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1. 发明授权

US06329483B1 Copolymers of carboxylic acids and quaternary ammonium compounds and the use thereof as thickeners of dispersants 失效
标题翻译：羧酸和季铵化合物的共聚物及其作为分散剂增稠剂的用途
公开(公告)号：US06329483B1
公开(公告)日：2001-12-11
申请号：US08313175
申请日：1994-09-29
申请人： Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
发明人： Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
IPC分类号： C08F22204
CPC分类号： A61Q19/00 , A61K8/817 , A61K2800/48 , C08F220/04 , C08F222/00
摘要： A copolymer obtainable by free-radical polymerization of A) 50-99.99% by weight of an olefinically unsaturated C3-C5 monocarboxylic acid, of an olefinically unsaturated C4-C8 dicarboxylic acid or the anhydride thereof or a mixture of such carboxylic acids or anhydrides with B) 0.01-50% by weight of an olefinically unsaturated quaternary ammonium compound of the formula I or II where R1 is C6-C20-alkyl, C6-C20-alkenyl, C5-C8-cycloalkyl, phenyl, phenyl(C1-C12-alkyl) or (C1-C12-alkyl)phenyl, R2 is hydrogen, methyl or phenyl, R3 and R4 are each H or C1-C4-alkyl, X is halogen, C1-C4-alkoxysulfonyloxy or C1-C4-alkanesulfonate, it also being possible for the latter to occur as R3 or R4 with the formation of a betaine structure, Y is O or NH, and A is C1-C6-alkylene, or a mixture of such ammonium compounds, C) 0 to 49.99% by weight of an acrylate or methacrylate of the formula III where R1, R2 and Y have the abovementioned meanings, R5 is hydrogen, methyl or ethyl, and n is a number from 0 to 25, D) 0-49.99% by weight of other copolymerizable monomers and E) 0-5% by weight of one or more compounds with at least two olefinically unsaturated groups in the molecule as crosslinker. The copolymers are suitable as thickeners and dispersants, especially in cosmetic compositions.
摘要翻译：可通过自由基聚合得到的共聚物，A）50-99.99重量％的烯属不饱和C 3 -C 5单羧酸，烯属不饱和C 4 -C 8二羧酸或其酸酐或这些羧酸或酸酐与B）的混合物， 0.01-50重量％的式I或II的烯属不饱和季铵化合物，其中R 1是C 6 -C 20 - 烷基，C 6 -C 20 - 烯基，C 5 -C 8 - 环烷基，苯基，苯基（C 1 -C 12 - 烷基）或（C 1 -C 12 - 烷基）苯基，R 2是氢，甲基或苯基，R 3和R 4各自为H或C 1 -C 4烷基，X为卤素，C 1 -C 4烷氧基磺酰氧基或C 1 -C 4烷基磺酸盐，也是可能的后者以R3或R4形成甜菜碱结构，Y为O或NH，A为C 1 -C 6亚烷基，或这些铵化合物的混合物，C）0至49.99重量％的丙烯酸酯或甲基丙烯酸酯，其中R 1，R 2和Y具有上述含义，R 5是氢，甲基或乙基，n是0至25的数，D）0-4 9.99重量％的其它可共聚单体和E）0-5重量％的一种或多种在分子中具有至少两个烯属不饱和基团的化合物作为交联剂。该共聚物适合用作增稠剂和分散剂，特别是在化妆品组合物中。

2. 发明授权

US07465774B1 Use of copolymers of carboxylic acids and long-chain compounds with isolated C-C multiple bonds as thickeners or dispersants 失效
标题翻译：使用具有分离的C-C多重键的羧酸和长链化合物的共聚物作为增稠剂或分散剂
公开(公告)号：US07465774B1
公开(公告)日：2008-12-16
申请号：US08325219
申请日：1993-04-14
申请人： Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
发明人： Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
IPC分类号： C08F220/06
CPC分类号： A61K8/8164 , A61K47/32 , A61Q19/00 , C08F220/04 , C08F222/00
摘要： The use of copolymers obtainable by the radically initiated polymerization of A) 50 to 99.9 wt % of an olefinically unsaturated C3 to C5 monocarboxylic acid, an olefinically unsaturated C4 to C8 dicarboxylic acid or its anhydride, or a mixture of such carboxylic acids or carboxylic acid anhydrides with B) 0.1 to 50 wt % of one or more long-chained compounds with isolated multiple C—C bonds from the group (1) mono or polyunsaturated C8 to C30 monocarboxylic acids which may have additional hydroxyl groups and their alkaline metal and earth alkaline metal salts, alkyl esters, amides, sorbitane esters, glycerin esters and polyglycerin esters, (2) mono or polyunsaturated aliphatic Ca to C30 amines, (3) mono or polyunsaturated C8 to C30 alcohols and esters thereof with saturated Cl to C4 monocarboxylic acids, (4) to (C8 to C30 alkyl) vinyl ether which may incorporate up to 25 alkylene oxide units, and (5) final and medium-position Ci3 to C30 alkenes; C) 0 to 49.9 wt % of other copolymerizable monomers, and D) 0 to 10 wt % of one or more compounds with at least two olefinically unsaturated groups in the molecule as cross-linking agents, as thickening or dispersing agents, especially in cosmetic and pharmaceutical preparations.
摘要翻译：通过自由基引发的A）50-99.9重量％的烯属不饱和C 3 -C 5单羧酸，烯属不饱和C 4 -C 8二羧酸或其酸酐，或这些羧酸或羧酸的混合物酸酐与B）0.1至50重量％的一种或多种具有分离的多个CC键的长链化合物（1）可具有额外羟基的单或多不饱和C8至C30单羧酸及其碱金属和碱土金属盐，烷基酯，酰胺，脱水山梨糖醇酯，甘油酯和聚甘油酯，（2）单或多不饱和脂肪族Ca至C30胺，（3）单或多不饱和C8至C30醇及其与饱和C1至C4单羧酸的酯（ 4）至（C8至C30烷基）乙烯基醚，其可以并入至多25个环氧烷单元，和（5）最终和中等位置的C 13至C 30烯烃; C）0〜49.9重量％的其它可共聚单体，D）0〜10重量％的一种或多种在分子中具有至少两个烯属不饱和基团的化合物作为交联剂，作为增稠剂或分散剂，特别是化妆品和药物制剂。

3. 发明授权

US5147644A Use of mixtures of polyglycerol fatty esters as emulsifiers in cosmetic and pharmaceutical formulations 失效
标题翻译：在化妆品和药物制剂中使用聚甘油脂肪酸酯作为乳化剂的混合物
公开(公告)号：US5147644A
公开(公告)日：1992-09-15
申请号：US659254
申请日：1991-02-22
申请人： Knut Oppenlaender , Brigette Wegner , Karl Stork , Franz Frosch , Hans-Ulrich Wekel
发明人： Knut Oppenlaender , Brigette Wegner , Karl Stork , Franz Frosch , Hans-Ulrich Wekel
IPC分类号： A61K8/06 , A61K8/39 , A61K9/00 , A61K47/14 , A61Q19/00 , B01F17/00 , B01F17/34 , C07C69/33
CPC分类号： C07C69/33 , A61K47/14 , A61K8/06 , A61K8/39 , A61K9/0014 , A61Q19/00 , B01F17/0092 , Y10S424/05 , Y10S514/937 , Y10S514/938 , Y10S514/939
摘要： Mixtures of polyglycerol fatty esters obtainable by partial esterification of a polyglycerol mixture consisting offrom 0 to 5% by weight of monoglycerol,from 15 to 40% by weight of diglycerol,from 30 to 55% by weight of triglycerol,from 10 to 25% by weight of tetraglycerol,from 0 to 15% by weight of pentaglycerol,from 0 to 10% by weight of hexaglycerol andfrom 0 to 5% by weight of higher polyglycerolswith one or more saturated fatty acids of 12 to 22 carbon atoms or one or more unsaturated fatty acids of 16 to 22 carbon atoms, where the unsaturated fatty acid or fatty acid mixture used may furthermore contain up to 10% by weight of saturated fatty acids of 16 to 22 carbon atoms and the degree of esterification of the saturated or unsaturated fatty acids in the mixture is from 20 to 70%, are used as emulsifiers in cosmetic and pharmaceutical formulations.
摘要翻译：通过由0-5重量％的单甘油，15至40重量％的双甘油，30至55重量％的三甘油，10至25重量％的三甘油酯组成的聚甘油混合物进行部分酯化获得的聚甘油脂肪酯的混合物，的四甘油，0至15重量％的五甘油，0至10重量％的六甘油和0至5重量％的具有12至22个碳原子的一种或多种饱和脂肪酸的较高级聚甘油或一种或更多的16至22个碳原子的不饱和脂肪酸，其中所用的不饱和脂肪酸或脂肪酸混合物还可含有至多10重量％的16至22个碳原子的饱和脂肪酸和饱和或混合物中的不饱和脂肪酸为20至70％，用作化妆品和药物制剂中的乳化剂。

4. 发明授权

US5152991A Use of selectively hydrogenated styrene/butadiene copolymers in cosmetic and pharmaceutical compositions 失效
标题翻译：在化妆品和药物组合物中使用选择性氢化苯乙烯/丁二烯共聚物
公开(公告)号：US5152991A
公开(公告)日：1992-10-06
申请号：US714702
申请日：1991-06-13
申请人： Friedrich Vogel , Franz Frosch , Horst Westenfelder
发明人： Friedrich Vogel , Franz Frosch , Horst Westenfelder
IPC分类号： A61K8/72 , A61K8/00 , A61K8/81 , A61K9/00 , A61K9/06 , A61K9/107 , A61K9/70 , A61K47/32 , A61Q17/00 , A61Q19/00 , A61Q19/10
CPC分类号： A61K9/0014 , A61K47/32 , A61K8/8194 , A61K9/7015 , A61Q19/00 , A61Q17/00 , Y10S514/844
摘要： Copolymers selectively hydrogenated on the olefinic double bond and composed ofA) 50 to 65% by weight styrene,B) 35 to 50% by weight butadiene andC) 0 to 5% by weight other copolymerizable monomers are used in cosmetic and pharmaceutical compositions.
摘要翻译：由烯属双键选择氢化的共聚物，A）50-65％（重量）苯乙烯，B）35-50％重量丁二烯和C）0-5％重量的其它可共聚单体用于化妆品和药物组合物中。

5. 发明授权

US5155171A Preparation of copolymers of monoalkyl maleates or maleic acid and salts thereof and vinyl alkyl ethers 失效
标题翻译：单糖醛酸或马来酸及其盐和乙烯醇的共聚物的制备
公开(公告)号：US5155171A
公开(公告)日：1992-10-13
申请号：US709216
申请日：1991-06-03
申请人： Harald Meyer , Axel Sanner , Hans-Juergen Raubenheimer , Franz Frosch
发明人： Harald Meyer , Axel Sanner , Hans-Juergen Raubenheimer , Franz Frosch
IPC分类号： C08F4/32 , A61K8/72 , A61K8/81 , C08F2/06 , C08F4/28 , C08F4/34 , C08F8/12 , C08F8/14 , C08F16/12 , C08F20/02 , C08F22/10 , C08F216/12 , C08F216/18 , C08F222/02 , C08F222/06 , C08F222/16
CPC分类号： A61Q5/06 , A61K8/8164 , C08F222/06
摘要： Copolymers of monoalkyl maleates or maleic acid and salts thereof and vinyl alkyl ethers are prepared by free radical copolymerization of maleic anhydride and vinyl alkyl ethers and subsequent reaction with an alkanol or water and optionally metal hydroxides and/or oxides in a process wherein at every stage of the polymerization the vinyl alkyl ether component is present in excess in the reaction mixture, the free radical copolymerization is carried out in acetone and the acetone is removed by distillation during or after the esterification or hydrolysis, which comprises using a peroxyester of a carboxylic acid of 8 or more carbon atoms as polymerization initiator. The copolymers obtained are used in cosmetic preparations.
摘要翻译：马来酸单烷基酯或马来酸单烷基酯及其盐和乙烯基烷基醚的共聚物通过马来酸酐和乙烯基烷基醚的自由基共聚制备，随后与链烷醇或水和任选的金属氢氧化物和/或氧化物反应，其中在每个阶段的聚合反应中，乙烯基烷基醚组分在反应混合物中过量存在，自由基共聚在丙酮中进行，丙酮在酯化或水解过程中或之后通过蒸馏除去，其中包括使用羧酸的过氧酯 8个或更多个碳原子作为聚合引发剂。获得的共聚物用于化妆品制剂中。

6. 发明授权

US5698649A Copolymers based on vinyl ethers and monoethylenically unsaturated dicarboxylic anhydrides, their preparation and their use 失效
标题翻译：基于乙烯基醚和单烯属不饱和二羧酸酐的共聚物，其制备及其应用
公开(公告)号：US5698649A
公开(公告)日：1997-12-16
申请号：US645047
申请日：1996-05-13
申请人： Harald Meyer , Walter Denzinger , Axel Sanner , Hans Richter , Hans-Juergen Raubenheimer , Franz Frosch
发明人： Harald Meyer , Walter Denzinger , Axel Sanner , Hans Richter , Hans-Juergen Raubenheimer , Franz Frosch
IPC分类号： A61K8/81 , A61K47/32 , A61Q5/06 , A61Q11/00 , C08F216/18 , C08F222/04 , C08F222/14 , C08F222/06 , C08F216/14 , C08F222/10
CPC分类号： C08F222/14 , A61K47/32 , A61K8/8164 , A61Q11/00 , A61Q5/06 , C08F216/18 , C08F222/04
摘要： Copolymers which contain a) from 2 to 50 mol % of vinyl alkyl ethers having 3 to 30 carbon atoms in the molecule, b) from 10 to 88 mol % of monoethylenically unsaturated dicarboxylic anhydrides and c) from 10 to 88 mol % of dialkyl esters of monoethylenically unsaturated dicarboxylic acids as typical monomer units in polymerized form are prepared by copolymerizing the monomers a), b) and c) at from 40.degree. to 180.degree. C. in the presence of free radical initiators and are used as film-forming resins in hair sprays and, in the form of the alkali metal, ammonium or alkaline earth metal salts, as thickeners for aqueous systems, such as cosmetic and pharmaceutical formulations, textile print pastes, liquid detergents and cleaning agents.
摘要翻译：含有a）2〜50摩尔％的分子中具有3〜30个碳原子的乙烯基烷基醚的共聚物，b）10〜88摩尔％的单烯键式不饱和二羧酸酐和c）10〜88摩尔％的二烷基酯的单烯属不饱和二羧酸作为聚合形式的典型单体单元通过在自由基引发剂的存在下在40℃至180℃下共聚合单体a），b）和c）来制备，并用作成膜树脂在头发喷雾剂中，以碱金属的形式，铵或碱土金属盐作为水性体系的增稠剂，例如化妆品和药物制剂，纺织印花浆料，液体洗涤剂和清洁剂。

7. 发明授权

US5196188A Terpolymers, use thereof in hair setting compositions for increased stiffness, and hair setting compositions containing same 失效
标题翻译： TERPOLYMERS，在使用它的头发设定组合物增加的坚固性和头发设定组合物包含它们
公开(公告)号：US5196188A
公开(公告)日：1993-03-23
申请号：US763417
申请日：1991-09-20
申请人： Birgit Potthoff-Karl , Karin Sperling-Vietmeier , Franz Frosch , Axel Sanner
发明人： Birgit Potthoff-Karl , Karin Sperling-Vietmeier , Franz Frosch , Axel Sanner
IPC分类号： A61K8/72 , A61K8/00 , A61K8/81 , A61Q5/06 , C08F8/44 , C08F26/10 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/18 , C08F226/10
CPC分类号： A61Q5/06 , A61K8/8182 , C08F220/18 , C08F8/44 , Y10S424/01 , Y10S424/02
摘要： A terpolymer suitable for use as a film former in hair setting compositions is obtainable by free radical polymerization of 10%-24% by weight of N-vinylpyrrolidone, 46%-74% by weight of tert-butyl acrylate or methacrylate and 16%-30% by weight of acrylic or methacrylic acid, whose carboxyl groups may be partially or completely neutralized with an organic amine, ammonia or a basic alkali metal compound and which has a K value of from 25 to 65.
摘要翻译：适用于头发固化组合物中成膜剂的三元共聚物可通过10％-24％（重量）N-乙烯基吡咯烷酮，46％-74％（重量）丙烯酸叔丁酯或甲基丙烯酸酯和16％ - 30重量％的丙烯酸或甲基丙烯酸，其羧基可以用有机胺，氨或碱性碱金属化合物部分或完全中和，其K值为25至65。

8. 发明授权

US6008274A Stabilization of copolymers of maleic acid or maleic anhydride and vinyl alkyl ethers 失效
标题翻译：马来酸或马来酸酐和乙烯基烷基醚的共聚物的稳定化
公开(公告)号：US6008274A
公开(公告)日：1999-12-28
申请号：US307786
申请日：1994-09-30
申请人： Harald Meyer , Axel Sanner , Franz Frosch , Hans Richter
发明人： Harald Meyer , Axel Sanner , Franz Frosch , Hans Richter
IPC分类号： C08K5/41 , C08F16/12 , C08F216/14 , C08K3/30 , C08K3/32 , C08K5/1535 , C08L29/10 , C08L33/02 , C08L35/00 , C08L35/08 , C08K5/00
CPC分类号： C08K3/32 , C08K3/30 , C08K5/1535
摘要： A process for stabilizing a copolymer of maleic acid or maleic anhydride and vinyl alkyl ethers against a reduction in molecular weight in aqueous solution or in the solution of an organic solvent by adding 0.001 to 10% by weight, based on the copolymer, of a reducing agent, a tert-butyl-containing phenol or a mixture thereof.
摘要翻译： PCT No.PCT / EP93 / 00954 Sec。 371日期1994年9月30日 102（e）1994年9月30日PCT 1993年4月20日PCT公布。公开号WO93 / 22374 日期1993年11月11日一种用于稳定马来酸或马来酸酐和乙烯基烷基醚的共聚物的方法，其相对于水溶液中的分子量降低或在有机溶剂的溶液中，通过加入0.001至10重量％共聚物，还原剂，含叔丁基苯酚或其混合物。

9. 发明授权

US4622220A Preparation for oral hygiene 失效
公开(公告)号：US4622220A
公开(公告)日：1986-11-11
申请号：US702582
申请日：1985-02-19
申请人： Franz Frosch
发明人： Franz Frosch
IPC分类号： A61K8/44 , A61Q11/00 , A61K7/16
CPC分类号： A61K8/44 , A61Q11/00
摘要： A composition for oral hygiene with improved efficacy against dental plaque, said composition containing zinc aspartate and/or copper aspartate, preferably in an amount of 0.05 to 5% by weight based on the total weight of the composition.

10. 发明授权

US4339429A Toothpaste active against plaque comprising a copper compound and a plastic polishing agent 失效
标题翻译：针对包含铜化合物和塑料抛光剂的斑块活性的牙膏
公开(公告)号：US4339429A
公开(公告)日：1982-07-13
申请号：US252406
申请日：1981-04-09
申请人： Helmut Raaf , Dieter Becker , Franz Frosch , Helmut Harth , Helmar R. Wagner
发明人： Helmut Raaf , Dieter Becker , Franz Frosch , Helmut Harth , Helmar R. Wagner
IPC分类号： A61K8/00 , A61K8/33 , A61K8/36 , A61K8/365 , A61K8/42 , A61K8/44 , A61K8/81 , A61K8/84 , A61Q11/00 , A61K7/16 , A61K7/18 , A61K7/24 , A61K33/34
CPC分类号： A61K8/84 , A61K8/8152 , A61Q11/00
摘要： This invention relates to a novel toothpaste and more particularly, to a new toothpaste which includes a finely divided synthetic plastic material as a polishing agent and at least one copper compound. This toothpaste has proven effective against plaque formation on teeth but does not exhibit any of the untoward side effects of the prior art formulations such as discoloring.
摘要翻译：本发明涉及一种新型牙膏，更具体地说，涉及一种新的牙膏，其包括细分的合成塑料材料作为抛光剂和至少一种铜化合物。这种牙膏已被证明有效地抵抗牙齿上的斑块形成，但不表现出现有技术制剂如变色的任何不利影响。

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