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    • 1. 发明授权
      US06329483B1 Copolymers of carboxylic acids and quaternary ammonium compounds and the use thereof as thickeners of dispersants 失效
    • Copolymers of carboxylic acids and quaternary ammonium compounds and the use thereof as thickeners of dispersants
    • 羧酸和季铵化合物的共聚物及其作为分散剂增稠剂的用途
    • US06329483B1
    • 2001-12-11
    • US08313175
    • 1994-09-29
    • Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
    • Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
    • C08F22204
    • A61Q19/00 , A61K8/817 , A61K2800/48 , C08F220/04 , C08F222/00
    • A copolymer obtainable by free-radical polymerization of A) 50-99.99% by weight of an olefinically unsaturated C3-C5 monocarboxylic acid, of an olefinically unsaturated C4-C8 dicarboxylic acid or the anhydride thereof or a mixture of such carboxylic acids or anhydrides with B) 0.01-50% by weight of an olefinically unsaturated quaternary ammonium compound of the formula I or II  where R1 is C6-C20-alkyl, C6-C20-alkenyl, C5-C8-cycloalkyl, phenyl, phenyl(C1-C12-alkyl) or (C1-C12-alkyl)phenyl, R2 is hydrogen, methyl or phenyl, R3 and R4 are each H or C1-C4-alkyl, X is halogen, C1-C4-alkoxysulfonyloxy or C1-C4-alkanesulfonate, it also being possible for the latter to occur as R3 or R4 with the formation of a betaine structure, Y is O or NH, and A is C1-C6-alkylene, or a mixture of such ammonium compounds, C) 0 to 49.99% by weight of an acrylate or methacrylate of the formula III  where R1, R2 and Y have the abovementioned meanings, R5 is hydrogen, methyl or ethyl, and n is a number from 0 to 25, D) 0-49.99% by weight of other copolymerizable monomers and E) 0-5% by weight of one or more compounds with at least two olefinically unsaturated groups in the molecule as crosslinker. The copolymers are suitable as thickeners and dispersants, especially in cosmetic compositions.
    • 可通过自由基聚合得到的共聚物，A）50-99.99重量％的烯属不饱和C 3 -C 5单羧酸，烯属不饱和C 4 -C 8二羧酸或其酸酐或这些羧酸或酸酐与B）的混合物， 0.01-50重量％的式I或II的烯属不饱和季铵化合物，其中R 1是C 6 -C 20 - 烷基，C 6 -C 20 - 烯基，C 5 -C 8 - 环烷基，苯基，苯基（C 1 -C 12 - 烷基）或 （C 1 -C 12 - 烷基）苯基，R 2是氢，甲基或苯基，R 3和R 4各自为H或C 1 -C 4烷基，X为卤素，C 1 -C 4烷氧基磺酰氧基或C 1 -C 4烷基磺酸盐，也是可能的 后者以R3或R4形成甜菜碱结构，Y为O或NH，A为C 1 -C 6亚烷基，或这些铵化合物的混合物，C）0至49.99重量％的丙烯酸酯 或甲基丙烯酸酯，其中R 1，R 2和Y具有上述含义，R 5是氢，甲基或乙基，n是0至25的数，D）0-4 9.99重量％的其它可共聚单体和E）0-5重量％的一种或多种在分子中具有至少两个烯属不饱和基团的化合物作为交联剂。 该共聚物适合用作增稠剂和分散剂，特别是在化妆品组合物中。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
    • 2. 发明授权
      US07465774B1 Use of copolymers of carboxylic acids and long-chain compounds with isolated C-C multiple bonds as thickeners or dispersants 失效
    • Use of copolymers of carboxylic acids and long-chain compounds with isolated C-C multiple bonds as thickeners or dispersants
    • 使用具有分离的C-C多重键的羧酸和长链化合物的共聚物作为增稠剂或分散剂
    • US07465774B1
    • 2008-12-16
    • US08325219
    • 1993-04-14
    • Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
    • Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
    • C08F220/06
    • A61K8/8164 , A61K47/32 , A61Q19/00 , C08F220/04 , C08F222/00
    • The use of copolymers obtainable by the radically initiated polymerization of A) 50 to 99.9 wt % of an olefinically unsaturated C3 to C5 monocarboxylic acid, an olefinically unsaturated C4 to C8 dicarboxylic acid or its anhydride, or a mixture of such carboxylic acids or carboxylic acid anhydrides with B) 0.1 to 50 wt % of one or more long-chained compounds with isolated multiple C—C bonds from the group (1) mono or polyunsaturated C8 to C30 monocarboxylic acids which may have additional hydroxyl groups and their alkaline metal and earth alkaline metal salts, alkyl esters, amides, sorbitane esters, glycerin esters and polyglycerin esters, (2) mono or polyunsaturated aliphatic Ca to C30 amines, (3) mono or polyunsaturated C8 to C30 alcohols and esters thereof with saturated Cl to C4 monocarboxylic acids, (4) to (C8 to C30 alkyl) vinyl ether which may incorporate up to 25 alkylene oxide units, and (5) final and medium-position Ci3 to C30 alkenes; C) 0 to 49.9 wt % of other copolymerizable monomers, and D) 0 to 10 wt % of one or more compounds with at least two olefinically unsaturated groups in the molecule as cross-linking agents, as thickening or dispersing agents, especially in cosmetic and pharmaceutical preparations.
    • 通过自由基引发的A）50-99.9重量％的烯属不饱和C 3 -C 5单羧酸，烯属不饱和C 4 -C 8二羧酸或其酸酐，或这些羧酸或羧酸的混合物 酸酐与B）0.1至50重量％的一种或多种具有分离的多个CC键的长链化合物（1）可具有额外羟基的单或多不饱和C8至C30单羧酸及其碱金属和碱土金属 盐，烷基酯，酰胺，脱水山梨糖醇酯，甘油酯和聚甘油酯，（2）单或多不饱和脂肪族Ca至C30胺，（3）单或多不饱和C8至C30醇及其与饱和C1至C4单羧酸的酯（ 4）至（C8至C30烷基）乙烯基醚，其可以并入至多25个环氧烷单元，和（5）最终和中等位置的C 13至C 30烯烃; C）0〜49.9重量％的其它可共聚单体，D）0〜10重量％的一种或多种在分子中具有至少两个烯属不饱和基团的化合物作为交联剂，作为增稠剂或分散剂，特别是化妆品 和药物制剂。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
    • 9. 发明授权
      US06680390B2 Use of substituted vinyl-tetrahydronaphthalenes and vinyl-benzotetrahydropyrans as light protection agents 失效
    • Use of substituted vinyl-tetrahydronaphthalenes and vinyl-benzotetrahydropyrans as light protection agents
    • 使用取代的乙烯基 - 四氢萘和乙烯基 - 苯并四氢吡喃作为防光剂
    • US06680390B2
    • 2004-01-20
    • US10173277
    • 2002-06-18
    • Frank Prechtl , Thorsten Habeck , Horst Westenfelder , Thomas Wilnsch
    • Frank Prechtl , Thorsten Habeck , Horst Westenfelder , Thomas Wilnsch
    • C07D31174
    • A61K8/40 , A61K8/368 , A61K8/37 , A61K8/498 , A61K2800/52 , A61Q17/04
    • The invention relates to the use of compounds of the formula I in which X is the divalent radical of oxygen, a carbonyl radical, optionally aliphatically substituted imino or the radical ═CR9R10, Y is a carbonyl group or the radical ═CR9R10, R1 and R2 are identical or different electron-withdrawing radicals, chosen from the group consisting of cyano, alkyl- or arylcarbonyl, alkyloxy- or aryloxycarbonyl, optionally substituted aminocarbonyl, alkyl- or arylsulfinyl, alkyl- or arylsulfonyl and optionally substituted aminosulfonyl, R3 is a hydrogen atom, a cyano, hydroxyl, carboxyl or aminocarbonyl group or a C5-C20-aryl radical or C1-C20-alkylradical optionally bonded via an oxygen bridge, an aminocarbonyl bridge or oxycarbonyl bridge, R4 is a hydrogen atom, a hydroxyl group, an amino group, or a C5-C20-aryl radical or C1-C20-alkyl radical optionally bonded via an oxygen bridge, and R5 to R10 independently of one another are hydrogen or C1-C20-alkyl radicals and where in addition R7 and R8 together with the chain carbon atom are a carbonyl group, as photostable UV filters in cosmetic and pharmaceutical preparations for protecting human skin and human hair from solar rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
    • 本发明涉及式Iin的化合物，其中X是氧的二价基团，羰基，任选地是脂族取代的亚氨基或基团= CR 9 R 10，Y是羰基或基团= CR 9 R 10，R 1和R 2是相同或不同的吸电子基团，选自氰基，烷基 - 或芳基羰基，烷氧基 - 或芳氧基羰基，任选取代的氨基羰基，烷基 - 或芳基亚磺酰基，烷基 - 或芳基磺酰基和任选取代的氨基磺酰基，R 3是氢原子，氰基，羟基，羧基或氨基羰基或C 5 -C 20 - 芳基或任选经氧连接的C 1 -C 20 - 烷基 桥，氨基羰基桥或氧羰基桥，R 4是氢原子，羟基，氨基或任选通过氧桥键合的C 5 -C 20 - 芳基或C 1 -C 20 - 烷基， R 5至R 10彼此独立地是氢或C 1 -C 20烷基，并且其中 R 7和R 8与链碳原子一起是羰基，作为用于保护人类皮肤和人类头发免受太阳光线影响的化妆品和药物制剂中的光稳定性UV过滤剂，单独或与在 UV区域，并且本身已知化妆品和药物制剂。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
    • 10. 发明授权
      US06603014B1 Use of cyclic enamines as light protection agents 失效
    • Use of cyclic enamines as light protection agents
    • 使用环状烯胺作为防晒剂
    • US06603014B1
    • 2003-08-05
    • US10053323
    • 2002-01-23
    • Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder
    • Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder
    • C07D27764
    • A61K8/4946 , A61K8/49 , A61K8/494 , A61K2800/52 , A61Q1/04 , A61Q17/04
    • The use of compounds of the formula I in which R1 and R2 are identical or different, electron-withdrawing radicals chosen from the group consisting of cyano, alkyl- or arylcarbonyl, alkyloxy- or aryloxycarbonyl and optionally substituted aminocarbonyl, R3 is a hydrogen atom, a C1-C20-alkyl radical or a C3-C20-cycloalkyl radical or a radical of the formula —CH2—CH2—SO3—M+, where M+ is a cation, X is the divalent radical of oxygen, sulfur or the radical where R3 is as defined above, is the divalent radical of the formula II or III, which forms a fused system with the radical of the formula I where R4 can be bonded one or more times to the benzylidene ring I or naphthylidene ring II, and is hydrogen, alkyl, cycloalkyl, alkyloxy, cycloalkyloxy, alkoxycarbonyl, mono- or dialkylaminocarbonyl, alkylamino, dialkylamino, each having up to 20 carbon atoms, and also cyano, amino and SO3—M+, where M+ is a cation, as photostable UV filters in cosmetic and pharmaceutical preparations to protect human skin and human hair against solar rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
    • 使用其中R 1和R 2相同或不同的式Iin化合物，选自氰基，烷基 - 或芳基羰基，烷氧基 - 或芳氧基羰基和任选取代的氨基羰基的吸电子基，R 3是氢原子，C 1 -C 20 - 烷基或C 3 -C 20环烷基或式-CH 2 -CH 2 -SO 3 -M +的基团，其中M +是阳离子，X是氧，硫或基团的二价基团，其中R3如所定义 是式II或III的二价基团，其与式I的基团形成稠合体系，其中R 4可以与亚苄基环I或亚萘基环II键合一次或多次，并且是氢，烷基，环烷基 ，烷氧基，环烷氧基，烷氧基羰基，单或二烷基氨基羰基，烷基氨基，二烷基氨基，各自具有至多20个碳原子，以及氰基，氨基和SO3-M +，其中M +是阳离子，作为化妆品和药物制剂中的光稳定性UV过滤剂 保护人体皮肤a 将人类头发抵抗太阳光线，单独或与在UV区域吸收的化合物一起，并且本身已知用于化妆品和药物制剂。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
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