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    • 5. 发明授权
    • Process for reducing the sulfur content of a crude
    • 降低原油硫含量的方法
    • US5310479A
    • 1994-05-10
    • US956186
    • 1992-10-05
    • Costandi A. Audeh
    • Costandi A. Audeh
    • C10G27/12C10G19/02
    • C10G27/12
    • A process for reducing the aliphatic sulfur content of a crude oil in a production site is disclosed. A crude oil with a high aliphatic sulfur content is treated at ambient reaction temperature with an oxidant which comprises formic acid and hydrogen peroxide. Preferably, the crude is treated with an amount of the oxidant of about 2 moles of oxidant for each mole of aliphatic sulfur in the crude. Preferably reaction temperature ranges from about 30.degree. F. to 100.degree. F. The oxidant converts the aliphatic sulfur compounds of the crude to a water soluble phase which is separated from the crude oil in a water wash.
    • 公开了一种降低生产部位原油脂肪族硫含量的方法。 具有高脂肪族硫含量的原油在环境反应温度下与含有甲酸和过氧化氢的氧化剂一起处理。 优选地,将粗产物用粗氧化剂中每摩尔脂族硫的约2摩尔氧化剂的量的氧化剂处理。 优选的反应温度范围为约30°F至100°F。氧化剂将粗品的脂族硫化合物转化成水溶性相,其在水洗中与原油分离。
    • 6. 发明授权
    • HF alkylation unit with additive dispenser
    • 带有添加剂分配器的HF烷基化单元
    • US5114675A
    • 1992-05-19
    • US489986
    • 1990-03-07
    • Saverio G. GrecoCostandi A. Audeh
    • Saverio G. GrecoCostandi A. Audeh
    • C01B7/19
    • C01B7/191
    • An HF alkylation unit incorporates a source of a proton acceptor additive which may be added to the HF alkylation acid in the event of a release of acid from the unit. The addition of the proton acceptor to the acid alters the character of HF droplets in an HF cloud to make them more easily treated by a simple water drench. The proton acceptor is maintained in a pressurized container in the unit and is connected to the reaction section of the unit by way of additive release valves under the control of an emergency controller which opens the valves and permits the additive to enter the reaction section of the unit and mix with the acid to modify its characteristics. The container may be connected to the major acid-containing process vessels in the unit, specifically the acid settler and the acid cooler (in a gravity flow unit) or the acid settler and the reactor (in a pump-around unit).
    • HF烷基化单元包含质子受体添加剂的源,其可以在从该单元释放酸的情况下加入到HF烷基化酸中。 向酸中添加质子受体可以改变高频云中的HF液滴的特性,使其更容易通过简单的水浸剂进行处理。 质子受体保持在该单元中的加压容器中,并通过添加剂释放阀在紧急控制器的控制下连接到单元的反应部分,该应急控制器打开阀门并允许添加剂进入反应段 单位与酸混合以改变其特性。 容器可以连接到单元中的主要含酸处理容器,特别是酸沉降器和酸冷却器(在重力流动单元中)或酸沉降器和反应器(在泵送单元中)。