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1. 发明授权

US06476172B1 Metallocene catalyzed propylene-&agr;-olefin random copolymer melt spun fibers 有权
标题翻译：茂金属催化的丙烯-α-烯烃无规共聚物熔纺纤维
公开(公告)号：US06476172B1
公开(公告)日：2002-11-05
申请号：US09916476
申请日：2001-07-27
申请人： Darek Wachowicz , Cyril Chevillard , Lisa K. Albe
发明人： Darek Wachowicz , Cyril Chevillard , Lisa K. Albe
IPC分类号： C08F21006
CPC分类号： D01F6/30 , C08F210/06 , C08F210/16 , Y10T428/2913 , C08F2500/20 , C08F2500/03
摘要： A fiber product drawn from an isotactic propylene copolymer of a C2, C4, C5, C6, C7 or C8 &agr;-olefin monomer produced in the presence of a metallocene catalyst characterized by a bridged chiral and stereorigid cyclopentadienyl or substituted cyclopentadienyl ligand structure of a transitional metal selected from group 4b, 5b, or 6b metals of the Periodic Table of Elements, the copolymer having a MFR less than 35, suitably about 30 or less. The copolymer is heated to a molten state and extruded to form a fiber preform. The preform is subjected to spinning at a spinning speed of at least 300 meters per minutes and subsequent drawing at a speed of up to about 1500 meters per minute to provide a draw ratio of at least 1.5 up to 5:1 to produce a continuous fiber having high tenacity of about 3.5 grams per denier and greater and good hand.
摘要翻译：在由金属茂催化剂存在下产生的C2，C4，C5，C6，C7或C8-α-烯烃单体的全同立构丙烯共聚物拉伸的纤维产物，其特征在于桥联的手性和立体刚性环戊二烯基或取代的环戊二烯基配体结构的过渡选自元素周期表第4b，5b或6b族金属的金属，该共聚物的MFR小于35，合适地为约30或更小。将共聚物加热至熔融状态并挤出以形成纤维预制件。以每分钟至少300米的纺丝速度进行纺丝，随后以高达约1500米/分钟的速度拉伸，以提供至少1.5至5:1的拉伸比，以产生连续纤维具有约3.5克/旦的高韧性和较好的手。

2. 发明申请

US20110253596A1 Regenerable Composite Catalysts for Paraffin Aromatization 审中-公开
标题翻译：可再生复合催化剂用于石蜡芳构化
公开(公告)号：US20110253596A1
公开(公告)日：2011-10-20
申请号：US12763279
申请日：2010-04-20
申请人： Olga Khabashesku , James R. Butler , Darek Wachowicz , Callum Bailey
发明人： Olga Khabashesku , James R. Butler , Darek Wachowicz , Callum Bailey
IPC分类号： C10G35/06 , B01J29/04
CPC分类号： C10G35/06 , B01J21/08 , B01J23/06 , B01J23/08 , B01J23/36 , B01J29/06 , B01J29/40 , B01J29/90 , B01J35/0006 , B01J35/023 , B01J38/10 , B01J2229/42
摘要： A composite catalyst for aromatization of paraffins includes a molecular sieve catalyst and metal dehydrogenation catalyst present as discrete catalysts in a physical admixture. The molecular sieve catalyst can be a zeolite and the metal dehydrogenation catalyst can be in the form of a nanoctructure, such as zinc oxide nanopowder. The catalyst can convert feedstocks such as LPG to aromatics and can be regenerated in-situ.
摘要翻译：用于烷烃芳族化的复合催化剂包括作为物理混合物中的离散催化剂存在的分子筛催化剂和金属脱氢催化剂。分子筛催化剂可以是沸石，金属脱氢催化剂可以是纳米结构的形式，如氧化锌纳米粉末。催化剂可以将原料如LPG转化为芳族化合物，并且可以原位再生。

3. 发明申请

US20100185035A1 Nb/Mordenite Transalkylation Catalyst 审中-公开
标题翻译： Nb /丝光沸石烷基转移催化剂
公开(公告)号：US20100185035A1
公开(公告)日：2010-07-22
申请号：US12748953
申请日：2010-03-29
申请人： James Butler , Olga Khabashesku , Darek Wachowicz , Callum Bailey
发明人： James Butler , Olga Khabashesku , Darek Wachowicz , Callum Bailey
IPC分类号： C07C5/52 , B01J29/076 , B01J29/26
CPC分类号： B01J29/076 , B01J29/26 , C07C6/123 , C07C2529/26 , Y02P20/52 , Y02P20/588 , C07C15/06 , C07C15/04
摘要： A niobium-modified mordenite catalyst can be made from water soluble niobium precursors such as niobium oxalate and ammonium niobate(V) oxalate and can be used in toluene disproportionation reactions. Embodiments can provide a toluene conversion of at least 30 wt % of the toluene feed with selectivity to benzene above 40 wt % of the reaction product composition and to xylenes above 40 wt % of the reaction product composition and non-aromatics selectivity of less than 1.0 wt % of the reaction product composition.
摘要翻译：铌改性的丝光沸石催化剂可以由草酸铌和铌酸铌酸盐（V）等水溶性铌前体制成，可用于甲苯歧化反应。实施方案可以提供至少30重量％的甲苯进料的甲苯转化率，对于反应产物组合物的40重量％以上的苯的选择性以及反应产物组合物的40重量％以上的二甲苯和小于1.0的非芳烃选择性 wt％的反应产物组合物。

4. 发明授权

US08546287B2 Rhenium promoted catalyst 有权
标题翻译：铼促进催化剂
公开(公告)号：US08546287B2
公开(公告)日：2013-10-01
申请号：US12790917
申请日：2010-05-31
申请人： James Butler , Olga Khabashesku , Darek Wachowicz , Callum Bailey
发明人： James Butler , Olga Khabashesku , Darek Wachowicz , Callum Bailey
IPC分类号： B01J29/06 , B01J27/182
CPC分类号： B01J29/85 , B01J29/076 , B01J29/16 , B01J29/26 , B01J29/83 , B01J29/90 , B01J37/0203 , B01J38/10 , B01J38/12 , B01J38/14 , B01J2229/20 , C07C6/06 , C07C6/12 , C07C2523/20 , C07C2523/36 , C07C2529/06 , C07C2529/08 , C07C2529/18 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C15/04 , C07C15/08
摘要： A group V metal/rhenium-modified molecular sieve catalyst can be used in hydrocarbon conversion reactions. Embodiments can provide a toluene conversion of at least 30 wt % with selectivity to benzene above 40 wt % and to xylenes above 40 wt % and non-aromatics selectivity of less than 2.0 wt %.
摘要翻译： V族金属/铼改性分子筛催化剂可用于烃转化反应。实施方案可以提供至少30重量％的甲苯转化率，对苯高于40重量％的选择性和高于40重量％的二甲苯和小于2.0重量％的非芳族选择性。

5. 发明申请

US20110295048A1 Rhenium Promoted Catalyst 有权
标题翻译：铼促销催化剂
公开(公告)号：US20110295048A1
公开(公告)日：2011-12-01
申请号：US12790917
申请日：2010-05-31
申请人： James Butler , Olga Khabashesku , Darek Wachowicz , Callum Bailey
发明人： James Butler , Olga Khabashesku , Darek Wachowicz , Callum Bailey
IPC分类号： B01J29/22 , C07C4/18 , B01J21/12
CPC分类号： B01J29/85 , B01J29/076 , B01J29/16 , B01J29/26 , B01J29/83 , B01J29/90 , B01J37/0203 , B01J38/10 , B01J38/12 , B01J38/14 , B01J2229/20 , C07C6/06 , C07C6/12 , C07C2523/20 , C07C2523/36 , C07C2529/06 , C07C2529/08 , C07C2529/18 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C15/04 , C07C15/08
摘要： A group V metal/rhenium-modified molecular sieve catalyst can be used in hydrocarbon conversion reactions. Embodiments can provide a toluene conversion of at least 30 wt % with selectivity to benzene above 40 wt % and to xylenes above 40 wt % and non-aromatics selectivity of less than 2.0 wt %.
摘要翻译： V族金属/铼改性分子筛催化剂可用于烃转化反应。实施方案可以提供至少30重量％的甲苯转化率，对苯高于40重量％的选择性和高于40重量％的二甲苯和小于2.0重量％的非芳族选择性。

6. 发明申请

US20100022813A1 Process for Reducing Ethylbenzene Content from an Aromatic Stream 审中-公开
标题翻译：从芳香流中还原乙苯含量的方法
公开(公告)号：US20100022813A1
公开(公告)日：2010-01-28
申请号：US12181276
申请日：2008-07-28
申请人： James R. Butler , Joseph E. Pelati , Darek Wachowicz , Taylor Rives , Xin Xiao
发明人： James R. Butler , Joseph E. Pelati , Darek Wachowicz , Taylor Rives , Xin Xiao
IPC分类号： C07C1/00 , C07C5/52
CPC分类号： C07C6/123 , C07C5/2708 , C07C2529/08 , C07C2529/24 , C07C2529/70 , C10G2400/30 , C07C15/08
摘要： A method of reducing the ethylbenzene content in a stream containing xylene is disclosed. The method includes the reaction of ethylbenzene, such as a disproportionation or transalkylation reaction, to produce benzene and other hydrocarbon compound and can include the separation of at least a portion of the resulting benzene and other hydrocarbon compounds to produce a xylene stream having reduced ethylbenzene content.
摘要翻译：公开了一种降低含二甲苯的流中的乙苯含量的方法。该方法包括乙苯的反应，例如歧化或烷基转移反应，以产生苯和其他烃化合物，并且可以包括至少部分所得苯和其它烃化合物的分离，以产生具有降低的乙苯含量的二甲苯料流。

7. 发明申请

US20060240733A1 Fibers and fabrics prepared from blends of homopolymers and copolymers 审中-公开
标题翻译：由均聚物和共聚物共混物制成的纤维和织物
公开(公告)号：US20060240733A1
公开(公告)日：2006-10-26
申请号：US11114352
申请日：2005-04-25
申请人： John Bieser , Mike McLeod , Darek Wachowicz
发明人： John Bieser , Mike McLeod , Darek Wachowicz
IPC分类号： D04H1/00 , D04H3/00 , D04H1/56 , D04H3/16
CPC分类号： D01F6/46 , D04H1/56 , D04H3/16 , Y10T428/2904 , Y10T428/2913 , Y10T442/68 , Y10T442/681 , Y10T442/696
摘要： A fiber comprising a propylene polymer composition is disclosed. The composition comprises a resin blend of from about 75 to about 95 weight percent of a Ziegler-Natta or metallocene catalyzed isotactic polypropylene homopolymer, and from about 95 to about 75 weight percent of a metallocene catalyzed polypropylene copolymer. In this blend the copolymer component includes a comonomer in an amount from about 0.05 to about 25 weight percent, based on the copolymer. Non-woven fabrics prepared by thermally bonding the inventive fibers show improved tensile strengths, particularly machine direction, at comparable basis weights that are at least about 5 percent higher than those of fabrics prepared using identical preparation techniques but from the isotactic polypropylene homopolymer alone.
摘要翻译：公开了一种包含丙烯聚合物组合物的纤维。组合物包含约75至约95重量％的齐格勒 - 纳塔或茂金属催化的全同立构聚丙烯均聚物和约95至约75重量％的金属茂催化的聚丙烯共聚物的树脂共混物。在该混合物中，基于共聚物，共聚物组分包括约0.05至约25重量％的量的共聚单体。通过热粘合本发明的纤维制备的无纺织物显示出提高的拉伸强度，特别是机器方向，其比例比使用相同制备技术制备的织物至少高约5％，但是来自全同立构聚丙烯均聚物。

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