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    • 7. 发明授权
    • Preservatives for cellulose containing products
    • 含有纤维素的产品防腐剂
    • US4970201A
    • 1990-11-13
    • US391469
    • 1989-08-09
    • Eberhard GiebelerDetlef WehleHelmut HartnerFranz KonigHelmut Berenbold
    • Eberhard GiebelerDetlef WehleHelmut HartnerFranz KonigHelmut Berenbold
    • B27K3/36A01N55/08B27K3/15B27K3/50C08G65/26
    • B27K3/163B27K3/15C08G65/2639C08L97/02C08L79/02Y10S514/947
    • A biocidal preservative for cellulose-containing products containing a biocidally effective amount of a polymeric quaternary ammonium borate obtained by simultaneous reaction of (A) at least one member of the group consisting of boric acid and salts and esters thereof and (B) an amine of the formula ##STR1## and (C) ethylene oxide or propylene oxide wherein R.sub.1 is alkyl or alkenyl of 8 to 22 carbon atoms and R.sub.2 is hydrogen, alkyl of 1 to 22 carbon atoms or --CH.sub.2 CH.sub.2 NH.sub.2 or R.sub.1 is alkyl of 1 to 4 carbon atoms and R.sub.2 is --(CH.sub.2 CH.sub.2 O).sub.x --H or --(CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --H, R.sub.3 is selected from the group consisting of hydrogen, --(CH.sub.2 CH.sub.2 O).sub.x --H, (CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --H and --CH.sub.2 CH.sub.2 CH.sub.2 NH.sub.2, R.sub.4 and R.sub.6 are individually selected from the group consisting of alkyl of 1 to 4 carbon atoms, --(CH.sub.2 CH.sub.2 O).sub.x --H and --(CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --H, and R.sub.5 and R.sub.7 are individually --(CH.sub.2 CH.sub.2 O).sub.x --H and --(CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --H, A is selected from the group consisting of --(CH.sub.2).sub.n, --(CH.sub.2 CH.sub.2 --O--CH.sub.2 CH.sub.2).sub.n -- and --(CH.sub.2 CH.sub.2 --NH--CH.sub.2 CH.sub.2).sub.n --x is an integer from 1 to 55 and n is an integer of 1 to 20, the molar ratio of A:B:C being 1:2 to 20:0.6 to 1.5.
    • 含有生物有效量的聚合季铵硼酸盐的含有杀生物剂的产品的杀生物防腐剂,其通过(A)由硼酸及其盐和酯组成的组中的至少一个成员同时反应而获得,和(B) 式(IMA)和(C)环氧乙烷或环氧丙烷,其中R1是8-22个碳原子的烷基或烯基,R2是氢,1-22个碳原子的烷基或-CH2CH2NH2或R1是1到4个碳原子的烷基 原子,R 2是 - (CH 2 CH 2 OCH 2)x H或 - (CH 2 CH 2 CH 2 O)x H,R 3选自氢, - (CH 2 CH 2 O)x H,(CH 2 CH 2 CH 2 O)x H和-CH 2 CH 2 CH 2 NH 2,R 4和R 6各自选自 具有1至4个碳原子的烷基, - (CH 2 CH 2 O)x H和 - (CH 2 CH 2 CH 2 O)x H,且R 5和R 7分别为 - (CH 2 CH 2 O)x H和 - (CH 2 CH 2 CH 2 O)x H,A选自 - (CH 2 )n, - (CH 2 CH 2 -O-CH 2 CH 2)n - 和 - (CH 2 CH 2 -NH-CH 2 CH 2)n x为1〜55的整数,n为整数 r为1〜20,A:B:C的摩尔比为1:2〜20:0.6〜1.5。