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1. 发明授权

US4931271A Cosmetic compostions based upon N-hydroxybutyl-chitosans, N-hydroxybutyl-chitosans as well as processes for the production thereof 失效
标题翻译：基于N-羟基丁基壳聚糖，N-羟基丁基 - 壳聚糖的化妆品组合物及其制备方法
公开(公告)号：US4931271A
公开(公告)日：1990-06-05
申请号：US134779
申请日：1987-12-18
申请人： Gunther Lang , Eugen Konrad , Harald Wendel , Gerhard Maresch , Hans-Rudi Lenz
发明人： Gunther Lang , Eugen Konrad , Harald Wendel , Gerhard Maresch , Hans-Rudi Lenz
IPC分类号： A61K8/00 , A61K8/04 , A61K8/34 , A61K8/72 , A61K8/73 , A61K31/715 , A61P17/00 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/10 , A61Q17/04 , A61Q19/00 , A61Q19/10 , C08B1/00 , C08B37/08
CPC分类号： A61Q19/00 , A61K8/736 , A61Q5/12 , C08B37/003 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/065 , A61Q5/10 , Y02W10/37
摘要： The invention is directed to cosmetic compositions for the treatment of hair or skin characterized in that they contain new N-hydroxybutyl-chitosans, or their salts, consisting of(a) 4 to 40 mole percent monomer units of the formula (I) ##STR1## and (b) 60 to 96 mole percent monomer units of the formula (II) ##STR2## wherein R.sup.1 and R.sup.2 are identical or different and designate hydrogen or the group ##STR3## with n being equal to an integer from 1 to 5, provided that R.sup.1 and R.sup.2 are not simultaneously hydrogen in at least 50 percent of the units of formula (II). In addition, it is directed to new N-hydroxybutyl-chitosans and their salts and a process for producing these new compounds from butylene oxide and chitosan.
摘要翻译： PCT No.PCT / EP87 / 00207 Sec。 371日期：1987年11月18日 102（e）1987年11月18日PCT PCT 1987年4月16日PCT公布。公开号WO87 / 06461 日本公开1987年11月5日。本发明涉及用于治疗毛发或皮肤的化妆品组合物，其特征在于它们含有新的N-羟基丁基壳聚糖或其盐，其由（a）4至40摩尔％的单体单元式（I）（I）和（b）60至96摩尔％的式（II）的单体单元其中R 1和R 2相同或不同，并且表示氢或基团

2. 发明授权

US4923977A Cosmetic composition based upon N-hydroxypropylisopropylether chitosans as well as new N-hydroxypropylisopropylether derivatives of chitosan 失效
标题翻译：基于N-羟丙基异丙基醚壳聚糖的化妆品组合物以及壳聚糖的新型N-羟基乙基异丙基醚衍生物
公开(公告)号：US4923977A
公开(公告)日：1990-05-08
申请号：US228928
申请日：1988-07-29
申请人： Gunther Lang , Gerhard Maresch , Hans-Rudi Lenz
发明人： Gunther Lang , Gerhard Maresch , Hans-Rudi Lenz
IPC分类号： A61K8/73 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/10 , A61Q19/00 , C08B37/08
CPC分类号： A61Q19/00 , A61K8/736 , A61Q5/00 , A61Q5/02 , A61Q5/06 , A61Q5/065 , C08B37/003 , A61Q5/006 , A61Q5/04 , A61Q5/10 , Y02W10/37 , Y10S514/846 , Y10S514/881
摘要： The present invention relates to a cosmetic for the treatment of hair and skin which is characterized by a content of novel N-hydroxy-propyl-isopropyl ether chitosans consisting of (a) 4 to 40 mole percent of monomer units having the formula (I) ##STR1## and (b) 60 to 96 mole percent of monomer units having the formula (II) ##STR2## wherein R.sup.1 and R.sup.2 are identical or different and represent hydrogen or the group ##STR3## wherein n equals 1 or 2, with the condition that in at least half the units having the formula (II) R.sup.1 and R.sup.2 do not simultaneously represent hydrogen. The present invention also relates to novel N-hydroxy-propyl-isopropyl ether chitosans.
摘要翻译： PCT No.PCT / EP87 / 00774 371日期：1988年7月29日第 102（e）日期1988年7月29日PCT Filted 1987年12月12日PCT公布。公开号WO88 / 05790 日本1988年8月11日。本发明涉及一种用于治疗毛发和皮肤的化妆品，其特征在于由（a）4〜40摩尔％的单体组成的新型N-羟基 - 丙基 - 异丙基醚壳聚糖的含量具有式（I）的单元（I）和（b）60至96摩尔％的具有式（II）的单体单元（II）其中R 1和R 2相同或不同并且表示氢或其中n等于1或2，条件是在至少一半具有式（II）的单元R1和R2不同时表示氢的条件下。本发明还涉及新型的N-羟基 - 丙基 - 异丙基醚壳聚糖。

3. 发明授权

US4954619A O-benzyl-N-hydroxyalkyl derivatives of chitosan and nail polish containing the same 失效
标题翻译：壳聚糖的O-苄基-N-羟烷基衍生物和含有它的指甲油
公开(公告)号：US4954619A
公开(公告)日：1990-09-04
申请号：US217763
申请日：1988-07-11
申请人： Gunther Lang , Gerhard Maresch , Hans-Rudi Lenz
发明人： Gunther Lang , Gerhard Maresch , Hans-Rudi Lenz
IPC分类号： A61K8/00 , A61K8/72 , A61K8/73 , A61K8/96 , A61Q3/02 , C08B37/08
CPC分类号： C08B37/003 , A61K8/736 , A61Q3/02
摘要： Nail polish is disclosed, based upon a film-former, a resin component and a solvent system, containing as film-former and/or resin component an O-benzyl-N-hydroxyalkyl chitosan fo the formula (I)HO[C.sub.6 H.sub.11-m-q NO.sub.4 (R.sup.1).sub.m (R.sup.2).sub.n (R.sup.3).sub.q ].sub.p H (I)(with m=0 to 0.6; n=0.1 to 10; q=0.1 to 4; p=an integer from 50 to 5,000; R.sup.1 =acetyl; R.sup.2 =hydroxyethyl, 2-hydroxypropyl or 2-hydroxybutyl and R.sup.3 =benzyl).The polish film obtained with the nail polish possesses a high luster, outstanding adhesion, as well as an increased hardness compared to nail polishes based upon nitro-cellulose, with even more sufficient elasticity. Also included in the present invention are the new O-benzyl-N-hydroxyalkyl-chitosans of formula (I).
摘要翻译：公开了基于成膜剂，树脂组分和溶剂体系的指甲油，其包含作为成膜剂和/或树脂组分的式（I）的HO- [C 6 H 11 -m]的O-苄基-N-羟烷基壳聚糖 -qNO4（R1）m（R2）n（R3）q] pH（I）（m = 0至0.6; n = 0.1至10; q = 0.1至4; p = 50至5,000的整数; R1 = 乙酰基; R 2 =羟乙基，2-羟丙基或2-羟基丁基，R 3 =苄基）。用指甲油获得的抛光膜与基于硝基纤维素的指甲油相比，具有高光泽，优异的粘附性以及增加的硬度，具有更充分的弹性。本发明还包括新的式（I）的O-苄基-N-羟基烷基 - 壳聚糖。

4. 发明授权

US4845204A Cosmetic compositions on the basis of alkyl-hydroxypropyl-substituted chitosan derivatives, new chitosan derivatives and processes for the production thereof 失效
标题翻译：基于烷基 - 羟丙基取代的壳聚糖衍生物的化妆品组合物，新的壳聚糖衍生物及其制备方法
公开(公告)号：US4845204A
公开(公告)日：1989-07-04
申请号：US946576
申请日：1986-10-03
申请人： Gunther Lang , Gerhard Maresch , Hans-Rudi Lenz , Eugen Konrad , Lothar Breuer , Dietrich Hoch
发明人： Gunther Lang , Gerhard Maresch , Hans-Rudi Lenz , Eugen Konrad , Lothar Breuer , Dietrich Hoch
IPC分类号： A61K8/00 , A61K8/34 , A61K8/73 , A61K8/96 , A61Q5/00 , A61Q5/06 , A61Q5/10 , A61Q19/00 , C08B1/00 , C08B37/08
CPC分类号： A61K8/736 , A61Q5/06 , C08B37/003 , Y10S424/01 , Y10S424/02 , Y10S514/844
摘要： New alkyl-hydroxypropyl-chitosans of the formula IHO[C.sub.6 H.sub.11-m-q NO.sub.4 (R.sup.1).sub.m (R.sup.2).sub.n (R.sup.3).sub.q ].sub.p H (I)(m=0-0.6; n=0.5-10; q=0.5-4; p=50-5000; R.sup.1 =acetyl; ##STR1## R.sup.3 =C.sub.1 -C.sub.6 -alkyl) and their salts with organic or inorganic acids. The invention is directed, in addition, to a process for producing the chitosan derivatives of the formula I, as well as cosmetic compositions for the treatment of hair or skin, particularly compositions for strengthening hair, comprising a content of these chitosan derivatives. The described alkyl-hydroxypropyl-chitosans are distinguished by their favorable solubility in organic solvents. Therefore, they can also be used, for example, in anhydrous hairsprays.
摘要翻译： PCT No.PCT / EP86 / 00041 Sec。 371日期1986年10月3日第 102（e）日期1986年10月3日PCT 1985年1月30日PCT PCT。出版物WO86 / 04590 日期：1986年8月14日。式I HO [C6H11-m-qNO4（R1）m（R2）n（R3）q] pH（I）（m = 0-0.6; n = 0.5-10; q = 0.5-4; p = 50-5000; R1 =乙酰基; R3 = C1-C6-烷基）及其与有机或无机酸的盐。本发明还涉及制备式I的壳聚糖衍生物的方法，以及用于治疗毛发或皮肤的化妆品组合物，特别是用于加强头发的组合物，其包含这些壳聚糖衍生物的含量。所描述的烷基 - 羟丙基 - 壳聚糖通过其在有机溶剂中的良好溶解度来区分。因此，它们也可以用于例如无水发胶中。

5. 发明授权

US4835266A Cosmetic compositions based upon n-hydroxypropyl-chitosans, new n-hydroxypropyl-chitosans, as well as processes for the production thereof 失效
标题翻译：基于n-羟丙基 - 壳聚糖，新的n-羟丙基 - 壳聚糖的化妆品组合物，以及其生产方法
公开(公告)号：US4835266A
公开(公告)日：1989-05-30
申请号：US185868
申请日：1988-04-22
申请人： Gunther Lang , Gerhard Maresch , Harald Wendel , Eugen Konrad , Hans-Rudi Lenz , Jurgen Titze
发明人： Gunther Lang , Gerhard Maresch , Harald Wendel , Eugen Konrad , Hans-Rudi Lenz , Jurgen Titze
IPC分类号： A61K8/73 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/10 , A61Q19/00 , C08B37/08
CPC分类号： A61Q5/02 , A61K8/736 , A61Q19/00 , A61Q5/00 , A61Q5/06 , A61Q5/065 , A61Q5/12 , C08B37/003 , A61Q5/04 , A61Q5/10 , Y10S514/847
摘要： Cosmetic compositions are disclosed, for the treatment of skin or hair, with a content of new N-hydroxypropyl-chitosan derivatives, composed of (a) 4 to 40 Mol-% units of Formula (I) ##STR1## and (b) 60 to 96 Mol-% units of Formula (II) ##STR2## wherein R.sup.1 and R.sup.2 are the same or different and are each hydrogen or the group ##STR3## with n being equal to an integer from 1 to 5, with the proviso that in at least 50% of the units (II), R.sup.1 and R.sup.2 are not simultaneously hydrogen, or the salts thereof; along with new N-hydroxypropyl-chitosan derivatives and their salts as well a a process for the production of these new compounds from propylene oxide and chitosan.
摘要翻译：公开了用于治疗皮肤或毛发的化妆品组合物，其含有新的N-羟丙基 - 壳聚糖衍生物，其由（a）4-40摩尔％的式（I）单元组成（I）和（ b）60至96摩尔％的式（II）单元其中R 1和R 2相同或不同，各自为氢或基团，其中n等于1至5的整数。条件是在至少50％的单元（II）中，R 1和R 2不同时为氢，或其盐; 以及新的N-羟丙基 - 壳聚糖衍生物及其盐，以及由环氧丙烷和壳聚糖生产这些新化合物的方法。

6. 发明授权

US4780310A Cosmetic compositions based upon N-hydroxypropyl-chitosans, new N-hyroxypropyl-chitosans, as well as processes for the production thereof 失效
标题翻译：基于N-羟丙基 - 壳聚糖的新型N-羟丙基 - 壳聚糖的化妆品组合物及其制备方法
公开(公告)号：US4780310A
公开(公告)日：1988-10-25
申请号：US933793
申请日：1986-11-21
申请人： Guther Lang , Gerhard Maresch , Harald Wendel , Eugen Konrad , Hans-Rudi Lenz , Jurgen Titze
发明人： Guther Lang , Gerhard Maresch , Harald Wendel , Eugen Konrad , Hans-Rudi Lenz , Jurgen Titze
IPC分类号： A61K8/73 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/10 , A61Q19/00 , C08B37/08 , A61K7/06 , A61K7/08 , A61K7/13
CPC分类号： A61Q5/02 , A61K8/736 , A61Q19/00 , A61Q5/00 , A61Q5/06 , A61Q5/065 , A61Q5/12 , C08B37/003 , A61Q5/04 , A61Q5/10 , Y10S514/847
摘要： Cosmetic compositions are disclosed, for the treatment of skin or hair, with a content of new N-hydroxypropyl-chitosan derivatives, composed of (a) 4 to 40 Mol-% units of Formula (I) ##STR1## and (b) 60 to 96 Mol-% units of Formula (II) ##STR2## wherein R.sup.1 and R.sup.2 are the same or different and are each hydrogen or the group ##STR3## with n being equal to an integer from 1 to 5, with the proviso that in at least 50% of the units of (II), R.sup.1 and R.sup.2 are not simultaneously hydrogen, or the salts thereof; along with new N-hydroxypropyl-chitosan derivatives and their salts as well as a process for the production of these new compounds from propylene oxide and chitosan.
摘要翻译：公开了用于治疗皮肤或毛发的化妆品组合物，其含有新的N-羟丙基 - 壳聚糖衍生物，其由（a）4-40摩尔％的式（I）单元组成（I）和（ b）60至96摩尔％的式（II）单元其中R 1和R 2相同或不同，各自为氢或基团，其中n等于1至5的整数。条件是在（II），R1和R2的至少50％的单元不是氢的情况下，或其盐; 以及新的N-羟丙基 - 壳聚糖衍生物及其盐，以及由环氧丙烷和壳聚糖生产这些新化合物的方法。

7. 发明授权

US5635170A Composition and method for permanent shaping of hair 失效
标题翻译：头发永久成型的组成和方法
公开(公告)号：US5635170A
公开(公告)日：1997-06-03
申请号：US552576
申请日：1995-11-03
申请人： Gunther Lang , Gerhard Maresch
发明人： Gunther Lang , Gerhard Maresch
IPC分类号： A61K8/00 , A61K8/42 , A61K8/44 , A61K8/64 , A61Q5/04 , A61K7/09
CPC分类号： A61Q5/04 , A61K8/64
摘要： The composition for permanent shaping of hair based on a hair keratin-reducing agent contains N-glycyl-L-cysteine and/or L-cysteinyl-glycine as the hair keratin-reducing agent. The N-glycyl-L-cysteine and/or L-cysteinyl-glycine is advantageously the only hair keratin-reducing substance present. The compositions have a preferred pH range of 6.5 to 9.0 and contain from 8 to 30 percent by weight of the N-glycyl-L-cysteine and/or L-cysteinyl-glycine. Use of this composition for permanent shaping of hair avoids a troublesome white deposit or coating on the hair which occurs when cysteine-containing hair shaping compositions are used.
摘要翻译：基于毛发角蛋白还原剂的头发永久成形用组合物含有作为头发角蛋白减少剂的N-甘氨酰-L-半胱氨酸和/或L-半胱氨酰 - 甘氨酸。 N-甘氨酰-L-半胱氨酸和/或L-半胱氨酰 - 甘氨酸有利地是唯一存在的毛发角蛋白减少物质。组合物的优选pH范围为6.5〜9.0，含有8〜30重量％的N-甘氨酰-L-半胱氨酸和/或L-半胱氨酰 - 甘氨酸。使用这种组合物来永久塑造头发避免了当使用含半胱氨酸的头发成型组合物时发生的毛发上的麻烦的白色沉积物或涂层。

8. 发明授权

US5637295A Methods and compositions for permanent shaping of hair 失效
标题翻译：头发永久成型的方法和组合物
公开(公告)号：US5637295A
公开(公告)日：1997-06-10
申请号：US559375
申请日：1995-11-16
申请人： Guenther Lang , Kirstin Uhl , Gerhard Sendelbach , Gerhard Maresch
发明人： Guenther Lang , Kirstin Uhl , Gerhard Sendelbach , Gerhard Maresch
IPC分类号： A61K8/895 , A61K8/898 , A61Q5/04 , A61K7/09
CPC分类号： A61Q5/04 , A61K8/898
摘要： The permanent shaping composition for permanent shaping of hair includes from 2 to 25 percent by weight of a conventional keratin-reducing compound and from 0.02 to 5 percent by weight of certain diquaternary polysiloxanes. The permanent wave-pretreatment composition includes from 0.02 to 5 percent by weight of the diquaternary polysiloxanes. The permanent shaping composition advantageously includes mercaptocarbonic acid reducing agents and has a pH of from 6 to 10 and may include conventional cosmetic additives. Methods for using the permanent shaping composition and the permanent wave-pretreatment composition are described which provide a more uniform permanant wave from the hair roots to the hair tips.
摘要翻译：用于永久成型头发的永久性成形组合物包含2至25重量％的常规角蛋白减少化合物和0.02至5重量％的某些二季聚硅氧烷。永久波浪预处理组合物包含0.02至5重量％的二季聚硅氧烷。永久性成形组合物有利地包括巯基碳酸还原剂，并且pH为6至10，并且可以包括常规的化妆品添加剂。描述了使用永久成形组合物和永久性波浪预处理组合物的方法，其提供从发根到毛发尖端的更均匀的永久波。

9. 发明授权

US5503826A Hair keratin-reducing mono, di- and triglycerides of cysteine and compositions 失效
标题翻译：头发角蛋白降低的半胱氨酸和组合物的单，二和甘油三酯
公开(公告)号：US5503826A
公开(公告)日：1996-04-02
申请号：US330363
申请日：1994-10-27
申请人： Guenther Lang , Hans-Juergen Braun , Gerhard Maresch
发明人： Guenther Lang , Hans-Juergen Braun , Gerhard Maresch
IPC分类号： A61K8/00 , A61K8/44 , A61Q5/04 , C07C323/58 , A61K7/09 , A61K7/06
CPC分类号： A61Q5/04 , A61K8/447 , C07C323/58
摘要： The new keratin-reducing substances useful in compositions for permanent shaping of hair are glyceryl esters of cysteine, especially the monoglyceryl esters. As monoglyceryl esters of cysteine 2-amino-3-mercaptopropionic acid-(2',3'-dihydroxypropyl)ester and 2-amino-3-mercaptopropionic acid-(1',3'-dihydroxyisopropyl)ester are particularly preferred. A preferred embodiment of the compositions for permanent shaping of hair consists of a ready-to-use mixture of a water-free component including at least one glyceryl ester of cysteine and at least one other component which is kept physically separately from the water-free component until the mixture is prepared. The compositions also can include other conventional ingredients normally used in permanent shaping compositions such as surfactants and thickeners. The compositions have a preferred pH range of 6.0 to 8.5 and contain from 8 to 28 percent by weight of the glyceryl esters of cysteine.
摘要翻译：用于头发永久成型的组合物中的新的角蛋白还原物质是半胱氨酸的甘油酯，特别是单甘油酯。作为半胱氨酸2-甘氨酸酯，2-氨基-3-巯基丙酸 - （2'，3'-二羟基丙基）酯和2-氨基-3-巯基丙酸 - （1'，3'-二羟基异丙基）酯是特别优选的。用于永久成型头发的组合物的优选实施方案是由包含至少一种半胱氨酸甘油酯和至少一种其它成分的无水组分的即用混合物组成的物质与水分离物质分开组分直到制备混合物。组合物还可以包括通常用于永久成型组合物如表面活性剂和增稠剂的其它常规成分。组合物具有6.0至8.5的优选pH范围并且含有8至28重量％的半胱氨酸的甘油酯。

10. 发明授权

US06506501B1 Foil for wrapping hair ends 失效
标题翻译：用于包裹头发的箔
公开(公告)号：US06506501B1
公开(公告)日：2003-01-14
申请号：US09355656
申请日：2001-09-27
申请人： Dieter Schonert , Gerhard Maresch , Gernot Mecks
发明人： Dieter Schonert , Gerhard Maresch , Gernot Mecks
IPC分类号： B32B2900
CPC分类号： A61K8/362 , A61K8/0208 , A61K8/31 , A61K8/36 , A61K8/365 , A61K8/39 , A61K8/86 , A61K8/922 , A61Q5/04 , Y10T428/1303 , Y10T428/31971 , Y10T428/31986 , Y10T428/31993
摘要： The permanent shaping method avoids overcurling of hair tips. Prior to performing the permanent shaping of the hair, the hair tips are protected by wrapping the hair tips with an impregnated foil and then performing the permanent shaping of the hair. The foil is an impregnated hair-tip paper that has been treated with an aqueous preparation that provides superior permanent shaping results. This aqueous preparation contains water, from 20 to 70 percent by weight of at least one lipophilic substance; from 1 to 25 percent by weight of at least one emulsifier and from 0.5 to 15 percent by weight of at least one organic acid. An impregnated foil made from silk or rice paper is also described.
摘要翻译：永久性成形方法避免头发过度发生。在进行头发的永久成形之前，通过用浸渍的箔包裹毛发头部然后进行头发的永久成形来保护头发尖端。箔是经浸渍的头发纸，其已经用提供优异的永久成形结果的水性制剂处理。该水性制剂含有20-70％重量的至少一种亲脂性物质的水; 1至25重量％的至少一种乳化剂和0.5至15重量％的至少一种有机酸。还描述了由丝绸或米纸制成的浸渍箔。

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