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1. 发明授权

US5977254A Molding material 失效
标题翻译：成型材料
公开(公告)号：US5977254A
公开(公告)日：1999-11-02
申请号：US833462
申请日：1997-04-07
申请人： Graham Edmund Mc Kee , Norbert Niessner , Herbert Fisch
发明人： Graham Edmund Mc Kee , Norbert Niessner , Herbert Fisch
IPC分类号： C08K7/04 , C08K7/00 , C08L51/04 , C08L55/00 , C08L55/02 , C08L59/00 , C08L67/02 , C08L71/02 , C08L75/00 , C08L75/04 , C08L75/06 , C08L77/00 , C08L101/00 , C08L61/02
CPC分类号： C08L59/00 , C08L51/04 , C08L67/02 , C08L71/02 , C08L75/04 , C08L77/00 , C08L75/06
摘要： A molding material contains, based on the sum of the components A and B, and, if required, C, D and/or E,A: 1-99% by weight of a particulate microemulsion polymer having a glass transition temperature below 0.degree. C. and a median particle size of less than 50 nm,B: 1-99% by weight of a semicrystalline polymer B, in particular selected from at least one polymer from semicrystalline polyamides, partly aromatic copolyamides, polyolefins, ionomers, polyesters, polyetherketones, polyoxyalkylenes and polyarylene sulfides,C: 0-50% by weight of a polymer selected from a particulate graft copolymer having a median particle size of from 60 to 10,000 nm, a thermoplastic polyurethane, a thermoplastic elastomer and an acrylate, diene, EP, EPDM or silicone rubber,D: 0-50% by weight of polycarbonates andE: 0-50% by weight of fibrous or particulate fillers or of a mixture thereof.
摘要翻译：成型材料基于组分A和B的总和，并且如果需要，包含C，D和/或E，A：1-99重量％的玻璃化转变温度低于0℃的微粒微乳液聚合物 C，中值粒径小于50nm，B：1-99重量％的半结晶聚合物B，特别是选自至少一种来自半结晶聚酰胺的聚合物，部分芳族共聚酰胺，聚烯烃，离聚物，聚酯，聚醚酮聚氧亚烷基和聚亚芳基硫醚，C：0-50重量％的选自中值粒径为60至10,000nm的颗粒接枝共聚物的聚合物，热塑性聚氨酯，热塑性弹性体和丙烯酸酯，二烯，EP， EPDM或硅橡胶，D：0-50重量％的聚碳酸酯和E：0-50重量％的纤维或颗粒填料或其混合物。

2. 发明授权

US06566436B1 Molded forms for use in gardening and animal husbandry 失效
标题翻译：用于园艺和畜牧业的成型形式
公开(公告)号：US06566436B1
公开(公告)日：2003-05-20
申请号：US09806863
申请日：2001-04-05
申请人： Norbert Güntherberg , Heiner Görrissen , Graham Edmund Mc Kee , Norbert Niessner , Martin Weber
发明人： Norbert Güntherberg , Heiner Görrissen , Graham Edmund Mc Kee , Norbert Niessner , Martin Weber
IPC分类号： C08L500
CPC分类号： C08L23/16 , C08L25/12 , C08L33/02 , C08L51/00 , C08L69/00 , C08L2666/04
摘要： The use of a thermoplastic molding composition which is not ABS, comprising, based on the total of the amounts of components A, B, C, and, where appropriate, D, this total being 100% by weight, a: as component A, from 1 to 48% by weight of at least one particulate emulsion polymer which has one or more phases and has a glass transition temperature below 0° C. in at least one phase, and has a median particle size from 50 to 1000 nm, b: as component B, from 1 to 48% by weight of at least one amorphous or semicrystalline polymer, c: as component C, from 51 to 90% by weight of polycarbonates, and d: as component D, from 0 to 47% by weight of conventional addictives and/or fibrous or particulate fillers, or a mixture of these, for producing moldings, or corresponding semifinished products, for the garden sector or animal-keeping sector.
摘要翻译：使用不是ABS的热塑性模塑组合物，其包含基于组分A，B，C的总量，并且在合适的情况下，D总计为100重量％，a：作为组分A， 1至48重量％的至少一种具有一个或多个相的至少一种微粒乳液聚合物，并且在至少一个相中具有低于0℃的玻璃化转变温度，并且中值粒度为50-1000nm，b ：作为组分B，1至48重量％的至少一种无定形或半结晶聚合物，c：作为组分C，51至90重量％的聚碳酸酯，和d：作为组分D，0至47重量％的常规上瘾剂和/或纤维或颗粒填料，或它们的混合物，用于生产模制品或相应的半成品，用于花园部门或动物饲养部门。

3. 发明授权

US06420483B1 Preparation of impact-modified plastics 失效
标题翻译：冲击改性塑料的制备
公开(公告)号：US06420483B1
公开(公告)日：2002-07-16
申请号：US09685742
申请日：2000-10-11
申请人： Graham Edmund Mc Kee , Hermann Gausepohl , Norbert Niessner , Norbert Güntherberg
发明人： Graham Edmund Mc Kee , Hermann Gausepohl , Norbert Niessner , Norbert Güntherberg
IPC分类号： C08F8100
CPC分类号： C08L55/02 , C08F279/02 , C08F279/04 , C08L2666/14 , C08L2666/02
摘要： The invention relates to a process for preparing an impact-modified plastic, where particles of a crosslinked rubber are produced from a first monomer mixture which has at least 50% by weight of conjugated diene compounds, the rubber particles are added to a second monomer mixture which has at least 85% by weight, preferably at least 90% by weight, in particular at least 98% by weight, of styrene, and the monomers of the second monomer mixture are polymerized. This process can prepare novel and improved impact-modified plastics. Novel impact-modified plastics are also described.
摘要翻译：本发明涉及一种制备冲击改性塑料的方法，其中交联橡胶的颗粒由具有至少50重量％的共轭二烯化合物的第一单体混合物制备，将橡胶颗粒加入到第二单体混合物中，具有至少85重量％，优选至少90重量％，特别是至少98重量％的苯乙烯，并且第二单体混合物的单体被聚合。该方法可以制备新的和改进的冲击改性塑料。还描述了新的冲击改性塑料。

4. 发明授权

US06835775B2 Thermoplastic molding compounds with improved impact resistance 有权
标题翻译：具有改善耐冲击性的热塑性模塑料
公开(公告)号：US06835775B2
公开(公告)日：2004-12-28
申请号：US10275012
申请日：2002-10-31
申请人： Michael Breulmann , Sabine Oepen , Norbert Niessner , Norbert Güntherberg , Wil Duijzings , Graham Edmund Mc Kee , Peter Rossmanith
发明人： Michael Breulmann , Sabine Oepen , Norbert Niessner , Norbert Güntherberg , Wil Duijzings , Graham Edmund Mc Kee , Peter Rossmanith
IPC分类号： C08F25500
CPC分类号： C08L25/12 , C08F265/04 , C08F279/02 , C08F279/04 , C08F291/02 , C08L51/04 , C08L55/02 , C08F2/22 , C08L2666/24 , C08L2666/02
摘要： The graft copolymer made from a1: from 10 to 90% by weight of a particulate graft base A1, made from a particulate emulsion polymer with a glass transition temperature below 0° C. made from a11: from 70 to 100% by weight of butadiene or of at least one C1-8-alkyl acrylate, or of mixtures of these, as component A11, a12: from 0 to 20% by weight of at least one polyfunctional crosslinking monomer, as component A12, a13: from 0 to 30% by weight of other copolymerizable monomers, as component A13, the total amount of these being 100% by weight, a2: from 10 to 90% by weight of a graft A2 made from the following monomers, the amounts being based on A2, a21: from 60 to 100% by weight of at least one vinylaromatic monomer, or of a (meth)acrylic ester or of mixtures of these, as component A21, and a22: from 0 to 40% by weight of at least one ethylenically unsaturated monomer, as component A22, has a median particle diameter of from 130 to 500 nm and has polymodal particle size distribution in which less than 40% by weight of the particles are present in any particle size range of width 50 nm.
摘要翻译：由a1制得的接枝共聚物：10至90重量％的微粒接枝基质A1，其由玻璃化转变温度低于0℃的颗粒状乳液聚合物制成，由11：70至100重量％的丁二烯或至少一种丙烯酸C 1-8 - 或它们的混合物，作为组分A11，a12：0-20重量％的至少一种多官能交联单体，作为组分A12，a13：0-30重量％的其它可共聚单体作为组分A13，其总量为100重量％，a2：10至90重量％的由以下单体制备的接枝A2，其量基于A2，a21：60 至100重量％的至少一种乙烯基芳族单体或（甲基）丙烯酸酯或它们的混合物作为组分A21和a22：0至40重量％的至少一种烯属不饱和单体作为组分A22 具有130-500nm的中值粒径，并且具有多模态粒度分布，其中le 超过40重量％的颗粒存在于宽度为50nm的任何粒度范围内。

5. 发明授权

US06441062B1 Method for precipitating microsuspension polymers 失效
标题翻译：沉淀微悬浮聚合物的方法
公开(公告)号：US06441062B1
公开(公告)日：2002-08-27
申请号：US09600311
申请日：2000-08-18
申请人： Graham Edmund Mc Kee , Bernhard Czauderna , Harmut Heinen , Jürgen Koch
发明人： Graham Edmund Mc Kee , Bernhard Czauderna , Harmut Heinen , Jürgen Koch
IPC分类号： C08J300
CPC分类号： C08J3/16 , C08F6/24 , C08F265/06 , C08J3/005 , C08F2/18
摘要： In a process for precipitating microsuspension polymers from a suspension comprising them, a polymer dispersion prepared by emulsion polymerization is added to the suspension.
摘要翻译：在从包含它们的悬浮液中沉淀微悬浮聚合物的方法中，将通过乳液聚合制备的聚合物分散体加入到悬浮液中。

6. 发明授权

US6111012A Polymer compositions for graft copolymer as well as mixtures thereof and thermoplastic compounds containing them 失效
标题翻译：接枝共聚物的聚合物组合物及其混合物和含有它们的热塑性化合物
公开(公告)号：US6111012A
公开(公告)日：2000-08-29
申请号：US981292
申请日：1997-12-22
申请人： Michael Fischer , Jurgen Koch , Bernhard Rosenau , Graham Edmund Mc Kee , Sven Grabowski , Norbert Mosbach , Wolfgang Fischer , Walter Heckmann
发明人： Michael Fischer , Jurgen Koch , Bernhard Rosenau , Graham Edmund Mc Kee , Sven Grabowski , Norbert Mosbach , Wolfgang Fischer , Walter Heckmann
IPC分类号： C08F257/02 , C08F265/04 , C08F285/00 , C08L69/00 , C08L51/04
CPC分类号： C08F285/00 , C08F257/02 , C08F265/04 , C08L69/00
摘要： Graft copolymers (P1) contain, in any desired sequence, at least (P1.1) a hard segment having a glass transition temperature of at least 11.degree. C., which contains at least one vinylaromatic monomer as the monomer or as one of two or more monomers copolymerizable with one another and a crosslinker component comprising at least dihydrodicyclopentadienyl acrylate as a crosslinking agent having two or more functional groups of different reactivity and at least one crosslinking agent having two or more functional groups of the same reactivity, and (P1.2) a soft segment having a glass transition temperature of not more than 10.degree. C., which contains at least one acrylate as the monomer or as one of two or more monomers copolymerizable with one another, and blends and thermoplastic materials contain said graft copolymers.
摘要翻译： PCT No.PCT / EP96 / 02793 Sec。 371 1997年12月22日第 102（e）1997年12月22日PCT PCT 1996年6月26日PCT公布。第WO97 / 01588号公报日期1997年1月16日接枝共聚物（P1）以任何期望的顺序含有至少（P1.1）具有至少11℃的玻璃化转变温度的硬链段，其含有至少一种乙烯基芳族单体作为单体或作为彼此可共聚的两种或更多种单体之一和至少包含二氢二环戊二烯基丙烯酸酯作为具有两个或更多个不同反应性官能团的交联剂的交联剂组分和至少一种具有两个或更多个具有相同反应性的官能团的交联剂，和（P1.2）具有玻璃化转变温度不超过10℃的软链段，其包含至少一种作为单体的丙烯酸酯或作为可彼此共聚的两种或更多种单体之一，以及共混物和热塑性材料含有所述接枝共聚物。

7. 发明申请

US20080254295A1 Method for Preparing Surface-Modified, Nanoparticulate Metal Oxides, Metal Hydroxides and/or Metal Oxyhydroxides 审中-公开
标题翻译：制备表面改性纳米颗粒金属氧化物，金属氢氧化物和/或金属羟基氧化物的方法
公开(公告)号：US20080254295A1
公开(公告)日：2008-10-16
申请号：US12088334
申请日：2006-09-21
申请人： Hartmut Hibst , Jens Rieger , Jutta Kissel , Valerie Andre , Graham Edmund Mc Kee
发明人： Hartmut Hibst , Jens Rieger , Jutta Kissel , Valerie Andre , Graham Edmund Mc Kee
IPC分类号： C08K3/22 , B32B5/16
CPC分类号： C09C3/10 , A61K8/27 , A61K8/88 , A61K2800/412 , A61K2800/413 , A61Q17/04 , B82Y5/00 , B82Y30/00 , C01G9/02 , C01G49/0072 , C01G49/08 , C01P2004/64 , C01P2006/12 , C09C1/043 , C09C1/24 , Y10T428/2998
摘要： Methods are disclosed comprising: (a) mixing (i) an aqueous solution of at least one salt of at least one metal selected from the group consisting of aluminum, magnesium, cerium, iron, manganese, cobalt, nickel, titanium, zinc, zirconium and mixtures thereof with (ii) an aqueous solution of at least one polymer, at a pH value of 3 to 13 and at a temperature T1 of 0 to 50° C. to form a mixture; and (b) heating the mixture at a temperature T2 of 60 to 300° C. to form an aqueous suspension of surface-modified nanoparticulate particles comprising at least one compound selected from the group consisting of oxides, hydroxides, and oxide hydroxides of the at least one metal; along with powders prepared therefrom and uses therefore.
摘要翻译：公开的方法包括：（i）混合（i）至少一种选自铝，镁，铈，铁，锰，钴，镍，钛，锌，锆的金属盐的水溶液和其混合物与（ii）至少一种聚合物的水溶液，pH值为3至13，温度T 1为0至50℃以形成混合物; 和（b）在60至300℃的温度T 2下加热混合物以形成表面改性的纳米颗粒颗粒的水悬浮液，其包含至少一种选自以下的氧化物，氢氧化物和氧化物氢氧化物的化合物：至少一种金属; 以及由此制备的粉末并因此使用。

8. 发明授权

US06458879B1 Thermoplastic materials containing nanocomposites and an additional elastomer 失效
标题翻译：含有纳米复合材料和附加弹性体的热塑性材料
公开(公告)号：US06458879B1
公开(公告)日：2002-10-01
申请号：US09831398
申请日：2001-05-09
申请人： Stefan Grutke , Graham Edmund Mc Kee , Christof Mehler
发明人： Stefan Grutke , Graham Edmund Mc Kee , Christof Mehler
IPC分类号： C08K334
CPC分类号： C08L101/00 , Y10S977/775 , Y10S977/786 , Y10S977/926 , C08L2666/02
摘要： The invention relates to thermoplastic nanocomposites, comprising a) a thermoplastic (A), b) at least one compound (B) (delaminated phyllosilicate), whose structure has been built up from negatively charged phyllosilicates and from cations embedded between these, and which have been dispersed uniformly in component (A), and c) a rubber or rubber mixtures (C), where component (C) has a particle size distribution with a d(50) value of from 10 to 1000 nm. The invention further relates to a process for preparing these nanocomposites, and also to their use.
摘要翻译：本发明涉及热塑性纳米复合材料，其包括a）热塑性（A），b）至少一种化合物（B）（脱层页硅酸盐），其结构已经由带负电的页硅酸盐和从它们之间嵌入的阳离子构成，分散在组分（A）中，和c）橡胶或橡胶混合物（C），其中组分（C）具有ad（50）值为10至1000nm的粒度分布。本发明还涉及一种制备这些纳米复合材料的方法，以及它们的用途。

9. 发明授权

US06254949B1 Thermoplastic shaped bodies with segments of varying rigidity 有权
标题翻译：具有不同刚度段的热塑性成形体
公开(公告)号：US06254949B1
公开(公告)日：2001-07-03
申请号：US09402540
申请日：1999-10-06
申请人： Alexander Glück , Walter Götz , Volker Lohrbächer , Graham Edmund Mc Kee , Mark Völkel
发明人： Alexander Glück , Walter Götz , Volker Lohrbächer , Graham Edmund Mc Kee , Mark Völkel
IPC分类号： B29D2200
CPC分类号： C08L77/00 , Y10T428/1393 , Y10T428/31732 , C08L2666/02 , C08L51/00
摘要： The shaped article consists of a) from 5 to 95% by weight of a molding composition A made from at least one thermoplastic polyamide, copolyamide or blends of these as component A1, fillers and/or reinforcing materials, if desired, as component A2, impact modifiers as component A3 and other additives and processing aids as component A4, and b) from 5 to 95% by weight of a molding composition B, made from at least one thermoplastic polyamide, copolyamide or blends of these as component B1, at least one crosslinked elastomeric polymer as component B2 and, if desired, other additives and processing aids as component B3, where, in the shaped article, segments of molding compositions A and B are connected to one another over a relatively large area. These shaped articles may be used in the motor vehicle sector, for example as air or coolant ducts.
摘要翻译：成型制品由以下组成的a）5至95重量％的由至少一种热塑性聚酰胺，共聚酰胺或它们作为组分A1的共混物制成的模制组合物A，如果需要，填料和/或增强材料作为组分A2，冲击作为组分A3的改性剂和作为组分A4的其它添加剂和加工助剂，以及b）5-95重量％的由至少一种热塑性聚酰胺，共聚酰胺或它们作为组分B1的共混物制成的模塑组合物B，至少一种交联作为组分B2的弹性体聚合物和如果需要的其它添加剂和加工助剂作为组分B3，其中在成型制品中，模塑组合物A和B的链段在相对较大的区域上彼此连接。这些成型制品可以用在机动车辆部件中，例如用作空气或冷却剂管道。

10. 发明授权

US6022915A Thermoplastic molding compounds and a method of reducing the formation of residual monomers in these molding compounds 失效
标题翻译：热塑性成型化合物和减少这些模塑料中残留单体形成的方法
公开(公告)号：US6022915A
公开(公告)日：2000-02-08
申请号：US981688
申请日：1998-05-12
申请人： Anton Ticktin , Graham Edmund Mc Kee , Wolfgang Fischer , Binnur Gunesin , Norbert Guntherberg
发明人： Anton Ticktin , Graham Edmund Mc Kee , Wolfgang Fischer , Binnur Gunesin , Norbert Guntherberg
IPC分类号： C08J3/20 , C08F2/44 , C08F6/00 , C08K5/1545 , C08L25/16 , C08L33/12 , C08L33/20 , C08L55/02 , C08K5/15
CPC分类号： C08K5/1545
摘要： The invention relates to thermoplastic molding compositions consisting ofA) 98-99.995% by weight, based on A+B, of at least one acrylonitrile-containing polymer, andB) 0.005-2% by weight, based on A+B, of .alpha.-tocopherol.The invention also relates to a method for reducing the formation of residual monomers on thermal stress and shearing of the thermoplastic molding compositions by adding .alpha.-tocopherol.
摘要翻译： PCT No.PCT / EP96 / 02896 Sec。 371日期：1998年5月12日 102（e）日期1998年5月12日PCT 1996年7月2日PCT公布。出版物WO97 / 02314 日本1997年1月23日本发明涉及由A）98-99.995重量％（基于A + B）至少一种含丙烯腈的聚合物组成的热塑性模塑组合物，以及B）0.005-2重量％ A + B，α-生育酚。本发明还涉及通过加入α-生育酚来减少残余单体在热应力上的形成和热塑性模塑组合物的剪切的方法。

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