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1. 发明授权

US6136868A Preparation of high activity catalysts; the catalysts and their use 有权
标题翻译：制备高活性催化剂; 催化剂及其用途
公开(公告)号：US6136868A
公开(公告)日：2000-10-24
申请号：US153363
申请日：1998-09-15
申请人： Claude C. Culross , Charles H. Mauldin
发明人： Claude C. Culross , Charles H. Mauldin
IPC分类号： B01J23/75 , B01J23/889 , B01J37/02 , C07B61/00 , C07C1/04 , C07C9/14 , C10G2/00 , C07C27/00
CPC分类号： C10G2/332 , B01J23/75 , B01J23/8896 , B01J37/0203 , C07C1/0445 , C07C1/0485 , C07C2521/06 , C07C2521/08 , C07C2523/36 , C07C2523/75 , C07C2523/889 , Y10S502/506 , Y10S502/514
摘要： A process for the preparation of a catalyst useful for conducting carbon monoxide conversion reactions, especially a Fischer-Tropsch catalyst, use of the catalyst for conducting such reactions, especially Fischer-Tropsch reactions, and the composition produced by said process. In the preparation of the catalyst, a solution of a carbohydrate, or sugar, notably a monosaccharide or disaccharide, particularly sucrose, is employed to impregnate and disperse a compound or salt of a catalytic metal, or metals, e.g., copper or an Iron Group metal such as iron, cobalt, or nickel, or in a preferred embodiment both a compound or salt of rhenium and a compound or salt of a catalytic metal, or metals, e.g., copper or an Iron Group metal such as iron, cobalt, or nickel, onto a refractory inorganic oxide support, e.g., titania. The rhenium, when present only in small amount permits full and complete reduction of the catalytic metal, or metals, dispersed by the carbohydrate. Higher catalyst activities with lower rhenium loadings are thus achieved than in previous preparations where higher concentrations of rhenium were required to both effectively disperse, and reduce the catalytic metal, or metals, during the preparation. Surprisingly, as little as about 1/10 of the rhenium is required to accomplish the reduction promotion where the dispersion is effected with the carbohydrate.
摘要翻译：用于制备用于进行一氧化碳转化反应的催化剂，特别是费 - 托催化剂的方法，所述催化剂用于进行这种反应，特别是费 - 托反应，以及由所述方法制备的组合物。在催化剂的制备中，使用碳水化合物或糖，特别是单糖或二糖，特别是蔗糖的溶液来浸渍和分散催化金属或金属例如铜或铁组的化合物或盐金属如铁，钴或镍，或在优选的实施方案中，铼的化合物或盐和催化金属的化合物或盐，或金属，例如铜或铁族金属如铁，钴或镍，添加到耐火无机氧化物载体上，例如二氧化钛。铼当仅存在少量时，允许完全和完全地还原由碳水化合物分散的催化金属或金属。因此实现了较低的铼负载量的较高催化剂活性，而不需要较高浓度的铼在制备期间有效地分散和还原催化金属或金属的以前制备。令人惊奇的是，只要大约+ E，需要铼的1/10 + EE即可完成使用碳水化合物进行分散的还原促进。

2. 发明授权

US5856261A Preparation of high activity catalysts; the catalysts and their use 失效
公开(公告)号：US5856261A
公开(公告)日：1999-01-05
申请号：US847957
申请日：1997-04-22
申请人： Claude C. Culross , Charles H. Mauldin
发明人： Claude C. Culross , Charles H. Mauldin
IPC分类号： B01J23/75 , B01J23/889 , B01J37/02 , C07B61/00 , C07C1/04 , C07C9/14 , C10G2/00 , B01J23/00 , B01J23/70 , B01J23/72 , C07C27/00
CPC分类号： C10G2/332 , B01J23/75 , B01J23/8896 , B01J37/0203 , C07C1/0445 , C07C1/0485 , C07C2521/06 , C07C2521/08 , C07C2523/36 , C07C2523/75 , C07C2523/889 , Y10S502/506 , Y10S502/514
摘要： A process for the preparation of a catalyst useful for conducting carbon monoxide conversion reactions, especially a Fischer-Tropsch catalyst, use of the catalyst for conducting such reactions, especially Fischer-Tropsch reactions, and the composition produced by said process. In the preparation of the catalyst, a solution of a carbohydrate, or sugar, notably a monosaccharide or disaccharide, particularly sucrose, is employed to impregnate and disperse a compound or salt of a catalytic metal, or metals, e.g., copper or an Iron Group metal such as iron, cobalt, or nickel, or in a preferred embodiment both a compound or salt of rhenium and a compound or salt of a catalytic metal, or metals, e.g., copper or an Iron Group metal such as iron, cobalt, or nickel, onto a refractory inorganic oxide support, e.g., titania. The rhenium, when present only in small amount permits full and complete reduction of the catalytic metal, or metals, dispersed by the carbohydrate. Higher catalyst activities with lower rhenium loadings are thus achieved than in previous preparations where higher concentrations of rhenium were required to both effectively disperse, and reduce the catalytic metal, or metals, during the preparation. Surprisingly, as little as about 1/10 of the rhenium is required to accomplish the reduction promotion where the dispersion is effected with the carbohydrate.

3. 发明授权

US08057572B2 Metal recovery 有权
标题翻译：金属回收
公开(公告)号：US08057572B2
公开(公告)日：2011-11-15
申请号：US12322792
申请日：2009-02-06
申请人： Charles H. Mauldin
发明人： Charles H. Mauldin
IPC分类号： B01J38/60 , B22F9/04
CPC分类号： B01J23/8896 , B01J21/063 , B01J37/0045 , B01J37/0205 , C22B3/065 , C22B7/007 , C22B7/009 , C22B11/048 , C22B23/026 , Y02P10/214 , Y02P10/224 , Y02P10/234
摘要： A method is provided for recovering rhenium from a titania-supported, rhenium-containing catalyst by treating the catalyst in the reduced form with an acid in an amount and for a time sufficient to dissolve the rhenium without dissolving the support.
摘要翻译：提供了一种从二氧化钛负载的含铼催化剂中回收铼的方法，通过用足够量的溶解铼而不溶解载体的酸处理还原形式的催化剂。

4. 发明授权

US06319960B1 Method for hydrocarbon synthesis reactions 失效
标题翻译：烃合成反应方法
公开(公告)号：US06319960B1
公开(公告)日：2001-11-20
申请号：US07118619
申请日：1987-11-06
申请人： William C. Behrmann , Kym B. Arcuri , Charles H. Mauldin , Mordechay Herskowitz
发明人： William C. Behrmann , Kym B. Arcuri , Charles H. Mauldin , Mordechay Herskowitz
IPC分类号： C07C2706
CPC分类号： B01J37/0232 , B01J23/75 , B01J23/83 , B01J23/8896 , B01J23/8913 , C07C1/0435 , C07C1/0445 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/36 , C07C2523/46 , C07C2523/75 , C07C2523/83 , C07C2523/889
摘要： A method for hydrocarbon synthesis reactions from carbon monoxide and hydrogen using a catalyst pellet which includes a solid core and a coated layer of porous support impregnated with a catalyst which optimizes the CO conversion.
摘要翻译：一种使用催化剂颗粒从一氧化碳和氢气中进行碳氢化合物反应的方法，所述催化剂颗粒包括固体芯和浸渍有优化CO转化率的催化剂的多孔载体的涂层。

5. 发明授权

US4762959A Cobalt catalysts, and use thereof for the conversion of methanol and for Fischer-Tropsch synthesis, to produce hydrocarbons 失效
公开(公告)号：US4762959A
公开(公告)日：1988-08-09
申请号：US57302
申请日：1987-06-04
申请人： Charles H. Mauldin , Stephen M. Davis , Kym B. Arcuri
发明人： Charles H. Mauldin , Stephen M. Davis , Kym B. Arcuri
IPC分类号： B01J23/75 , B01J23/83 , C07C1/04 , C07C1/20 , C07C1/00
CPC分类号： C07C1/20 , B01J23/75 , B01J23/83 , C07C1/0435 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/75 , C07C2523/83 , Y02P20/52
摘要： A zirconium, hafnium, cerium or uranium promoted cobalt catalyst and process for the conversion of methanol or synthesis gas to hydrocarbons. Methanol is contacted, preferably with added hydrogen, over said catalyst, or synthesis gas is contacted over said catalyst to produce, at reaction conditions, an admixture of C.sub.10 + linear paraffins and olefins. These hydrocarbons can be further refined to high quality middle distillate fuels, and other valuable products such as mogas, diesel fuel, and jet fuel, particularly premium middle distillate fuels of carbon number ranging to about C.sub.20.

6. 发明授权

US4751345A Cobalt catalysts, and use thereof for the conversion of methanol to hydrocarbons, and for Fisher-Tropsch synthesis 失效
标题翻译：钴催化剂，以及其用于将甲醇转化成烃和用于费 - 托合成的用途
公开(公告)号：US4751345A
公开(公告)日：1988-06-14
申请号：US7493
申请日：1987-01-28
申请人： Charles H. Mauldin
发明人： Charles H. Mauldin
IPC分类号： B01J23/889 , C07C1/04 , C07C1/20 , C10G3/00 , C07C1/00
CPC分类号： B01J23/8896 , C07C1/0435 , C07C1/20 , C10G3/45 , C10G3/48 , C10G3/50 , C07C2521/06 , C07C2523/12 , C07C2523/36 , C07C2523/75 , C07C2523/83 , C07C2523/889 , C10G2300/1022 , C10G2300/4018 , C10G2400/04 , C10G2400/10 , C10G2400/18 , C10G2400/22 , Y02P30/20
摘要： A rhenium promoted cobalt catalyst, especially a rhenium and thoria promoted cobalt catalyst, and process for the conversion of methanol to hydrocarbons. Methanol is contacted, preferably with added hydrogen, over said catalyst, or synthesis gas is contacted over said catalyst to produce, at reaction conditions, an admixture of C.sub.10 + linear paraffins and olefins. These hydrocarbons can be further refined to high quality middle distillate fuels, and other valuable products such as mogas, diesel fuel, jet fuel, lubes and speciality solvents, particularly premium middle distillate fuels of carbon number ranging from about C.sub.10 to about C.sub.20.
摘要翻译：铼促进钴催化剂，特别是铼和硫堇促进的钴催化剂，以及甲醇转化为烃的方法。甲醇在所述催化剂上接触，优选与加入的氢气接触，或者合成气在所述催化剂上接触，以在反应条件下产生C10 +直链烷烃和烯烃的混合物。这些碳氢化合物可以进一步精制成高质量的中间馏分燃料，以及其他有价值的产品，如摩尔瓦，柴油，喷气燃料，润滑剂和特种溶剂，特别是碳数为约C10至约C20的优质中间馏分燃料。

7. 发明授权

US4513161A Conversion of methanol to hydrocarbons 失效
标题翻译：甲醇转化为碳氢化合物
公开(公告)号：US4513161A
公开(公告)日：1985-04-23
申请号：US626025
申请日：1984-06-29
申请人： Charles H. Mauldin
发明人： Charles H. Mauldin
IPC分类号： C10G3/00 , B01J23/00 , C07B61/00 , C07C1/00 , C07C1/20 , C07C9/00 , C07C67/00
CPC分类号： C07C1/20 , C07C2521/06 , C07C2523/46 , Y02P20/52 , Y02P30/20
摘要： A process wherein methanol is contacted, in the presence of hydrogen, over a ruthenium-titania catalyst to produce, at reaction conditions, an admixture of C.sub.10 + linear paraffin and olefins, which can be further refined and upgraded to high quality middle distillate fuels, and other valuable products such as mogas, diesel fuel, jet fuel, lubes, and specialty solvents, especially premium middle distillate fuels of carbon number ranging from about C.sub.10 to C.sub.20.
摘要翻译：一种方法，其中甲醇在氢气存在下在钌 - 二氧化钛催化剂上接触，以在反应条件下制备可以进一步精炼和升级为高质量中间馏分燃料的C 10 +线性链烷烃和烯烃的混合物，以及其他有价值的产品，如莫斯卡，柴油，喷气燃料，润滑剂和特种溶剂，特别是碳数高于C10至C20的优质中间馏分燃料。

8. 发明授权

US4303500A Reforming with multimetallic catalysts 失效
标题翻译：用多金属催化剂重整
公开(公告)号：US4303500A
公开(公告)日：1981-12-01
申请号：US206091
申请日：1980-11-12
申请人： Paul E. Eberly, Jr. , Charles H. Mauldin , William C. Baird, Jr.
发明人： Paul E. Eberly, Jr. , Charles H. Mauldin , William C. Baird, Jr.
IPC分类号： B01J23/89 , B01J27/057 , C10G35/09 , C10G35/085
CPC分类号： B01J23/8926 , B01J27/0573 , C10G35/09
摘要： A catalyst comprised of platinum, copper, selenium and halogen, composited with an inorganic oxide support or carrier, preferably alumina. The catalyst is one which possesses an intrinsically high activity, is stable and can operate at reforming conditions at high severities.
摘要翻译：由铂，铜，硒和卤素组成的催化剂，与无机氧化物载体或载体，优选氧化铝复合。该催化剂是具有本质上高活性的，稳定的并且能够在高浓度的重整条件下操作的催化剂。

9. 发明授权

US06331575B1 Preparation of high activity catalysts; the catalysts and their use 有权
标题翻译：制备高活性催化剂; 催化剂及其用途
公开(公告)号：US06331575B1
公开(公告)日：2001-12-18
申请号：US09153364
申请日：1998-09-15
申请人： Charles H. Mauldin
发明人： Charles H. Mauldin
IPC分类号： C07C2700
CPC分类号： B01J37/0203 , B01J23/8896 , B01J35/0066 , C07C1/0445 , C07C2523/36 , C07C2523/889 , Y10S502/506 , Y10S502/514
摘要： A process for the preparation of a catalyst useful for conducting carbon monoxide conversion reactions, especially a Fischer-Tropsch catalyst, use of the catalyst for conducting such reactions, especially Fischer-Tropsch reactions, and the composition produced by said process. In the preparation of the catalyst, a solution of a polyol is employed to impregnate and disperse a compound or salt of a catalytic metal, or metals, e.g., copper or an Iron Group metal such as iron, cobalt, or nickel, or in a preferred embodiment both a compound or salt of rhenium and a compound or salt of a catalytic metal, or metals, e.g., copper or an Iron Group metal such as iron, cobalt, or nickel onto a refractory inorganic oxide support, e.g., titania. The rhenium, when present only in small amount permits full and complete reduction of the catalytic metal, or metals, dispersed by the polyol. Higher catalyst activities with lower rhenium loadings are thus achieved than in previous preparations where higher concentrations of rhenium were required to both effectively disperse, and reduce the catalytic metal, or metals, during the preparation. Surprisingly, as little as about {fraction (1/10)} of the rhenium is required to accomplish the reduction promotion where the dispersion is effected with the polyol.
摘要翻译：用于制备用于进行一氧化碳转化反应的催化剂，特别是费 - 托催化剂的方法，所述催化剂用于进行这种反应，特别是费 - 托反应，以及由所述方法制备的组合物。在催化剂的制备中，使用多元醇溶液来浸渍和分散催化金属的化合物或盐，或金属，例如铜或铁族金属如铁，钴或镍，或在优选的实施方案是将铼的化合物或盐和催化金属的化合物或盐，或诸如铜或铁族金属如铁，钴或镍的金属加入耐火无机氧化物载体（例如二氧化钛）上。当仅存在少量的铼允许充分和完全地还原由多元醇分散的催化金属或金属。因此实现了较低的铼负载量的较高催化剂活性，而不需要较高浓度的铼在制备期间有效地分散和还原催化金属或金属的以前制备。令人惊奇的是，为了实现其中分散体与多元醇进行的还原促进，需要少至约{分数（1/10）}的铼。

10. 再颁专利

USRE37406E1 Surface supported cobalt catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas and process for the preparation of said catalysts 有权
标题翻译：表面负载的钴催化剂，利用这些催化剂从合成气中制备烃的方法和制备所述催化剂的方法
公开(公告)号：USRE37406E1
公开(公告)日：2001-10-09
申请号：US09133422
申请日：1998-08-13
申请人： William C. Behrmann , Kym B. Arcuri , Charles H. Mauldin
发明人： William C. Behrmann , Kym B. Arcuri , Charles H. Mauldin
IPC分类号： C07C2706
CPC分类号： B01J37/0221 , B01J23/75 , B01J23/83 , B01J23/8896 , B01J23/8913 , B01J35/008 , B01J37/0232 , C07C1/0435 , C07C1/0445 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/36 , C07C2523/46 , C07C2523/75 , C07C2523/83 , C07C2523/889
摘要： A supported particulate cobalt catalyst is formed by dispersing cobalt, alone or with a metal promoter, particularly rhenium, as a thin catalytically active film upon a particulate support, especially a silica or titania support. This catalyst can be used to convert an admixture of carbon monoxide and hydrogen to a distillate fuel constituted principally of an admixture of linear paraffins and olefins, particularly a C10+ distillate, at high productivity, with low methane selectivity. A process is also disclosed for the preparation of these catalysts.
摘要翻译：通过将单独或与金属促进剂，特别是铼作为薄催化活性的膜分散在颗粒载体上，特别是二氧化硅或二氧化钛载体上来形成负载的颗粒状钴催化剂。该催化剂可用于将一氧化碳和氢气的混合物转化为主要由线性链烷烃和烯烃，特别是C10 +馏出物的混合物组成的馏出物燃料，其生产率高，甲烷选择性低。还公开了制备这些催化剂的方法。

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