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1. 发明授权

US5627151A Use of vinylpyrrolidone copolymers as detergent additives, novel polymers of vinylpyrrolidone, and preparation thereof 失效
标题翻译：使用乙烯基吡咯烷酮共聚物作为洗涤剂添加剂，乙烯基吡咯烷酮的新型聚合物及其制备
公开(公告)号：US5627151A
公开(公告)日：1997-05-06
申请号：US325177
申请日：1995-04-21
申请人： Juergen Detering , Christian Schade , Wolfgang Trieselt , Juergen Tropsch
发明人： Juergen Detering , Christian Schade , Wolfgang Trieselt , Juergen Tropsch
IPC分类号： C08F2/10 , C08F26/00 , C08F26/10 , C08F226/06 , C08F226/10 , C08F289/00 , C11D3/00 , C11D3/37 , C11D3/28
CPC分类号： C11D3/3776 , C08F289/00 , C11D3/0021 , C11D3/3788
摘要： There are described the use of copolymers obtainable by free-radically initiated copolymerization of monomer mixtures comprising(a) 60-99% by weight of 1-vinylpyrrolidone, 1-vinylimidazole or mixtures thereof,(b) 1-40% by weight of nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of salts or in quaternized form, and optionally(c) up to 20% by weight of other monoethylenically unsaturated monomers,as detergent additives for inhibiting dye transfer during the wash, detergents which contain such polymers, and polymers which are obtainable by free-radically initiated polymerization of(a) 1-vinylpyrrolidone, 1-vinylimidazole, 1-vinylimidazolium compounds, or mixtures thereof, and optionally(b) other nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of the salts or in quaternized form, and/or(c) other monoethylenically unsaturated monomers,in an aqueous medium in the presence of water-soluble proteins and a process for the preparation of the polymers by polymerising the monomers (a) and optionally (b) and/or (c) in an aqueous medium in the presence of water-soluble proteins using from 0.5 to 400 parts by weight of protein per 100 parts by weight of monomer used in the polymerization.
摘要翻译： PCT No.PCT / EP93 / 02851 Sec。 371日期1995年04月21日 102（e）日期1995年4月21日PCT 1993年10月15日PCT公布。公开号WO94 / 10281 日本1994年5月11日描述了通过自由基引发的单体混合物共聚获得的共聚物的用途，所述共聚物包含（a）60-99重量％的1-乙烯基吡咯烷酮，1-乙烯基咪唑或其混合物，（b）1-40重量％重量的游离碱形式的含氮碱性烯键式不饱和单体，以盐形式或季铵化形式，和任选地（c）最多20％重量的其它单烯属不饱和单体作为洗涤剂添加剂，用作（a）1-乙烯基吡咯烷酮，1-乙烯基咪唑，1-乙烯基咪唑鎓化合物或其混合物，和任选地（b）可通过自由基引发的聚合获得的聚合物，在盐水介质中以盐形式或季铵化形式的其它含氮的碱性烯属不饱和单体，和/或（c）其它单烯属不饱和单体在水溶性蛋白质存在下，通过在水溶性蛋白质的存在下在水溶性介质中聚合单体（a）和任选地（b）和/或（c））来制备聚合物的方法，使用相对于聚合中使用的单体100重量份，为0.5〜400重量份的蛋白质。

2. 发明授权

US5846924A Use of vinylpyrrolidone and vinylimidazole copolymers as detergent additives, novel polymers of vinylpyrrolidone and of vinylimidazole, and preparation thereof 失效
标题翻译：使用乙烯基吡咯烷酮和乙烯基咪唑共聚物作为洗涤剂添加剂，乙烯基吡咯烷酮和乙烯基咪唑的新型聚合物及其制备
公开(公告)号：US5846924A
公开(公告)日：1998-12-08
申请号：US694023
申请日：1996-08-08
申请人： Juergen Detering , Christian Schade , Wolfgang Trieselt , Juergen Tropsch
发明人： Juergen Detering , Christian Schade , Wolfgang Trieselt , Juergen Tropsch
IPC分类号： C08F2/10 , C08F26/00 , C08F26/10 , C08F226/06 , C08F226/10 , C08F289/00 , C11D3/00 , C11D3/37 , C11D3/28
CPC分类号： C11D3/3776 , C08F289/00 , C11D3/0021 , C11D3/3788
摘要： There are described the use of copolymers obtainable by free-radically initiated copolymerization of monomer mixtures comprising (a) 60-99% by weight of 1-vinylpyrrolidone, 1-vinyl-imidazole or mixtures thereof, (b) 1-40% by weight of nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of salts or in quaternized form, and optionally (c) up to 20% by weight of other monoethylenically unsaturated monomers, as detergent additives for inhibiting dye transfer during the wash, detergents which contain such polymers, and polymers which are obtainable by free-radically initiated polymerization of (a) 1-vinylpyrrolidone, 1-vinylimidazole, 1-vinylimidazolium compounds, or mixtures thereof, and optionally (b) other nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of the salts or in quaternized form, and/or (c) other monoethylenically unsaturated monomers, in an aqueous medium in the presence of water-soluble proteins and a process for the preparation of the polymers by polymerising the monomers (a) and optionally (b) and/or (c) in an aqueous medium in the presence of water-soluble proteins using from 0.5 to 400 parts by weight of protein per 100 parts by weight of monomer used in the polymerization.
摘要翻译：描述了通过自由基引发的单体混合物共聚获得的共聚物的用途，所述单体混合物包含（a）60-99重量％的1-乙烯基吡咯烷酮，1-乙烯基 - 咪唑或其混合物，（b）1-40重量％的游离碱形式的含氮碱性烯键式不饱和单体，以盐形式或季铵化形式，以及任选地（c）至多20重量％的其它单烯属不饱和单体作为抑制染料的洗涤剂添加剂在洗涤期间的转移，含有这种聚合物的洗涤剂，以及可通过（a）1-乙烯基吡咯烷酮，1-乙烯基咪唑，1-乙烯基咪唑鎓化合物或其混合物和任选的（b）其他氮气的自由引发聚合而获得的聚合物含有游离碱形式的碱性烯属不饱和单体，以盐形式或季铵化形式，和/或（c）其它单烯键式不饱和单体，在预混物的水性介质中 ce的水溶性蛋白质的制备方法和通过在水溶性蛋白质的存在下在水溶液中使单体（a）和任选地（b）和/或（c）聚合而制备聚合物的方法，使用0.5至400 每100重量份聚合中使用的单体重量份蛋白质。

3. 发明授权

US5677384A Grafted polyamidoamines and grafted polyethyleneimines, preparation thereof, and use thereof as detergent additives 失效
标题翻译：接枝聚酰胺胺和接枝聚乙烯亚胺，其制备及其用作洗涤剂添加剂
公开(公告)号：US5677384A
公开(公告)日：1997-10-14
申请号：US513800
申请日：1995-09-07
申请人： Juergen Detering , Christian Schade , Knut Oppenlaender , Michael Zirnstein , Guenter Scherr , Wolfgang Trieselt , Volker Schwendemann
发明人： Juergen Detering , Christian Schade , Knut Oppenlaender , Michael Zirnstein , Guenter Scherr , Wolfgang Trieselt , Volker Schwendemann
IPC分类号： C08F226/06 , C08F283/00 , C08F283/04 , C08G73/02 , C11D3/37 , C08L77/00
CPC分类号： C11D3/3788 , C08F283/00 , C08G73/0206 , C08G73/0213 , C08G73/028
摘要： Grafted polyamidoamines and grafted polyethyleneimines obtainable by free-radically initiated polymerization of (a) 1-vinylpyrrolidone, 1-vinyltriazole, 1-vinylimidazoles, mixtures of said monomers or mixtures of at least one of said monomers with up to 20% by weight of other monoethylenically unsaturated monomers in the presence of (b) water-soluble or -dispersible polyamidoamines, polyethyleneimines or mixtures thereof in a weight ratio of (a):(b) from 5:95 to 95:5, are useful as dye transfer inhibitors in surfactant-based detergents when included therein in an amount from 0.05 to 10% by weight.
摘要翻译： PCT No.PCT / EP94 / 01801 Sec。 371 1995年9月7日第 102（e）1995年9月7日PCT PCT 1994年6月3日PCT公布。第WO94 / 29422号公报日期1994年12月22日通过（a）1-乙烯基吡咯烷酮，1-乙烯基三唑，1-乙烯基咪唑，所述单体的混合物或至少一种所述单体的混合物自由引发聚合得到的接枝聚酰亚胺和接枝聚乙烯亚胺与多达20个在（b）水溶性或可分散的聚酰胺胺，聚乙烯亚胺或其混合物（重量比为（a）：（b））5:95至95:5的存在下，其它单烯属不饱和单体的重量百分数是有用的作为基于表面活性剂的洗涤剂中的染料转移抑制剂，当其中包含0.05至10重量％的量时。

4. 发明授权

US5622926A Vinylpyrrolidone and vinylimidazole copolymers, their preparation and their use in detergents 失效
标题翻译：乙烯基吡咯烷酮和乙烯基咪唑共聚物，它们的制备及其在洗涤剂中的应用
公开(公告)号：US5622926A
公开(公告)日：1997-04-22
申请号：US454173
申请日：1995-06-21
申请人： Christian Schade , Juergen Detering , Wolfgang Trieselt
发明人： Christian Schade , Juergen Detering , Wolfgang Trieselt
IPC分类号： C08F279/00 , C08F279/02 , C08F283/00 , C08F283/01 , C08F283/12 , C08F290/00 , C08F290/04 , C08F290/06 , C08F291/00 , C08L25/08 , C08L39/00 , C08L39/06 , C08L51/00 , C08L51/04 , C08L51/08 , C08L55/00 , C11D3/00 , C11D3/37 , C11D1/94 , C11D3/28
CPC分类号： C11D3/0021 , C08F279/02 , C08F283/01 , C08F283/122 , C08F290/04 , C08F290/06 , C08F291/00 , C11D3/3776
摘要： Copolymers which are obtainable by free radical copolymerization of a mixture of(a) from 20 to 95% by weight of 1-vinylpyrrolidone, a 1-vinylimidazole or a mixture of 1-vinylpyrrolidone and/or 1-vinylimidazoles which may contain up to 20% by weight of other monoethylenically unsaturated monomers and(b) from 5 to 80% by weight of water-insoluble polymers which contain at least one ethylenically unsaturated double bond and/or one mercapto group in the molecule, processes for the preparation of the copolymers by copolymerization of the compounds of groups (a) and (b) in the abovementioned amounts in water, an alcohol, an ester or a ketone in the presence of free radical initiators, and the use of the copolymers thus obtainable and of copolymers of from 20 to 95% by weight of 1-vinylpyrrolidone or a mixture of 1-vinylpyrrolidone with up to 20% by weight of other monoethylenically unsaturated monomers andfrom 10 to 80% by weight of styrene as additives for detergents for inhibiting the dye transfer during the wash process, and detergents which contain the stated copolymers.
摘要翻译： PCT No.PCT / EP93 / 03598 Sec。 371日期：1995年6月21日 102（e）1995年6月21日日期PCT 1993年12月17日PCT PCT。出版物WO94 / 14861 日期1994年7月7日共聚物可以通过（a）20至95重量％的1-乙烯基吡咯烷酮，1-乙烯基咪唑或1-乙烯基吡咯烷酮和/或1-乙烯基咪唑的混合物的混合物的自由基共聚获得，可含有至多20重量％的其它单烯属不饱和单体和（b）5至80重量％的在分子中含有至少一个烯属不饱和双键和/或一个巯基的水不溶性聚合物，通过在自由基引发剂的存在下，在水，醇，酯或酮中将上述量的基团（a）和（b）的化合物共聚制备共聚物，以及由此获得的共聚物的用途以及20至95重量％的1-乙烯基吡咯烷酮或1-乙烯基吡咯烷酮与至多20重量％的其它单烯属不饱和单体和10至80重量％苯乙烯的混合物的共聚物，作为洗涤剂的添加剂在洗涤过程中抑制染料转移，以及含有所述共聚物的洗涤剂。

5. 发明授权

US5972237A Use of heterocyclic compounds as activators for inorganic peroxy compounds 失效
标题翻译：使用杂环化合物作为无机过氧化合物的活化剂
公开(公告)号：US5972237A
公开(公告)日：1999-10-26
申请号：US952076
申请日：1997-11-17
申请人： Reinhard Muller , Thomas Wehlage , Wolfgang Trieselt , Alfred Oftring , Elisabeth Kappes , Gunter Oetter , Dieter Boeckh , Roland Ettl , Albert Hettche
发明人： Reinhard Muller , Thomas Wehlage , Wolfgang Trieselt , Alfred Oftring , Elisabeth Kappes , Gunter Oetter , Dieter Boeckh , Roland Ettl , Albert Hettche
IPC分类号： C11D7/26 , C11D3/39 , C11D3/42 , C11D7/32 , C11D7/34 , C11D7/36 , C11D7/54 , D06L3/12 , A61L2/18
CPC分类号： C11D3/42 , C11D3/3907 , C11D3/393 , D06L3/1207 , D06L3/1257 , D06L3/1271
摘要： Heterocyclic compounds IR.sup.1 --X--L (I)whereL is a cyclic carbamate residue, a lactonoxy residue or a lactam residue,X is an oxygen-containing group ##STR1## where A is a linker, and R.sup.1 is an organic radical or a group L,are used as activators for inorganic peroxy compounds, in particular as cold bleach activators or optical brighteners in detergents, cleaners and bleaches and in disinfectants.
摘要翻译： PCT No.PCT / EP96 / 01863 Sec。 371日期：1997年11月17日 102（e）日期1997年11月17日PCT提交1996年5月4日PCT公布。 WO96 / 36686 PCT公开号日期：1996年11月21日杂环化合物I R1-XL（I）其中L是环状氨基甲酸酯残基，内酯氧基残基或内酰胺残基，X是含氧基团，其中A是连接基，R1是有机基团或一组L用作无机过氧化合物的活化剂，特别是作为洗涤剂，清洁剂和漂白剂以及消毒剂中的冷漂白活化剂或荧光增白剂。

6. 发明授权

US5175361A Preparation of copolymers of monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids 失效
标题翻译：单烯属不饱和一元羧酸和二羧酸的共聚物的制备
公开(公告)号：US5175361A
公开(公告)日：1992-12-29
申请号：US625621
申请日：1990-11-30
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C08F220/04 , C08F222/02
CPC分类号： C08F222/02 , C08F220/04
摘要： A process for the preparation of copolymers which contain monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids as copolymerized monomer units, which comprises copolymerizinga) 10 to 60% by weight, based on the sum of the monomers, of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, -or an alkali metal salt thereof or, an anhydride thereof,b) 90 to 40% by weight of a monoethylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms or an alkali metal salt thereof andc) 0 to 20% by weight of another monoethylenically unsaturated monomer, not having carboxyl groups and which is copolymerizable with a) and b);in an aqueous medium in the presence of from 0.5 to 5% by weight, based on monomers, of a water-soluble initiator.
摘要翻译：一种制备包含单烯属不饱和一元羧酸和二羧酸作为共聚单体单元的共聚物的方法，其包括将基于单体总量的10-60重量％的单烯属不饱和二羧酸与4- 6个碳原子，或其碱金属盐或其酸酐，b）90〜40重量％的3〜10个碳原子的单烯属不饱和一元羧酸或其碱金属盐，c）0〜20重量％重量的不具有羧基且可与a）和b）共聚的另一单烯属不饱和单体; 在水介质中，以0.5至5重量％的单体为基础，存在水溶性引发剂。

7. 发明授权

US5130476A Preparation of .beta.-alaninediacetic acid or its alkali metal or ammonium salts 失效
标题翻译：（BETA） - 亚氨酸或其碱金属或氨盐的制备
公开(公告)号：US5130476A
公开(公告)日：1992-07-14
申请号：US674149
申请日：1991-03-25
申请人： Richard Baur , Charalampos Gousetis , Wolfgang Trieselt , Werner Bochnitschek , Alfred Oftring
发明人： Richard Baur , Charalampos Gousetis , Wolfgang Trieselt , Werner Bochnitschek , Alfred Oftring
IPC分类号： C07C227/06 , C07C227/14 , C07C229/16
CPC分类号： C07C227/14
摘要： .beta.-Alaninediacetic acid (Ia) or its alkali metal or ammonium salts (Ib) are prepared by a process in which iminodiacetic acid and acrylic acida) for the preparation of Ia, are reacted with one another in a nonbasic aqueous medium andb) for the preparation of Ib, are reacted with one another in an alkaline aqueous medium or an aqueous medium containing a nitrogen base, or the Ia formed in the nonbasic medium is converted with an alkali metal base, ammonia or an amine into Ib.

8. 发明授权

US4997587A Washing and cleaning agents containing .beta.-alanine-N,N-diacetic acid 失效
标题翻译：含有β-丙氨酸-N，N-二乙酸的洗涤剂和清洁剂
公开(公告)号：US4997587A
公开(公告)日：1991-03-05
申请号：US394935
申请日：1989-08-17
申请人： Richard Baur , Charalampos Gousetis , Wolfgang Trieselt , Werner Bochnitschek , Alfred Oftring
发明人： Richard Baur , Charalampos Gousetis , Wolfgang Trieselt , Werner Bochnitschek , Alfred Oftring
IPC分类号： C11D3/30 , C11D3/00 , C11D3/33 , C11D7/32
CPC分类号： C11D3/33
摘要： Washing and cleaning agents for aqueous use contain from 2 to 25% by weight, based on the total weight of the agent, of .beta.-alanine-N,N-diacetic acid or an alkali metal or ammonium salt thereof as water softener. The washing and cleaning agent is effective in preventing hardness deposits on textiles and fabrics.
摘要翻译：水性洗涤剂和洗涤剂含量为2至25重量％，基于该试剂的总重量，β-丙氨酸-N，N-二乙酸或其碱金属或铵盐作为软水剂。洗涤剂和清洁剂有效防止纺织品和织物上的硬度沉积。

9. 发明授权

US4952655A Water-soluble copolymers, their preparation and their use 失效
标题翻译：水溶性共聚物，其制备及其用途
公开(公告)号：US4952655A
公开(公告)日：1990-08-28
申请号：US183611
申请日：1988-04-19
申请人： Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann , Wolfgang Trieselt , Alexander Kud
发明人： Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann , Wolfgang Trieselt , Alexander Kud
IPC分类号： A01N25/26 , C08F2/10 , C08F20/10 , C08F220/04 , C08F220/20 , C08F290/00 , C08F299/00 , C08L101/16
CPC分类号： C08F220/04 , A01N25/26
摘要： Water-soluble copolymers having a K value of from 15 to 120 (determined on the sodium salt according to H. Fikentscher in aqueous solution at 25.degree. C., a pH of 7 and a polymer concentration of the Na salt of 1% by weight) contain, in the polymerized form,(a) from 99.5 to 80 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids and(b) from 0.5 to 20 mol % of one or more comonomers which possess two or more ethylenically unsaturated, non-conjugated double bonds, are derived from esters and are obtainable by esterification of(b1) monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids with(b2) polyhydric alcohols of 2 to 6 carbon atoms, polyalkylene glycols, polyglycerols, polyvinyl alcohol and monohydric, monoethylenically unsaturated C.sub.3 -C.sub.6 -alcohols and(c) from 0 to 30 mol % of other water-soluble, monoethylenically unsaturated monomers which are copolymerizable with (a) and (b),the copolymers containing polymer segments which consist of units of the monomers (a) and (c), have a weight average molecular weight of not more than 15,000 and are bonded to one another via units of (b).
摘要翻译： K值为15〜120的水溶性共聚物（根据H.Fikentscher的钠盐在25℃的水溶液中测定，pH为7，Na盐的聚合物浓度为1重量％）包含（a）99.5-80mol％的一种或多种单烯属不饱和C 3 -C 6 - 单羧酸和（b）0.5至20摩尔％的一种或多种具有两个或多个烯键式的共聚单体的共聚单体不饱和的非共轭双键衍生自酯，可通过（b1）单烯属不饱和C3-C6-单羧酸与（b2）2至6个碳原子的多元醇酯，聚亚烷基二醇，聚甘油，聚乙烯醇和一元，单烯属不饱和C 3 -C 6醇和（c）0至30摩尔％可与（a）和（b）共聚的其它水溶性单烯属不饱和单体，所述共聚物含有聚合物链段， monom （a）和（c）的重均分子量不大于15,000，通过（b）单元彼此结合。

10. 发明授权

US4897220A Detergents containing water-soluble copolymers containing as copolymerized units monomers having two or more ethylenically unsaturated double bonds 失效
标题翻译：含有含有共聚单元的含有两个或更多个烯属不饱和双键的单体的水溶性共聚物的洗涤剂
公开(公告)号：US4897220A
公开(公告)日：1990-01-30
申请号：US191979
申请日：1988-05-10
申请人： Wolfgang Trieselt , Richard Baur , Ekhard Winkler , Paul Diessel , Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann
发明人： Wolfgang Trieselt , Richard Baur , Ekhard Winkler , Paul Diessel , Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann
IPC分类号： C08L33/02 , C08F20/10 , C08F220/04 , C08F220/06 , C08F222/16 , C11D3/37
CPC分类号： C11D3/3761
摘要： A surfactant-based detergent contains water-soluble copolymers which contain(a) from 99.5 to 15 mol % of one or more monoethylenically unsaturated C.sub.3 - to C.sub.6 -monocarboxylic acids,(b) from 0.5 to 20 mol % of one or more comonomers which contain two or more ethylenically unsaturated nonconjugated double bonds and have one or more --CO--OX groups where X is hydrogen, an alkali metal, one equivalent of an alkaline earth metal or ammonium,(c) from 0 to 84.5 mol % of one or more monoethylenically unsaturated C.sub.4 - to C.sub.6 -dicarboxylic acids,(d) from 0 to 20 mol % of one or more hydroxyalkyl esters of monoethylenically unsaturated C.sub.3 - to C.sub.6 -carboxylic acids and(e) from 0 to 30 mol % of other water-soluble monoethylenically unsaturated monomers copolymerizable with (a) to (d)as copolymerized units, with the proviso that the sum of the mol % ages (a) to (e) is always 100 and which have a Finkentscher K value of from 8 to 120.
摘要翻译：基于表面活性剂的洗涤剂含有水溶性共聚物，其含有（a）99.5〜15摩尔％的一种或多种单烯属不饱和C3〜C6-一元羧酸，（b）0.5〜20摩尔％的一种或多种共聚单体，含有两个或多个烯键式不饱和非共轭双键，并且具有一个或多个-CO-OX基团，其中X为氢，碱金属，1当量碱土金属或铵，（c）0至84.5摩尔％更多的单烯属不饱和C 4 -C 6 - 二羧酸，（d）0至20摩尔％的一种或多种单烯属不饱和C 3 -C 6羧酸的羟烷基酯和（e）0至30摩尔％可与（a）至（d）共聚的可溶性单烯属不饱和单体作为共聚单元，条件是mol％年龄（a）至（e）的总和始终为100，Finkentscher K值为8至120 。

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