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    • 1. 发明申请
    • CROSS-LINKED MULTILAYER POROUS POLYMER MEMBRANE BATTERY SEPARATORS
    • 交联多层多孔聚合物膜电池分离器
    • US20150056492A1
    • 2015-02-26
    • US13971900
    • 2013-08-21
    • GM GLOBAL TECHNOLOGY OPERATIONS LLC
    • XIAOSONG HUANG
    • H01M2/16C08J9/28
    • H01M2/1686H01M2/145H01M2/1653H01M10/0525
    • A cross-linkable polyolefin composition (polyethylene, polypropylene or an ethylene-propylene copolymer) is coextruded with ultrahigh molecular weight polyethylene to form two-layer separator membranes, or three-layer separator membranes, for lithium-ion battery cells. In three-layer separator membranes, the cross-linkable polyolefin is formed as the outer faces of the separator for placement against facing surfaces of cell electrodes. The polymer materials initially contain plasticizer oil, which is removed from the extruded membranes, and the extruded membranes are also stretched to obtain a suitable open pore structure in the layered membranes to provide for suitable infiltration with a liquid electrolyte. The cross-linked polyolefin layer provides strength at elevated temperatures and the lower-melting, ultrahigh molecular weight polyethylene layer provides the separator membrane with a thermal shutdown capability.
    • 将可交联聚烯烃组合物(聚乙烯,聚丙烯或乙烯 - 丙烯共聚物)与超高分子量聚乙烯共挤出以形成用于锂离子电池单元的两层隔膜或三层隔膜。 在三层隔膜中,形成可交联聚烯烃作为隔板的外表面以放置在电池电极的相对表面上。 聚合物材料最初含有增塑剂油,其从挤出的膜中除去,并且挤出的膜也被拉伸以在层状膜中获得合适的开孔结构,以提供与液体电解质合适的渗透。 交联聚烯烃层在升高的温度下提供强度,较低熔点的超高分子量聚乙烯层为隔膜提供了热关断能力。