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1. 发明授权

US3776921A Hydantoin acyl halides and their use as insecticides 失效
标题翻译： HYDANTOIN ACYL HALIDES及其用作杀虫剂
公开(公告)号：US3776921A
公开(公告)日：1973-12-04
申请号：US3776921D
申请日：1971-12-17
申请人： EXXON RESEARCH ENGINEERING CO
发明人： SINGHAL G , LESSER J
IPC分类号： A01N57/08 , C07D233/76 , C07D233/80 , C07F9/6506 , C07D49/32 , C07F9/08
CPC分类号： A01N57/08 , C07D233/80 , C07F9/6506 , C07F9/65061
摘要： ACYL HYDANTOIN DERIVATIVES DEFINED BY THE FOLLOWING STRUCTURAL FORMULA:

1-(X-C(-R6)(-R7)-CO-),2,5-DI(O=),3-R1,4-R2,4-R3-

IMIDAZOLIDINE

WHEREIN R1 IS ONE SELECTED FROM THE GROUP CONSISTING OF C1-C6 LOWER ALKYL OPTIONALLY SUBSTITUTED BY CHLORINE, BROMINE, C1-C6 ALKOXY AND C1-C6 ALKYLTHIO; C3-C6 ALKENYL; C3-C6 ALKYNYL; C3-C8 CYCLOAKLYL; OR PHENYL OPTIONALLY SUBSTITUTED WITH CHLORINE, BROMINE, TRIFLUROMETHYL OR NO2. R2 AND R3 CAN BE THE SAME OR DIFFERENT AND EITHER ONE IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, C1-C4 ALKYL, C1-C4 CHLOROALKYL, PHENYL OPTIONALLY SUBSTITUTED WITH CHLORINE OR NITRO AND C1-C4 ALKOXY. X IS ONE SELECTED FROM THE GROUP CONSISTING OF CHLORINE, BROMINE, FLUORINE AND A MOIETY DEFINED BY

-S-P(=Y)(-R3)-R5

HAVE BEEN FOUND TO POSSESS POST-EMERGENCE HERBICIDAL ACTIVITY. IN THIS STRUCTURE, R1, R2,R3, R7 AND R6 ARE DEFINED AS HEREINABOVE, AND Q IS ONE SELECTED FROM THE GROUP CONSISTING OF CHLORINE, BROMINE AND FLUORINE.

IMIDAZOLIDINE

1-(Q-C(-R6)(-R7)-CO-),2,5-DI(O=),3-R1,4-R2,4-R3-

WHEREIN Y CAN BE EITHER O OR S AND R4 AND R5 CAN BE THE SAME OR DIFFERENT AND SELECTED FROM THE GROUP CONSISTING OF C1-C6 ALKOXY, C1-C6 ALKYL, C1-C6 ALKYLTHIO, PHENYL OPTIONALLY SUBSTITUTED WITH CHLORINE OR BROMINE, PHENOXY OPTIONALLY SUBSTITUTED WITH CHLORINE OR BROMINE; R6 AND R7 CAN BE THE SAME OR DIFFERENT AND CAN BE SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, AND C1-C6 ALKYL. ORGANIC COMPOUNDS REPRESENTED BY THIS STRUCTURE HAVE BEEN FOUND TO HAVE PESTICIDAL, PARTICULARLY INSECTICIDAL, ACTIVITY. COMPOUNDS REPRESENTED BY THE FOLLOWING STRUCTUTE:

2. 发明授权

US3823161A Aminothiophene derivatives 失效
标题翻译：氨基苯衍生物
公开(公告)号：US3823161A
公开(公告)日：1974-07-09
申请号：US3558770
申请日：1970-05-07
申请人： EXXON RESEARCH ENGINEERING CO
发明人： LESSER J
IPC分类号： C07D333/38 , C07D63/16
CPC分类号： C07D333/38
摘要： THE COMPOUNDS OF THE SUBJECT INVENTION ARE REPRESENTED BY THE FOLLOWING FORMULA

2-R5,3-R4,(R2-C(=X)-N(-R1)-),(R3-CO-)-THIOPHENE

WHEREIN R1 IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, C1 THROUGH C8 ALKYL; R2 IS ONE SELECTED FROM THE GROUP CONSISTING OF C1 THROUGH C6 ALKYL (OPTIONALLY SUBSTITUTED BY CHLORINE, BROMINE, OR CYANO), C1-C6 ALKOXY, C1 TO C6 ALKYLTHIO, C1-C6 MONOALKYLAMINO, C2-C6 DIALKYLAMINO, PHENYL (OPTIONALLY SUBSTITUTED BY CHLORINE, NITRO, OR TRIFLUOROMETHYL), C3-C8 ALKENYL, C3-C6 ALKYNYL, C3-C8 CYCLOALKYL; R3 CAN BE C1 TO C10 ALKOXY, C1 TO C10 MONOALKYLAMINO, C2-C10 DIALKYLAMINO, PHENOXY, AND ANILIDO; R4 AND R5 CAN BE THE SAME OR DIFFERENT AND ARE SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, C1 TO C6 ALKYL, PHENYL, CHLORINE AND BROMINE; X IS EITHER O OR S, THESE COMPOUNDS HAVE BEEN FOUND TO PROCESS PESTICIDAL ACTIVITY AND, IN PARTICULAR, POST- AND PRE-EMERGENCE HERBICIDAL ACTIVITY AS WELL AS FUNGICIDAL ACTIVITY.

3. 发明授权

US3742098A Process for the preparation of s-vinylic esters of thiophosphorus acids 失效
标题翻译：制备硫代酸的S-乙酸酯的方法
公开(公告)号：US3742098A
公开(公告)日：1973-06-26
申请号：US3742098D
申请日：1969-07-07
申请人： EXXON RESEARCH ENGINEERING CO
发明人： OSWALD A , LESSER J
IPC分类号： C08F30/00 , A01N57/02 , A01N57/12 , A01N57/22 , B01J31/00 , C07B61/00 , C07F9/173 , C07F9/32 , C07F9/40 , C08F30/02 , C07F9/16 , A01N9/36
CPC分类号： C07F9/3264 , C07F9/173 , C07F9/327 , C07F9/4078
摘要： Phosphoryl disulfides can be added to acetylenes to form Svinylic thiophosphate esters. The additions occur by way of a free radical mechanism in the presence of radiation and/or chemical initiators. The adducts are highly effective as pesticides.
摘要翻译：可将磷酰二硫化物加入到乙炔中以形成S-乙烯基硫代磷酸酯。在辐射和/或化学引发剂存在下，通过自由基机理进行添加。加合物作为杀虫剂非常有效。

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