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1. 发明授权

US5660928A Substrate for ink jet printing having a dual layer ink-receptive coating 失效
标题翻译：用于具有双层油墨接受涂层的喷墨印刷用基材
公开(公告)号：US5660928A
公开(公告)日：1997-08-26
申请号：US496266
申请日：1995-06-28
申请人： Bruce George Stokes , Francis Joseph Kronzer
发明人： Bruce George Stokes , Francis Joseph Kronzer
IPC分类号： B41M5/00 , B32B27/00 , B41M5/50 , B41M5/52 , B41J2/01
CPC分类号： B41M5/506 , B41M5/508 , B41M5/5218 , B41M5/5245 , Y10T428/31855 , Y10T442/2115
摘要： A coated substrate which includes a first, second, and third layer. The first layer has first and second surfaces. For example, the first layer may be a film or a nonwoven web. Desirably, the first layer will be a cellulosic nonwoven web. The second layer overlays the first surface of the first layer. The second layer is composed of from about 25 to about 70 percent by weight of a latex binder, from about 25 to about 65 percent by weight of a hydrophilic silica, from about 5 to about 20 percent by weight of a latent base, and from about 1 to about 4 percent by weight of a water-soluble viscosity modifier, in which all percents by weight are based on the total dry weight of the second layer. The third layer overlays the second layer and is composed of a water-soluble cationic polymer. Additional layers may be present, if desired.
摘要翻译：包括第一层，第二层和第三层的涂覆基材。第一层具有第一和第二表面。例如，第一层可以是膜或非织造纤维网。期望地，第一层将是纤维素非织造纤维网。第二层覆盖第一层的第一表面。第二层由约25至约70重量％的胶乳粘合剂，约25至约65重量％的亲水性二氧化硅，约5至约20重量％的潜在碱和约1至约4重量％的水溶性粘度改性剂，其中所有重量百分比均基于第二层的总干重。第三层覆盖第二层，由水溶性阳离子聚合物组成。如果需要，可以存在附加层。

2. 发明授权

US06432549B1 Curl-resistant, antislip abrasive backing and paper 失效
标题翻译：耐卷曲，防滑磨料背衬和纸张
公开(公告)号：US06432549B1
公开(公告)日：2002-08-13
申请号：US09141052
申请日：1998-08-27
申请人： Francis Joseph Kronzer
发明人： Francis Joseph Kronzer
IPC分类号： B32B2502
CPC分类号： B24D11/02 , D21H19/20 , D21H19/28 , D21H19/84 , D21H27/14 , Y10T428/31786 , Y10T428/3179 , Y10T428/31794 , Y10T428/31797 , Y10T428/31855 , Y10T428/3188 , Y10T428/31895 , Y10T428/31899 , Y10T428/31902 , Y10T428/31909 , Y10T442/674 , Y10T442/675 , Y10T442/678 , Y10T442/679
摘要： A curl-resistant, antislip abrasive backing which includes a polymer-reinforced paper having a first surface and a second surface; a synthetic polymeric layer bonded to the first surface; and an amorphous, rubbery polymer film layer bonded to the second surface. Also provided is a curl-resistant, antislip abrasive paper which includes a polymer-reinforced paper having a first surface and a second surface; a synthetic polymeric layer bonded to the first surface; a layer of abrasive particles bonded to the synthetic polymer layer; and an amorphous, rubbery polymer film layer bonded to the second surface. By way of examples, the amorphous, rubbery polymer may be a polyester elastomer or an amorphous, rubbery polypropylene.
摘要翻译：一种抗卷曲防滑磨料背衬，其包括具有第一表面和第二表面的聚合物增强纸; 结合到第一表面的合成聚合物层; 以及结合到第二表面的无定形橡胶状聚合物膜层。还提供了一种抗卷曲防滑砂纸，其包括具有第一表面和第二表面的聚合物增强纸; 结合到第一表面的合成聚合物层; 结合到合成聚合物层的磨料颗粒层; 以及结合到第二表面的无定形橡胶状聚合物膜层。作为实例，无定形橡胶状聚合物可以是聚酯弹性体或无定形橡胶状聚丙烯。

3. 发明授权

US6113725A Printable heat transfer material having cold release properties 失效
标题翻译：具有冷脱模特性的可印刷传热材料
公开(公告)号：US6113725A
公开(公告)日：2000-09-05
申请号：US89910
申请日：1998-06-03
申请人： Francis Joseph Kronzer
发明人： Francis Joseph Kronzer
IPC分类号： B32B7/06 , B41M5/00 , B41M5/025 , B41M5/035 , B41M5/40 , B41M5/41 , B41M5/42 , B41M5/44 , B41M5/50 , B41M5/52 , B41M7/00 , B44C1/17 , B32B31/00 , B05D5/04 , B44C1/16
CPC分类号： B44C1/1737 , B41M5/0256 , B41M5/0355 , B41M5/41 , B41M5/42 , B41M5/506 , B41M5/508 , B41M5/52 , B44C1/1712 , B44C1/1716 , B41M5/44 , B41M5/502 , B41M7/009 , Y10S428/913 , Y10S428/914 , Y10T428/24843 , Y10T428/24942 , Y10T428/254 , Y10T428/2817 , Y10T428/31504 , Y10T428/31779 , Y10T428/3179 , Y10T428/3188 , Y10T428/31895 , Y10T428/31993
摘要： A printable heat transfer material having cold release properties, which material includes a flexible first layer having first and second surfaces. The first layer typically will be a film or a cellulosic nonwoven web. A second layer overlays the first surface of the first layer and includes a thermoplastic polymer, such as a hard acrylic polymer or a poly(vinyl acetate). A third layer overlays the second layer and includes a thermoplastic polymer which melts in a range of from about 65.degree. C. to about 180.degree. C. The first layer may be a cellulosic nonwoven web, such as a latex-impregnated paper. The thermoplastic polymer of which the second layer is composed may have a glass transition temperature of at least about 25.degree. C. The second layer also may include an effective amount of a release-enhancing additive, such as a divalent metal ion salt of a fatty acid, a polyethylene glycol, or a mixture thereof. The third layer may include a film-forming binder, which binder may include a powdered thermoplastic polymer. For an ink jet printable heat transfer material, a fourth layer may overlay the third layer, which fourth layer includes a film-forming binder and a powdered thermoplastic polymer. If desired, a fifth layer may overlay the second layer, thereby being located between the second layer and the third layer. The fifth layer may include a film-forming binder which melts in a range of from about 65.degree. C. to about 180.degree. C.
摘要翻译：具有冷脱性的可印刷热转印材料，该材料包括具有第一表面和第二表面的柔性第一层。第一层通常将是薄膜或纤维素非织造纤维网。第二层覆盖第一层的第一表面，并且包括热塑性聚合物，例如硬丙烯酸聚合物或聚（乙酸乙烯酯）。第三层覆盖第二层，并且包括在约65℃至约180℃范围内熔化的热塑性聚合物。第一层可以是纤维素非织造纤维网，例如胶乳浸渍的纸。组成第二层的热塑性聚合物可具有至少约25℃的玻璃化转变温度。第二层还可包括有效量的增效添加剂，例如脂肪的二价金属离子盐酸，聚乙二醇或其混合物。第三层可以包括成膜粘合剂，该粘合剂可以包括粉末状热塑性聚合物。对于可喷墨印刷的传热材料，第四层可以覆盖第三层，该第四层包括成膜粘合剂和粉末状热塑性聚合物。如果需要，第五层可以覆盖第二层，从而位于第二层和第三层之间。第五层可以包括在约65℃至约180℃范围内熔化的成膜粘合剂。

4. 发明授权

US6103364A Ink jet printable, washable saturated cellulosic substrate 失效
标题翻译：喷墨可打印的，可洗涤的饱和纤维素基材
公开(公告)号：US6103364A
公开(公告)日：2000-08-15
申请号：US885558
申请日：1997-06-30
申请人： Linda Garner Harris , Francis Joseph Kronzer , Russell Lynn Dolsey
发明人： Linda Garner Harris , Francis Joseph Kronzer , Russell Lynn Dolsey
IPC分类号： B41M5/00 , B32B5/26 , B41M5/50 , B41M5/52 , D04H1/46 , D04H1/48 , D04H13/00 , B32B5/16
CPC分类号： B32B5/26 , D04H1/425 , D04H1/48 , D04H1/488 , D04H1/49 , D04H1/587 , D04H1/64 , Y10T428/249932 , Y10T428/24994 , Y10T428/249944 , Y10T428/253 , Y10T428/254 , Y10T428/2915 , Y10T428/298
摘要： A saturated hydroentangled fibrous web which includes a fibrous web having a plurality of entanglement loci as a consequence of subjecting the fibrous web to high pressure liquid jets and a saturant which is present in the hydroentangled fibrous web at a level of from about 10 to about 100 percent, based on the dry weight of the fibers. The saturant is adapted to render the saturated paper durable and ink jet printable. The fibrous web is composed of fibers, in which from about 20 to 100 percent by weight, based on the total weight of the fibers, are cellulosic fibers; from 0 to about 70 percent by weight, based on the total weight of the fibers, are mercerized cellulosic fibers; and from about 80 to 0 percent by weight of the fibers, based on the total weight of the fibers, are synthetic polymer fibers. The saturant includes from about 98 to about 70 percent, on a dry weight basis, of a latex reinforcing polymer having a glass transition temperature of from about -40.degree. C. to about 25.degree. C.; and from about 5 to about 70 percent, on a dry weight basis, of a cationic polymer. Either or both of the latex reinforcing polymer and the cationic polymer have crosslinkable functional groups. In addition to the fibrous web, a bonded nonwoven may be present.
摘要翻译：饱和水刺纤维网，其包括具有多个缠结位点的纤维网，其结果是将纤维网经受高压液体射流和在水力缠结纤维网中以约10至约100的水平存在的饱和物基于纤维的干重。饱和度适于使饱和纸耐用和喷墨打印。纤维网由纤维组成，其中基于纤维总重量的约20至100重量％是纤维素纤维; 0至约70重量％，基于纤维的总重量，是丝光纤维素纤维; 和约80至0重量％的纤维，基于纤维的总重量，为合成聚合物纤维。饱和剂包括基于干重约98％至约70％的玻璃化转变温度为约-40℃至约25℃的胶乳增强聚合物; 和约5-约70重量％的阳离子聚合物。胶乳增强聚合物和阳离子聚合物中的任一种或两者具有可交联官能团。除了纤维网之外，可以存在粘合的非织造布。

5. 发明授权

US6033739A Fusible printing coating for durable images 有权
标题翻译：用于耐用图像的易熔印刷涂层
公开(公告)号：US6033739A
公开(公告)日：2000-03-07
申请号：US285958
申请日：1999-04-05
申请人： Francis Joseph Kronzer
发明人： Francis Joseph Kronzer
IPC分类号： B41M5/00 , B05D5/04 , B05D7/24 , B32B27/00 , B41M5/50 , B41M5/52 , B41M7/00 , C09D5/00 , C09D123/04 , C09D177/00 , C09D201/00 , D06P1/52 , D06P1/56 , D06P5/20 , D06P5/30 , B05D3/02
CPC分类号： B41M5/52 , B41M7/0054 , D06P5/2072 , D06P5/2077 , D06P5/30 , B41M5/508 , B41M5/5227 , B41M5/5245 , B41M5/5254 , B41M5/5272 , D06P1/5214 , D06P1/5235 , D06P1/5257 , D06P1/5278 , D06P1/56 , Y10T428/249921 , Y10T428/254 , Y10T428/31551 , Y10T428/31591 , Y10T428/31725 , Y10T428/31757 , Y10T428/31783 , Y10T428/31902 , Y10T428/31971 , Y10T442/2787 , Y10T442/2811
摘要： A coating composition which encompasses an aqueous dispersion of from about 2 to about 40 percent by dry weight, based on the dry weight of the coating composition, of a cationic polymer; and from about 60 to about 98 percent by dry weight, based on the dry weight of the coating composition, of a nonionic or cationic binder. The coating composition is thermally fusible and adapted to be receptive to ink jet inks and to retain the ink jet inks after being thermally fused. Alternatively, the coating composition may encompass an aqueous dispersion of a powdered thermoplastic polymer and from about 10 to about 150 dry parts by weight of a binder, based on 100 dry parts by weight of the powdered thermoplastic polymer. Desirably, the coating composition will encompass an aqueous dispersion of a powdered thermoplastic polymer; from about 2 to about 50 dry parts by weight, based on 100 dry parts by weight of the powdered thermoplastic polymer, of a cationic polymer; and from about 10 to about 150 dry parts by weight, based on 100 dry parts by weight of the powdered thermoplastic polymer, of a nonionic or cationic binder. The coating composition also may contain from about 1 to about 5 parts by weight, based on the weight of the coating composition, of a surfactant. When applied to a substrate, the coating composition permits printing on the substrate with ink jet inks to give a printed image which is durable, especially in the presence of water.
摘要翻译：一种涂料组合物，其包含基于涂料组合物的干重约2至约40重量％的水分散体阳离子聚合物; 和约60至约98％的干重，基于涂料组合物的干重，非离子或阳离子粘合剂。涂料组合物是热熔性的并且适于接受喷墨油墨并且在热熔融之后保持喷墨油墨。或者，涂料组合物可以包含粉末状热塑性聚合物的水分散体和约10至约150干重份的粘合剂，基于100重量份粉末状热塑性聚合物。期望地，涂料组合物将包括粉末状热塑性聚合物的水分散体; 约2至约50干重份，基于100重量份粉末状热塑性聚合物，阳离子聚合物; 和约10至约150干重份，基于100重量份粉末状热塑性聚合物，非离子或阳离子粘合剂。涂料组合物还可以含有约1至约5重量份，基于涂料组合物的重量，表面活性剂。当施加到基底上时，涂料组合物允许用喷墨油墨在基材上印刷，以得到耐久的印刷图像，特别是在水的存在下。

6. 发明授权

US5716900A Heat transfer material for dye diffusion thermal transfer printing 失效
标题翻译：用于染料扩散热转印的传热材料
公开(公告)号：US5716900A
公开(公告)日：1998-02-10
申请号：US432290
申请日：1995-05-01
申请人： Francis Joseph Kronzer , Jerry Wayne Estes
发明人： Francis Joseph Kronzer , Jerry Wayne Estes
IPC分类号： B32B7/02 , B41M5/00 , B41M5/50 , B41M5/52 , D06P5/24 , D06P5/28 , D06Q1/12 , B41M5/035 , B41M5/38
CPC分类号： D06Q1/12 , B32B7/02 , B41M5/0256 , B41M5/52 , D06P5/003 , D06P5/004 , B41M5/5227 , B41M5/5254 , Y10S428/913 , Y10S428/914 , Y10T428/24934 , Y10T428/24942 , Y10T428/31
摘要： A printable material which includes a first, second, and third layer. The first layer has first and second surfaces. For example, the first layer may be a film or a cellulosic nonwoven web. The second layer overlays the first surface of the first layer. The second layer is composed of a first thermoplastic polymer having a melt flow rate of at least about 15 g/10 minutes at a temperature of 190.degree. C. and a load of 2.16 kg. The third layer overlays the second layer. The third layer includes a second thermoplastic polymer having a glass transition temperature equal to or greater than about 30.degree. C. The third layer also may include from about 1 to about 40 parts by weight, per 100 parts by weight of the second thermoplastic polymer, of a release agent. Desirably, the first and second layers will have smoothness values, as measured by a Sheffield Smoothness Tester, no greater than about 150 cc/minute and no greater than about 100 cc/minute, respectively. The third layer may contain up to about 150 parts by weight, per 100 parts by weight of the second thermoplastic polymer, of a plasticizer, and up to about 100 parts by weight, per 100 parts by weight of the second thermoplastic polymer, of a polymeric adhesion-transfer aid. The printable material is especially suitable for use as a dye diffusion thermal transfer printable heat transfer material.
摘要翻译：包括第一层，第二层和第三层的可印刷材料。第一层具有第一和第二表面。例如，第一层可以是膜或纤维素非织造纤维网。第二层覆盖第一层的第一表面。第二层由在190℃的温度和2.16kg的载荷下的熔体流动速率为至少约15g / 10分钟的第一热塑性聚合物组成。第三层覆盖第二层。第三层包括玻璃化转变温度等于或大于约30℃的第二热塑性聚合物。第三层还可以包含每100重量份第二热塑性聚合物约1至约40重量份，的脱模剂。理想地，第一层和第二层将具有由谢菲尔德平滑度测试仪测量的平滑度值，分别不大于约150cc /分钟且不大于约100cc /分钟。相对于每100重量份的第二热塑性聚合物，第三层可以含有至多约150重量份，相对于每100重量份的第二热塑性聚合物，增塑剂，和至多约100重量份，聚合物粘合转移助剂。可印刷材料特别适合用作染料扩散热转印可印刷热转印材料。

7. 发明授权

US06703086B2 Printable material 有权
标题翻译：可打印材料
公开(公告)号：US06703086B2
公开(公告)日：2004-03-09
申请号：US09766266
申请日：2001-01-19
申请人： Francis Joseph Kronzer , Leonard Eugene Zelazoski , Ty Jackson Stokes , Jeffrey Lawrence McManus
发明人： Francis Joseph Kronzer , Leonard Eugene Zelazoski , Ty Jackson Stokes , Jeffrey Lawrence McManus
IPC分类号： B41M500
CPC分类号： D06P5/30 , B32B5/26 , B41M5/506 , B41M5/508 , B41M5/52 , B41M5/5245 , B41M5/5254 , B41M7/00 , B44C1/1712 , D06P5/003 , Y10T428/273 , Y10T428/277
摘要： A printable material which includes a flexible first layer having first and second surfaces and a second layer. The first layer may be a film or a cellulosic nonwoven web. The second layer overlays and is bonded to the first surface of the first layer and includes a nonwoven web. The first layer has a basis weight of from about 20 to about 140 grams per square meter. The thermoplastic polymer has a melting point of from about 90° C. to about 250° C. and the second layer has a basis weight of at least about 10 grams per square meter. The first layer may be a cellulosic nonwoven web, such as a latex-impregnated paper. The second layer may be thermally bonded to the first layer or bonded by an adhesive. A release layer may be present between the first layer and the heat-activated adhesive. The second layer may contain from about 0.1 to about 20 percent by weight, based on the weight of the second layer, of a material which increases the viscosity of an ink jet ink when printed on the second layer. The second layer also may contain from about 0.1 to about 5 percent by weight, based on the weight of the second layer, of a cationic polymer. When the second layer is prepared from a thermoplastic polymer, the ink jet printable material may be used as a heat transfer material. Methods of preparing the printable material also are described.
摘要翻译：一种可印刷材料，其包括具有第一表面和第二表面的柔性第一层和第二层。第一层可以是膜或纤维素非织造纤维网。第二层覆盖并结合到第一层的第一表面并且包括非织造纤维网。第一层的基重为约20至约140克/平方米。热塑性聚合物的熔点为约90℃至约250℃，第二层的基重为至少约10克/平方米。第一层可以是纤维素非织造纤维网，例如胶乳浸渍的纸。第二层可以热粘合到第一层或通过粘合剂粘合。释放层可以存在于第一层和热活化粘合剂之间。基于第二层的重量，第二层可含有约0.1至约20重量％的材料，其在印刷在第二层上时增加喷墨油墨的粘度。第二层还可以含有约0.1至约5重量％的基于第二层的重量的阳离子聚合物。当第二层由热塑性聚合物制备时，喷墨印刷材料可用作传热材料。还描述了制备可印刷材料的方法。

8. 发明授权

US06281166B1 Thermal dye diffusion coating and substrate 失效
标题翻译：热染料扩散涂层和基材
公开(公告)号：US06281166B1
公开(公告)日：2001-08-28
申请号：US09286483
申请日：1999-04-05
申请人： Francis Joseph Kronzer
发明人： Francis Joseph Kronzer
IPC分类号： B41M5035
CPC分类号： B41M5/5227 , Y10T428/25
摘要： A coating suitable for receiving an image by dye diffusion printing which includes a thermoplastic polymer having a glass transition temperature of at least about 30° C. and a powdered plasticizer having a melting point of at least about 80° C. The thermoplastic polymer may have a glass transition temperature of at least about 40° C. For example, the thermoplastic polymer may be a vinyl chloride-acrylate copolymer. The plasticizer may be an aromatic carboxylic acid ester, such as cyclohexane dimethanol dibenzoate. The average particle size of the powdered plasticizer may be no greater than about 20 micrometers. The weight ratio of the thermoplastic polymer to the plasticizer typically is in a range of from about 80:20 to about 40:60. Finally, the coating includes a release agent. The release agent may be present in a range of from about 0.5 to about 10 percent by weight, based on the weight of dry coating. The present invention also provides a coated substrate suitable for receiving an image by dye diffusion printing and a coating composition which is an aqueous dispersion of a thermoplastic polymer having a glass transition temperature of at least about 30° C., a powdered plasticizer having a melting point of at least about 80° C., and a release agent.
摘要翻译：适于通过染料扩散印刷接收图像的涂层，其包括玻璃化转变温度至少约30℃的热塑性聚合物和熔点至少约80℃的粉末状增塑剂。热塑性聚合物可具有玻璃化转变温度至少约40℃。例如，热塑性聚合物可以是氯乙烯 - 丙烯酸酯共聚物。增塑剂可以是芳族羧酸酯，例如环己烷二甲醇二苯甲酸酯。粉末增塑剂的平均粒度可以不大于约20微米。热塑性聚合物与增塑剂的重量比通常在约80:20至约40:60的范围内。最后，涂层包括脱模剂。基于干涂层的重量，脱模剂可以以约0.5至约10重量％的范围存在。本发明还提供了适用于通过染料扩散印刷接收图像的涂布基材和作为玻璃化转变温度为至少约30℃的热塑性聚合物的水性分散体的涂料组合物，具有熔融的玻璃化转变温度的粉末状增塑剂至少约80℃的点和脱模剂。

9. 发明授权

US06200668B1 Printable heat transfer material having cold release properties 失效
标题翻译：具有冷脱模特性的可印刷传热材料
公开(公告)号：US06200668B1
公开(公告)日：2001-03-13
申请号：US09081191
申请日：1998-05-19
申请人： Francis Joseph Kronzer
发明人： Francis Joseph Kronzer
IPC分类号： B32B700
CPC分类号： B44C1/1737 , B41M5/0256 , B41M5/0355 , B41M5/41 , B41M5/42 , B41M5/44 , B41M5/502 , B41M5/506 , B41M5/508 , B41M5/52 , B41M7/009 , B44C1/1712 , B44C1/1716 , Y10S428/913 , Y10S428/914 , Y10T428/24843 , Y10T428/24942 , Y10T428/254 , Y10T428/2817 , Y10T428/31504 , Y10T428/31779 , Y10T428/3179 , Y10T428/3188 , Y10T428/31895 , Y10T428/31993
摘要： A printable heat transfer material having cold release properties, which material includes a flexible first layer having first and second surfaces. The first layer typically will be a film or a cellulosic nonwoven web. A second layer overlays the first surface of the first layer and includes a thermoplastic polymer, such as a hard acrylic polymer or a poly(vinyl acetate). A third layer overlays the second layer and includes a thermoplastic polymer which melts in a range of from about 65° C. to about 180° C. The first layer may be a cellulosic nonwoven web, such as a latex-impregnated paper. The thermoplastic polymer of which the second layer is composed may have a glass transition temperature of at least about 25° C. The second layer also may include an effective amount of a release-enhancing additive, such as a divalent metal ion salt of a fatty acid, a polyethylene glycol, or a mixture thereof. The third layer may include a film-forming binder, which binder may include a powdered thermoplastic polymer. For an ink jet printable heat transfer material, a fourth layer may overlay the third layer, which fourth layer includes a film-forming binder and a powdered thermoplastic polymer. If desired, a fifth layer may overlay the second layer, thereby being located between the second layer and the third layer. The fifth layer may include a film-forming binder which melts in a range of from about 65° C. to about 180° C.
摘要翻译：具有冷脱性的可印刷热转印材料，该材料包括具有第一表面和第二表面的柔性第一层。第一层通常将是薄膜或纤维素非织造纤维网。第二层覆盖第一层的第一表面，并且包括热塑性聚合物，例如硬丙烯酸聚合物或聚（乙酸乙烯酯）。第三层覆盖第二层，并且包括在约65℃至约180℃范围内熔化的热塑性聚合物。第一层可以是纤维素非织造纤维网，例如胶乳浸渍的纸。组成第二层的热塑性聚合物可以具有至少约25℃的玻璃化转变温度。第二层还可以包括有效量的释放增强添加剂，例如脂肪族的二价金属离子盐酸，聚乙二醇或其混合物。第三层可以包括成膜粘合剂，该粘合剂可以包括粉末状热塑性聚合物。对于可喷墨印刷的传热材料，第四层可以覆盖第三层，该第四层包括成膜粘合剂和粉末状热塑性聚合物。如果需要，第五层可以覆盖第二层，从而位于第二层和第三层之间。第五层可以包括在约65℃至约180℃的范围内熔化的成膜粘合剂。

10. 发明授权

US5945375A Thermal dye diffusion coating and substrate 失效
标题翻译：热染料扩散涂层和基材
公开(公告)号：US5945375A
公开(公告)日：1999-08-31
申请号：US27515
申请日：1998-02-20
申请人： Francis Joseph Kronzer
发明人： Francis Joseph Kronzer
IPC分类号： B41M5/382 , B41M5/50 , B41M5/52 , B41M5/035 , B41M5/38
CPC分类号： B41M5/5227 , Y10S428/913 , Y10S428/914 , Y10T428/24802 , Y10T428/24942 , Y10T428/25
摘要： A coating suitable for receiving an image by dye diffusion printing which includes a thermoplastic polymer having a glass transition temperature of at least about 30.degree. C. and a powdered plasticizer having a melting point of at least about 80.degree. C. The thermoplastic polymer may have a glass transition temperature of at least about 40.degree. C. For example, the thermoplastic polymer may be a vinyl chloride-acrylate copolymer. The plasticizer may be an aromatic carboxylic acid ester, such as cyclohexane dimethanol dibenzoate. The average particle size of the powdered plasticizer may be no greater than about 20 micrometers. The weight ratio of the thermoplastic polymer to the plasticizer typically is in a range of from about 80:20 to about 40:60. Finally, the coating includes a release agent. The release agent may be present in a range of from about 0.5 to about 10 percent by weight, based on the weight of dry coating. The present invention also provides a coated substrate suitable for receiving an image by dye diffusion printing and a coating composition which is an aqueous dispersion of a thermoplastic polymer having a glass transition temperature of at least about 30.degree. C., a powdered plasticizer having a melting point of at least about 80.degree. C., and a release agent.
摘要翻译：适用于通过染料扩散印刷接收图像的涂层，其包括玻璃化转变温度至少约30℃的热塑性聚合物和熔点至少为约80℃的粉末状增塑剂。热塑性聚合物可具有玻璃化转变温度为至少约40℃。例如，热塑性聚合物可以是氯乙烯 - 丙烯酸酯共聚物。增塑剂可以是芳族羧酸酯，例如环己烷二甲醇二苯甲酸酯。粉末增塑剂的平均粒度可以不大于约20微米。热塑性聚合物与增塑剂的重量比通常在约80:20至约40:60的范围内。最后，涂层包括脱模剂。基于干涂层的重量，脱模剂可以以约0.5至约10重量％的范围存在。本发明还提供了适用于通过染料扩散印刷接收图像的涂布基材和作为玻璃化转变温度为至少约30℃的热塑性聚合物的水性分散体的涂料组合物，具有熔融至少约80℃，以及脱模剂。

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