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    • 8. 发明授权
    • Method for the secondary cross-linking of hydrogels with N-acyl-2-oxazolidinones
    • 水凝胶与N-酰基-2-恶唑烷酮二次交联的方法
    • US06559239B1
    • 2003-05-06
    • US09831920
    • 2001-05-29
    • Ulrich RiegelMatthias WeismantelVolker FrenzThomas DanielFritz Engelhardt
    • Ulrich RiegelMatthias WeismantelVolker FrenzThomas DanielFritz Engelhardt
    • C08F830
    • C08F8/30C08J3/245C08J2300/14C08J2333/02C08F220/06
    • Liquid-absorbent polymers are prepared by a process for the gel and/or surface postcrosslinking of water-absorbent polymers by the polymer being treated with a surface postcrosslinking solution and being postcrosslinked and dried during and after the treatment by raising the temperature, wherein the surface postcrosslinking solution comprises as crosslinker a compound of the formula I where R1, R2, R3 and R4 are independently hydrogen, C1-C12-alkyl, C1-C12-alkenyl, C6-C12-aryl or C1-C12-alkoxy, R5 is C1-C16-alkyl, C1-C4-hydroxyalkyl, C6-C12-aryl, C1-C16-alkenyl or a group of the formula —(CH2)n—COOH or —(CH2)n—SO3H in the form of the acid or a respective metal salt, ammonium salt or triethanolammonium salt thereof or —(CH2—CH2—O—)m—R6, R6 is hydrogen or C1-C16-alkyl, n is from 1 to 10, m is from 1 to 20 dissolved in an inert solvent, and are used in hygiene articles, packaging materials and nonwovens.
    • 通过用表面后交联溶液处理的聚合物进行凝胶和/或表面后吸附吸水性聚合物的方法制备液体吸收聚合物,并且在处理之间和之后通过升高温度进行后交联和干燥,其中表面 后交联溶液包含作为交联剂的式I化合物,其中R 1,R 2,R 3和R 4独立地是氢,C 1 -C 12 - 烷基,C 1 -C 12 - 烯基,C 6 -C 12 - 芳基或C 1 -C 12 - 烷氧基,R 5是C 1 -C 16 - 烷基,C 1 -C 4 - 羟基烷基,C 6 -C 12 - 芳基,C 1 -C 16 - 烯基或式 - (CH 2)n -COOH或 - (CH 2)n -SO 3 H的基团,其形式为酸或相应的 金属盐,铵盐或三乙醇铵盐或 - (CH 2 -CH 2 -O-)m -R 6,R 6是氢或C 1 -C 16 - 烷基,n为1至10,m为1至20,溶于惰性溶剂 ,用于卫生用品,包装材料和无纺布。
    • 10. 发明授权
    • Water-soluble copolymers useful in drilling fluids
    • 用于钻井液的水溶性共聚物
    • US5510436A
    • 1996-04-23
    • US260037
    • 1994-06-15
    • Martin HilleHeinz WittkusJurgen TonhauserFritz EngelhardtUlrich Riegel
    • Martin HilleHeinz WittkusJurgen TonhauserFritz EngelhardtUlrich Riegel
    • C04B24/16C08F20/52C08F26/02C08F26/10C08F220/58C08F226/04C08F226/10C08L33/24C08L33/26C08L39/00C08L39/02C09D17/00C09K8/04C09K8/24C09K8/46C09K8/487C08F228/02
    • C04B24/163C04B24/16C04B24/2652C08F220/58C08F226/04C09D17/001C09K8/24C09K8/46C09K8/487
    • The water-soluble copolymer comprises 5-90% by weight of groups of the formula ##STR1## in which R.sup.1 is hydrogen or methyl, R.sup.2 is C.sub.2 -C.sub.10 -alkylene, and Me is ammonium or an alkali metal, 5-90% by weight of groups of the formula--CH.dbd.CH--CH.sub.2 --N.sup.+ R.sup.3 R.sup.4 --CH.sub.2 --CH.dbd.CH-- X.sup.- IIin which X is a halogen, R.sup.3 and R.sup.4, independently of one another, are C.sub.1 -C.sub.6 -alkyl, 0-60% by weight of groups of the formula ##STR2## in which R.sup.5 and R.sup.6 together are a propylene group which with inclusion of the radical ##STR3## forms a pyrrolidone radical, and 0-30% by weight of groups of the formula--CHR.sup.7 --CHR.sup.8 -- IVin which R.sup.7 is hydrogen or methyl and R.sup.8 is CONH.sub.2, CON(CH.sub.3).sub.2, cyano, SO.sub.3 H, SO.sub.3 Me, C.sub.6 H.sub.4 SO.sub.3 H, C.sub.6 H.sub.4 SO.sub.3 Me, CH.sub.2 SO.sub.3 H, CH.sub.2 SO.sub.3 Me, COOH, COOMe, or carboxy-C.sub.1 -C.sub.15 --alkyl, and Me is an ammonium cation or an alkali metal cation, and the order of components I to IV can be as desired.The copolymer is used as water-binding additive for suspensions of solids, preferably for cement slurries, gypsum slurries, mortars, drilling muds or pigment suspensions, or as water-binding additive for aqueous salt solutions.
    • 水溶性共聚物包含5-90重量%的式I的基团,其中R 1是氢或甲基,R 2是C 2 -C 10 - 亚烷基,Me是铵或碱金属,5-90% 的式-CH = CH-CH 2 -N + R 3 -CH 4 -CH = CH-X-II的基团,其中X是卤素,R 3和R 4彼此独立地是C 1 -C 6 - 烷基, 0-60重量%的其中R 5和R 6一起是含有基团“IMAGE”的丙烯基团的式“IMAGE”III形成吡咯烷酮基团,和0-30重量%的 其中R 7是氢或甲基,R 8是CONH 2,CON(CH 3)2,氰基,SO 3 H,SO 3 Me,C 6 H 4 SO 3 H,C 6 H 4 SO 3 Me,CH 2 SO 3 H,CH 2 SO 3 Me,COOH,COOMe或羧基-C 1 -C 15 - 烷基,Me是铵阳离子或碱金属阳离子,组分I至IV的顺序可以根据需要进行。 该共聚物用作固体悬浮液的水结合添加剂,优选用于水泥浆料,石膏浆料,砂浆,钻井泥浆或颜料悬浮液,或作为盐水溶液的水结合添加剂。