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1. 发明授权

US5070053A FCC catalyst composition and method of making same 失效
标题翻译： FCC催化剂组合物及其制备方法
公开(公告)号：US5070053A
公开(公告)日：1991-12-03
申请号：US631561
申请日：1990-12-21
申请人： Claude C. Culross , Gordon F. Stuntz , William E. Winter, Jr.
发明人： Claude C. Culross , Gordon F. Stuntz , William E. Winter, Jr.
IPC分类号： B01J21/12 , B01J37/00 , B01J37/02 , C10G11/04 , C10G11/05
CPC分类号： C10G11/05 , B01J21/12 , B01J37/0018 , B01J37/02 , C10G11/04
摘要： Disclosed is a FCC catalyst composite, and a method of making said composite comprised of an alumina-on-silica additive, an inorganic refractory oxide, and optionally a zeolite material.
摘要翻译：公开了一种FCC催化剂复合材料，以及由氧化铝 - 二氧化硅添加剂，无机难熔氧化物和任选的沸石材料制成所述复合材料的方法。

2. 发明授权

US5026475A Coal hydroconversion process comprising solvent extraction (OP-3472) 失效
标题翻译：包括溶剂萃取的煤加氢转化法（OP-3472）
公开(公告)号：US5026475A
公开(公告)日：1991-06-25
申请号：US455654
申请日：1989-12-21
申请人： Gordon F. Stuntz , Claude C. Culross , Steve D. Reynolds
发明人： Gordon F. Stuntz , Claude C. Culross , Steve D. Reynolds
IPC分类号： C10G1/00
CPC分类号： C10G1/00 , C10G1/006
摘要： An improved process for the hydroconversion of coal comprising pretreating coal in an aqueous carbon monoxide-containing environment, followed by extracting a soluble hydrocarbon material from the coal, and subsequently hydroconverting the extracted material in a hydroconversion reactor. The extracted material consists of a relatively hydrogen-rich material which is readily converted to valuable liquid products in high yield. The residue from the extraction stage is relatively hydrogen deficient material which can be gasified to produce hydrogen and carbon monoxide for the hydroconversion and pretreatment stages, respectively.
摘要翻译：一种用于煤的加氢转化的改进方法，包括在含一氧化碳的环境中预处理煤，然后从煤中提取可溶性烃材料，随后在加氢转化反应器中将提取的材料进行加氢转化。提取的材料由相对富含氢的材料组成，其容易以高产率转化为有价值的液体产品。来自萃取阶段的残余物是相对缺水的物质，其可以气化以分别产生用于加氢转化和预处理阶段的氢气和一氧化碳。

3. 发明授权

US5074990A Fluid catalytic cracking using catalysts containing an alumina-on-silica component 失效
标题翻译：使用含有氧化铝 - 二氧化硅组分的催化剂进行流化催化裂化
公开(公告)号：US5074990A
公开(公告)日：1991-12-24
申请号：US543503
申请日：1990-06-25
申请人： Claude C. Culross , Gordon F. Stuntz , William E. Winter
发明人： Claude C. Culross , Gordon F. Stuntz , William E. Winter
IPC分类号： B01J21/12 , B01J29/08 , B01J37/00 , B01J37/02 , C10G11/04 , C10G11/05
CPC分类号： B01J37/0018 , B01J21/12 , B01J37/02 , C10G11/04 , C10G11/05
摘要： Disclosed is a fluid catalytic cracking process using a catalyst composite comprised of an alumina-on-silica material, an inorganic refractory oxide, and optionally a zeolite material. The alumina-on-silica material is comprised of silica particles with surface bound aluminum groups chemically bonded to the silica surface through surface oxygen atoms, which material is dispersed in a matrix of a refractory oxide.
摘要翻译：公开了使用由氧化铝 - 二氧化硅材料，无机耐火氧化物和任选的沸石材料组成的催化剂复合物的流化催化裂化方法。氧化铝 - 二氧化硅材料由具有表面结合的铝基团的二氧化硅颗粒组成，其通过表面氧原子化学键合到二氧化硅表面，该材料分散在难熔氧化物的基质中。

4. 发明申请

US20110152062A1 DRYING DEVICE FOR PRODUCING SMALL QUANTITIES OF CONTROLLED PARTICLE SIZE CATALYSTS WHICH ARE APPROPRIATE FOR USE IN FLUIDIZED BED OPERATIONS SUCH AS FLUID CATALYTIC CRACKING 审中-公开
标题翻译：用于生产适用于流化床操作的受控粒度催化剂的小量数量的干燥装置，如流体催化裂化
公开(公告)号：US20110152062A1
公开(公告)日：2011-06-23
申请号：US12957817
申请日：2010-12-01
申请人： William A. Wachter , Brenda A. Raich , Theodore E. Datz , David O. Marler , Nicholas Rollman , Jeffrey T. Elks , Gordon F. Stuntz
发明人： William A. Wachter , Brenda A. Raich , Theodore E. Datz , David O. Marler , Nicholas Rollman , Jeffrey T. Elks , Gordon F. Stuntz
IPC分类号： B01J37/08 , B01J37/10 , B01J35/10 , B01J31/06 , B01J29/04
CPC分类号： B01J29/06 , B01J29/70 , B01J37/0018 , B01J37/0072 , B01J37/0236 , B01J37/08 , B01J2229/36 , B01J2229/42 , C10G11/05
摘要： Catalysts for experimentation are produced having a controlled matrix pore structure. The manufacturing process utilizes tape casting in the drying procedure in which a catalyst slurry is cast on a substrate and dried at a temperature of between about 50° C. to 200° C. for a period of time of about 0.1 to 1.0 hour. The dried catalyst particles can be removed from the substrate by several techniques, including scraping, burning, and deforming the substrate material, The resulting catalytic particles can be produced in an amount of about ca. 3 g to 300 g from slurries with volumes between 5 cc to 500 cc, which are suitable for small scale FCC reactors and for high throughput experimentation.
摘要翻译：生产具有受控矩阵孔结构的用于实验的催化剂。制造方法在干燥过程中使用带铸造，其中将催化剂浆料浇铸在基材上并在约50℃至200℃的温度下干燥约0.1至1.0小时的时间。干燥的催化剂颗粒可以通过几种技术从基材中除去，包括刮擦，燃烧和使基材变形。所得到的催化剂颗粒可以以约约 3克至300克，体积在5毫升至500毫升之间的浆料，适用于小规模的FCC反应器和高通量实验。

5. 发明授权

US07435335B1 Production of low sulfur distillates 有权
标题翻译：生产低硫馏分
公开(公告)号：US07435335B1
公开(公告)日：2008-10-14
申请号：US09553107
申请日：2000-04-20
申请人： Edward S. Ellis , William E. Lewis , Larry L. Iaccino , Michele S. Touvelle , Gordon F. Stuntz
发明人： Edward S. Ellis , William E. Lewis , Larry L. Iaccino , Michele S. Touvelle , Gordon F. Stuntz
IPC分类号： C10G45/00 , C10G45/44
CPC分类号： C10G65/12
摘要： A process for hydroprocessing a distillate stream to produce a stream exceptionally low in sulfur, with total aromatics and polynuclear aromatics being moderately reduced. A distillate stream is hydrodesulfurized in a first hydrodesulfurization stage. The product stream thereof is passed to a first separation stage wherein a vapor phase product stream and a liquid product stream are produced. The liquid phase product stream is passed to a second hydrodesulfurization stage and the product stream thereof is passed to a second separation stage wherein a vapor phase product stream and a liquid product stream low in sulfur are produced. At least a portion of the vapor product stream from said second separation stage can be cascaded to the first hydrodesulfurization stage.
摘要翻译：用于加氢处理馏出物流以产生异常低硫的流的方法，其中芳族化合物和多环芳烃被适度地还原。馏出物流在第一加氢脱硫阶段加氢脱硫。其产物流被送到第一分离阶段，其中产生气相产物流和液体产物流。将液相产物流送至第二加氢脱硫阶段，将其产物流送至第二分离阶段，其中产生气相产物流和硫含量低的液体产物流。来自所述第二分离级的至少一部分蒸汽产物流可以级联到第一加氢脱硫阶段。

6. 发明授权

US06803494B1 Process for selectively producing propylene in a fluid catalytic cracking process 失效
标题翻译：在流化催化裂化过程中选择性生产丙烯的方法
公开(公告)号：US06803494B1
公开(公告)日：2004-10-12
申请号：US09574261
申请日：2000-05-19
申请人： Paul K. Ladwig , John E. Asplin , Gordon F. Stuntz , William A. Wachter , Brian Erik Henry , Shun C. Fung
发明人： Paul K. Ladwig , John E. Asplin , Gordon F. Stuntz , William A. Wachter , Brian Erik Henry , Shun C. Fung
IPC分类号： C07C406
CPC分类号： C10G51/023 , C10G11/18 , C10G51/026 , C10G57/02 , C10G2400/20
摘要： A process for producing polypropylene from olefins selectively produced from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha stream is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures from about 500° C. to 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia. The catalyst may be pre-coked with a carbonaceous feed. Alternatively, the carbonaceous feed used to coke the catalyst may be co-fed with the naphtha feed.
摘要翻译：本文公开了从催化裂化或热裂化石脑油流选择性地生产的烯烃生产聚丙烯的方法。将石脑油流与含有约10至50wt。在包括约500℃至650℃的温度和约10至40psia的烃分压的反应条件下，平均孔径小于约0.7纳米的结晶沸石的％。催化剂可以用碳质进料预结焦。或者，用于焦化催化剂的碳质原料可以与石脑油进料共同进料。

7. 发明授权

US06315890B1 Naphtha cracking and hydroprocessing process for low emissions, high octane fuels 失效
标题翻译：用于低排放，高辛烷值燃料的石脑油裂解和加氢处理方法
公开(公告)号：US06315890B1
公开(公告)日：2001-11-13
申请号：US09436660
申请日：1999-11-10
申请人： Paul K. Ladwig , Gordon F. Stuntz , Garland B. Brignac , Thomas R. Halbert
发明人： Paul K. Ladwig , Gordon F. Stuntz , Garland B. Brignac , Thomas R. Halbert
IPC分类号： C10G6904
CPC分类号： C10G51/023 , C10G57/02 , C10G69/04 , C10G69/06 , C10G2400/20
摘要： The invention is related to a two step process wherein the first step comprises cracking an olefinic naphtha resulting in a cracked product having a diminished total concentration of olefinic species. The second step comprises hydroprocessing at least a portion of the cracked product, especially a naphtha fraction, to provide a hydroprocessed cracked product having a reduced concentration of contaminant species but without a substantial octane reduction.
摘要翻译：本发明涉及两步法，其中第一步骤包括裂化烯烃石脑油，产生具有减少的烯属物质总浓度的裂化产物。第二步骤包括对至少一部分裂化产物，特别是石脑油馏分进行加氢处理，以提供具有降低的污染物质浓度但没有显着辛烷值降低的加氢裂化产物。

8. 发明授权

US5320746A Process for recovering oil from tar sands 失效
标题翻译：从焦油砂中回收油的工艺
公开(公告)号：US5320746A
公开(公告)日：1994-06-14
申请号：US608130
申请日：1990-11-01
申请人： Robert C. Green , Gordon F. Stuntz , Russell J. Koveal
发明人： Robert C. Green , Gordon F. Stuntz , Russell J. Koveal
IPC分类号： C10G1/00 , C10G1/04
CPC分类号： C10G1/047 , C10G1/002
摘要： A process for recovering oil from tar sands by subjecting the tar sands to aqueous extraction to produce a bitumen-rich layer containing bitumen, water and solids and a bitumen-lean layer containing relatively less bitumen and relatively more water and solids. The solids present in the bitumen-lean layer contain a substantial portion of finely divided clay having adhered organic matter. The clay solids are retained with the bitumen from the bitumen-lean layer and the bitumen-clay mixture is pyrolyzed. Pyrolysis of the bitumen-lean layer containing clay having adhered organic matter reduces the volume of aqueous tailings which would otherwise be produced and also results in increased hydrocarbon yields.
摘要翻译：通过对焦油砂进行含水萃取以产生含有沥青，水和固体的沥青富含层以及含有相对较少的沥青和相对较多的水和固体的沥青贫层，从沥青砂中回收油的方法。存在于贫沥青层中的固体含有大部分具有粘附有机物质的细碎粘土。粘土固体与贫沥青层的沥青一起保留，沥青 - 粘土混合物被热解。含有附着有机物质的含有粘土的贫沥青层的热解减少了否则将产生的含水尾矿的体积，并且还导致增加的烃产率。

9. 发明授权

US4504380A Passivation of metal contaminants in cat cracking 失效
标题翻译：猫裂纹中金属污染物的钝化
公开(公告)号：US4504380A
公开(公告)日：1985-03-12
申请号：US525826
申请日：1983-08-23
申请人： Gordon F. Stuntz , Terry A. Reid
发明人： Gordon F. Stuntz , Terry A. Reid
IPC分类号： C10G11/04 , C10G11/18 , C10G11/00
CPC分类号： C10G11/04 , C10G11/18 , Y10S502/521
摘要： A method for passivating metal contaminants present in a hydrocarbon feedstock which become deposited on cracking catalyst is described. The method is directed at passing the cracking catalyst through a passivation zone having a reducing atmosphere maintained at an elevated temperature by the introduction of a process reducing gas. The unsaturated hydrocarbon content of the reducing gas is decreased prior to the introduction of the process reducing gas into the passivation zone to thereby lower the rate of coke formation. In a preferred embodiment process reducing gas is passed through a hydrogenation zone adapted to hydrogenate an unsaturated hydrocarbon present in the process reducing gas prior to the process reducing gas being added to the passivation zone.
摘要翻译：描述了一种钝化沉积在裂化催化剂上的烃原料中存在的金属污染物的方法。该方法涉及通过引入工艺还原气体使裂化催化剂通过具有保持在高温下的还原气氛的钝化区。在将工艺还原气体引入钝化区之前，还原气体的不饱和烃含量降低，从而降低焦炭形成速率。在一个优选的实施方案中，还原气体通过适于在工艺中存在的不饱和烃氢化的氢化区，还原气体在还原气体被加入钝化区之前。

10. 发明授权

US4370220A Process for reducing coke formation in heavy feed catalytic cracking 失效
标题翻译：重质进料催化裂化中焦炭形成减少的方法
公开(公告)号：US4370220A
公开(公告)日：1983-01-25
申请号：US285817
申请日：1981-07-22
申请人： Roby Bearden , Gordon F. Stuntz
发明人： Roby Bearden , Gordon F. Stuntz
IPC分类号： B01J21/20 , B01J29/90 , C10G11/02 , C10G11/18 , C10G9/16
CPC分类号： B01J29/90 , B01J21/20 , C10G11/02 , C10G11/187
摘要： A method for decreasing the amount of hydrogen and coke produced during the cracking of hydrocarbon feedstock to lower molecular weight products in a reaction zone is disclosed, where the feedstock contains at least one metal contaminant selected from the class consisting of nickel, vanadium and iron and where the contaminant becomes deposited on the catalyst such that at least 50 wt. % of the total of the metal contaminants comprises only one of the metal contaminants. The method comprises monitoring the composition of the metal contaminant on the catalyst, adding an effective passivating amount of at least one of the metal contaminants which is not the major contaminant on the catalyst and passing catalyst from the reaction zone through a regeneration zone operated under net reducing conditions and through a reduction zone maintained at an elevated temperature.
摘要翻译：公开了一种在反应区中将烃原料裂解成较低分子量产物时产生的氢和焦炭的量减少的方法，其中原料含有至少一种选自镍，钒和铁的金属污染物，其中污染物沉积在催化剂上，使得至少50wt。金属污染物总量的百分比仅包括一种金属污染物。该方法包括监测催化剂上的金属污染物的组成，在催化剂上添加不是主要污染物的至少一种金属污染物的有效钝化量，并将催化剂从反应区通过在网下运行的再生区并且通过保持在高温下的还原区。

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