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    • 3. 发明授权
    • Hydrocracking catalyst and hydrocracking process
    • 加氢裂化催化剂和加氢裂化工艺
    • US4897178A
    • 1990-01-30
    • US143473
    • 1988-01-13
    • Donald F. BestGary N. LongRegis J. PelletJule A. RaboEdward T. WolynicFrank P. GortsemaAlbert R. Springer
    • Donald F. BestGary N. LongRegis J. PelletJule A. RaboEdward T. WolynicFrank P. GortsemaAlbert R. Springer
    • B01J29/06C10G47/16
    • B01J29/061C10G47/16
    • A process for hydrocracking a crude oil feed, a hydrocracking catalyst employed therein, and a process for the preparation of this catalyst are disclosed. The hydrocracking catalyst comprises a zeolitic aluminosilicate which has an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least 6 and which has been treated by (i) thermal treatment at an effective temperature and for an effective time in the presence of steam, followed by (ii) ion-exchange with a solution containing ammonium ion; and (2) an effective amount of a hydrogenation component. In a preferred embodiment, the starting crystalline zeolitic aluminosilicate is a Y-type zeolite having an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least about 9 and a unit cell dimension (a.sub.o) of less than about 24.55 .ANG., and the steam treatment is carried out for a period sufficient to cause a decrease of not more than about 0.1 .ANG. in the unit cell dimension, thereby producing a Y-type zeolite product having a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least about 9 and a unit cell dimension of less than about 24.45 .ANG..
    • 公开了一种用于加氢裂化原油进料的方法,其中使用的加氢裂化催化剂和制备该催化剂的方法。 加氢裂化催化剂包括SiO 2 / Al 2 O 3摩尔比至少为6的沸石硅铝酸盐,其已经通过(i)在有效温度下热处理并在蒸汽存在下持续有效时间进行处理,随后是(ii) 与含有铵离子的溶液进行离子交换; 和(2)有效量的氢化组分。 在优选的实施方案中,起始结晶沸石硅铝酸盐是具有至少约9的SiO 2 / Al 2 O 3摩尔比和小于约24.55埃的晶胞尺寸(ao)的Y型沸石,并且进行蒸汽处理 使其在单元电极尺寸内足够降低不大于约0.1Ag的范围内,由此生产SiO 2 / Al 2 O 3摩尔比为至少约9的Y型沸石产物,并且晶胞尺寸小于约 24.45 ANGSTROM。