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    • 3. 发明授权
    • Upgrading oil emulsions with carbon monoxide or synthesis gas
    • 用一氧化碳或合成气升级油乳液
    • US5104516A
    • 1992-04-14
    • US578262
    • 1990-09-06
    • Theo J. W. de BruijnH. John Woods
    • Theo J. W. de BruijnH. John Woods
    • C10G9/00
    • C10G9/007
    • Several procedures are provided herein which reduce the viscosity and density of heavy oils to make them amenable for transportation by pipeline from the field to refineries for further processing. The procedure involves contacting a water emulsion of a heavy oil with carbon monoxide at a pressure range and a temperature range such that a water gas shift reaction takes place to convert the steam and carbon monoxide to hydrogen and carbon dioxide. Simultaneously, a thermal rearrangement takes place, thereby reducing the viscosity and density of the oil without any significant thermal cracking. Under one scheme, at a low temperature range, e.g. below about 400.degree. C., there is substantailly no cracking and minimal molecular changes. Under another scheme, at a higher temperature range, e.g. up to about 460.degree. C., significant cracking and molecular changes take place. Nevertheless under both schemes there is a net production of hydrogen and carbon dioxide, and both hydrogen and carbon dioxide are separated, and may be used in other processes.
    • 本文提供了若干程序,其降低了重油的粘度和密度,使得它们适合于从现场管道输送到炼油厂进行进一步加工。 该方法包括在压力范围和温度范围内使重油的水乳液与一氧化碳接触,从而进行水煤气变换反应,以将蒸汽和一氧化碳转化为氢气和二氧化碳。 同时,发生热重排,从而降低油的粘度和密度,而没有任何明显的热裂纹。 在一个方案下,在低温范围,例如 低于约400℃,没有破裂和分子变化最小。 在另一种方案中,在较高的温度范围,例如 高达约460℃,发生明显的裂解和分子变化。 然而,在这两种方案下,都有净生产氢和二氧化碳,氢气和二氧化碳都被分离,可用于其他工艺。