可通过(I)发泡可交联水性混合物得到,所述可交联水性混合物包括(a)至少一种碱性基团任选被中和的碱性聚合物,(b)至少一种交联剂,(c)至少一种 表面活性剂,(d)任选的至少一种增溶剂,(e)任选的增稠剂,泡沫稳定剂,填料,纤维和/或细胞成核剂,和(f)任选的颗粒状吸水性酸性聚合物, 在2至400巴的压力下在可交联水性混合物中的基团,随后将可交联的含水混合物减压至大气或通过分散对自由基呈惰性的气体的细小气泡,和(II)将发泡混合物交联以形成水凝胶 泡沫,如果适用,将聚合物泡沫的含水量调节至1-60重量%。 通过应用上述措施(I)和(II)制备泡沫体,并将如此获得的泡沫在卫生制品中的使用以吸收体液,在敷料中覆盖伤口作为密封材料作为包装材料,如 土壤改良剂,作为土壤替代物,去除污泥,吸收含水酸性废物,在处理剩余量的过程中加厚水性涂料或涂料,将含水油或碳氢化合物或用作过滤器的材料脱水 通风系统。