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1. 发明授权

US08901198B2 UV-curable coating compositions, multi-component composite coatings, and related coated substrates 有权
标题翻译：紫外光固化涂料组合物，多组分复合涂料和相关的涂布基材
公开(公告)号：US08901198B2
公开(公告)日：2014-12-02
申请号：US12940168
申请日：2010-11-05
申请人： Charles M. Kania , Kenneth T. Phelps , Kurt A. Humbert , Todd M. Roper , Jiping Shao , David C. Martin
发明人： Charles M. Kania , Kenneth T. Phelps , Kurt A. Humbert , Todd M. Roper , Jiping Shao , David C. Martin
IPC分类号： C08F2/50 , C08J3/28 , C08F2/48 , C08F2/46 , C08G18/79 , C09D175/16 , C08G18/67 , C08G18/32
CPC分类号： C08G18/792 , C08F2/48 , C08G18/3206 , C08G18/672 , C09D175/16
摘要： Disclosed herein are solventborne liquid UV-curable coating compositions comprising: a radiation curable compound comprising an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising: an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and an active hydrogen-containing acrylate; and a photoinitiator composition that includes a first photoinitiator composition for providing surface cure and a second photoinitiator composition for providing through cure of the resultant coating layer. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.
摘要翻译：本文公开了溶剂型液体UV可固化涂料组合物，其包含：包含具有大于两个不饱和位点的丙烯酸酯封端的化合物的可辐射固化化合物，其中所述丙烯酸酯封端的化合物包含反应物的反应产物，其包含：多异氰酸酯的加合物，其中多异氰酸酯的加成物包括包含多于两个异氰酸酯基的多异氰酸酯和具有与多异氰酸酯的异氰酸酯基反应的基团的化合物的反应物的反应产物; 和含活性氢的丙烯酸酯; 以及光引发剂组合物，其包括用于提供表面固化的第一光引发剂组合物和用于通过固化所得涂层提供的第二光引发剂组合物。还公开了相关的多组分复合涂层，涂覆的基底和用于涂覆基底的方法。

2. 发明申请

US20120115975A1 UV-Curable Coating Compositions, Multi-Component Composite Coatings, and Related Coated Substrates 有权
标题翻译： UV可固化涂料组合物，多组分复合涂料和相关涂层基材
公开(公告)号：US20120115975A1
公开(公告)日：2012-05-10
申请号：US12940168
申请日：2010-11-05
申请人： Charles M. Kania , Kenneth T. Phelps , Kurt A. Humbert , Todd M. Roper , Jiping Shao , David C. Martin
发明人： Charles M. Kania , Kenneth T. Phelps , Kurt A. Humbert , Todd M. Roper , Jiping Shao , David C. Martin
IPC分类号： C09D175/00 , C08F2/46
CPC分类号： C08G18/792 , C08F2/48 , C08G18/3206 , C08G18/672 , C09D175/16
摘要： Disclosed herein are solventborne liquid UV-curable coating compositions comprising: a radiation curable compound comprising an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising: an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and an active hydrogen-containing acrylate; and a photoinitiator composition that includes a first photoinitiator composition for providing surface cure and a second photoinitiator composition for providing through cure of the resultant coating layer. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.
摘要翻译：本文公开了溶剂型液体UV可固化涂料组合物，其包含：包含具有大于两个不饱和位点的丙烯酸酯封端的化合物的可辐射固化化合物，其中所述丙烯酸酯封端的化合物包含反应物的反应产物，其包含：多异氰酸酯的加合物，其中多异氰酸酯的加成物包括包含多于两个异氰酸酯基的多异氰酸酯和具有与多异氰酸酯的异氰酸酯基反应的基团的化合物的反应物的反应产物; 和含活性氢的丙烯酸酯; 以及光引发剂组合物，其包括用于提供表面固化的第一光引发剂组合物和用于通过固化所得涂层提供的第二光引发剂组合物。还公开了相关的多组分复合涂层，涂覆的基底和用于涂覆基底的方法。

3. 发明授权

US07132477B2 Powder coating compositions 失效
标题翻译：粉末涂料组合物
公开(公告)号：US07132477B2
公开(公告)日：2006-11-07
申请号：US10928902
申请日：2004-08-27
申请人： Kurt A. Humbert , Karen S. Rechenberg , Edward R. Coleridge , Charles M. Kania , Paul H. Lamers
发明人： Kurt A. Humbert , Karen S. Rechenberg , Edward R. Coleridge , Charles M. Kania , Paul H. Lamers
IPC分类号： C08F8/00
CPC分类号： C09D5/033 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , B05D7/57 , C08F8/00 , C08F210/10 , C08F220/06 , C08F220/10 , C08F220/32 , C08F290/046 , C08G18/6229 , C08G18/6254 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G59/4261 , C08G2150/20 , C08L33/02 , C08L33/04 , C08L33/068 , C08L2312/00 , C09D123/22 , C09D133/062 , C09D133/068 , C09D133/08 , C09D163/00 , Y10T428/31855 , C08L2666/04 , C08F220/00 , C08F2500/26 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F212/00 , C08F222/00 , C08F214/18 , C08F2500/03 , C08F2500/02
摘要： A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material, and a monocarboxylic acid. Multi-component composite coatings, coated substrates, and related methods are also provided.
摘要翻译：一种热固性组合物，其包含可共反应的固体，具有官能团的成膜材料的颗粒混合物，具有至少两个与成膜材料中的官能团反应的官能团的交联剂和一元羧酸。还提供了多组分复合涂层，涂覆的基材和相关方法。

4. 发明授权

US06277917B1 Powder coating compositions and coated substrates with multilayered coatings 失效
标题翻译：粉末涂料组合物和具有多层涂层的涂布基材
公开(公告)号：US06277917B1
公开(公告)日：2001-08-21
申请号：US09326921
申请日：1999-06-07
申请人： Anton Jurgetz , Karen B. Allen , John M. Furar , Kurt A. Humbert , Charles M. Kania , Stephen G. McQuown , Karen S. Rechenberg
发明人： Anton Jurgetz , Karen B. Allen , John M. Furar , Kurt A. Humbert , Charles M. Kania , Stephen G. McQuown , Karen S. Rechenberg
IPC分类号： C09D13314
CPC分类号： B05D7/532 , B05D7/534 , B05D7/572 , C08L33/068 , C08L73/02 , C08L2205/02 , C09D133/068 , Y10S525/934 , Y10T428/31504 , C08L2666/04 , C08L2666/28 , C08L2666/02
摘要： Curable powder clear coating composition and coated substrate with multilayered coatings have as the predominant film-forming polymer in the coating at least one epoxy acrylic copolymer in an amount from 60 to 99.99 percent by weight and 10 to 40 percent by weight of a polycarboxylic acid crosslinking agent. The percentages by weight are based on solids of the curable coating composition. A single predominant film-forming epoxy acrylic copolymer has a number average molecular weight in the range of about 1000 to 5500; a calculated Tg in the range of 50 to 85° C.; epoxy content in the range of 35 to 85, and a styrene content resulting from an amount of styrene monomer in the range of up to about 25 weight percent based on the weight percent of the monomers to form the copolymer. The blend of epoxy acrylic copolymer has one polymer which is the single epoxy acrylic copolymer or one having a number average molecular weight in the range of about 1000 to about 10,000, a calculated Tg in the range of about 40° C. to 85° C., and an epoxy content from 40 to 60 weight percent of the total weight of the monomers to prepare the epoxy acrylic copolymer. The other polymer of the blend has a number average molecular weight in the range of about 500 to about 3000, a calculated Tg in the range of about 35° C. to about 125° C., and an epoxy content from glycidyl functional ethylenically unsaturated monomer that is higher than that of the first epoxy functional acrylic copolymer of the blend and in the range of about 50 to about 100.
摘要翻译：可固化的粉末透明涂料组合物和具有多层涂料的涂布基材在涂层中具有作为主要成膜聚合物的至少一种环氧丙烯酸共聚物，其量为60至99.99重量％，10至40重量％的多元羧酸交联代理商重量百分比是基于可固化涂料组合物的固体。单一主要的成膜环氧丙烯酸共聚物的数均分子量在约1000至5500的范围内; 计算的Tg在50至85℃的范围内。环氧含量在35至85范围内，苯乙烯含量由苯乙烯单体的量的至多约25重量％范围内，基于形成共聚物的单体的重量百分数。环氧丙烯酸共聚物的共混物具有一种聚合物，其是单环氧丙烯酸共聚物或具有数均分子量在约1000至约10,000范围内的聚合物，计算的Tg在约40℃至85℃的范围内，并且环氧树脂含量为单体总重量的40至60重量％，以制备环氧丙烯酸共聚物。共混物的其它聚合物的数均分子量在约500至约3000的范围内，计算的Tg在约35℃至约125℃的范围内，并且来自缩水甘油基官能烯属不饱和的环氧基含量单体，高于共混物的第一环氧官能丙烯酸共聚物的单体，并且在约50至约100的范围内。

5. 发明授权

US06863982B2 Curable film-forming composition exhibiting improved yellowing resistance 失效
标题翻译：具有改善耐黄变性的可固化成膜组合物
公开(公告)号：US06863982B2
公开(公告)日：2005-03-08
申请号：US10269389
申请日：2002-10-11
申请人： Masayuki Nakajima , Charles M. Kania , Stephen G. McQuown , Karen S. Rechenberg , Susan A. Campbell , Kurt A. Humbert , Karen A. Barkac
发明人： Masayuki Nakajima , Charles M. Kania , Stephen G. McQuown , Karen S. Rechenberg , Susan A. Campbell , Kurt A. Humbert , Karen A. Barkac
IPC分类号： C08G59/30 , C08G59/32 , C08G59/42 , C09D5/03 , C09D7/12 , C09D163/00 , B32B27/38
CPC分类号： C09D163/00 , C08G59/304 , C08G59/3254 , C08G59/4284 , C09D5/036 , C09D7/63 , Y10T428/31511 , C08L2666/02
摘要： A curable film-forming composition of 5 to 95 weight percent (based on the total resin solids weight in the composition) of a crosslinking agent; 5 to 95 weight percent ot a polymer containing functional groups reactive with the crosslinking agent; and 0.01 to 15 weight percent of at least one additive selected from a reaction product of phosporous acid and: at least one diepoxide; at least one diepoxide and at least one anhydride; at least one diepoxide and at least one anhydride, chain extended with at least one diol; at least one monoepoxide and at least one anhydride, chain extended with at least one diepoxide; and mixtures thereof. The additives in the composition prevent thermal oxidation, minimizing visual effects (i.e., yellowing). A multi-component composite coating includes a base coat and a top coat which may be derived from the above curable film-forming composition.
摘要翻译：交联剂为5〜95重量％（基于组合物中树脂固体重量的总量）的可固化成膜组合物; 5至95重量％的含有与交联剂反应的官能团的聚合物; 和0.01至15重量％的至少一种选自磷酸和：至少一种二环氧化物的反应产物的添加剂; 至少一种二环氧化物和至少一种酸酐; 至少一种二环氧化物和至少一种酸酐，链与至少一种二醇延伸; 至少一种单环氧化物和至少一种酸酐，链与至少一种二环氧化物延伸; 及其混合物。组合物中的添加剂防止热氧化，使视觉效果最小化（即变黄）。多组分复合涂层包括底涂层和可以由上述可固化成膜组合物衍生的面漆。

6. 发明申请

US20110281115A1 CURABLE FILM-FORMING COMPOSITIONS CONTAINING ORTHO-HYDROXYL AROMATIC FUNCTIONAL ACRYLIC POLYMERS 有权
标题翻译：含有羟基官能丙烯酸聚合物的可固化成膜组合物
公开(公告)号：US20110281115A1
公开(公告)日：2011-11-17
申请号：US12779491
申请日：2010-05-13
申请人： Charles M. Kania , Lyle L. Foringer , Shiryn Tyebjee , Leigh Ann Humbert , Kevin C. Olson
发明人： Charles M. Kania , Lyle L. Foringer , Shiryn Tyebjee , Leigh Ann Humbert , Kevin C. Olson
IPC分类号： B32B27/00 , C08G63/52 , C08G63/181
CPC分类号： C09D133/14 , C08F8/14 , C08F212/08 , C08F2220/1858 , C08F2220/283 , C08F2220/302 , C08F2220/325 , C08K5/09 , Y10T428/31504 , C08F2220/1825 , C08F220/06 , C08L33/068
摘要： The present invention is directed to curable film-forming compositions comprising a film-forming resin and a crosslinking agent. The film-forming resin contains a polymer having functional aromatic groups derived from functional aromatic acids.The present invention further provides multi-component composite coating compositions comprising a first film-forming composition applied to a substrate to form a primer or base coat, and a second film-forming composition applied on top of the primer or base coat to form a top coat, the top coat comprising the composition described above.Coating compositions prepared from the curable compositions of the present invention demonstrate superior gloss and acid etch resistance properties, making them ideally suited for automotive applications.
摘要翻译：本发明涉及包含成膜树脂和交联剂的可固化成膜组合物。成膜树脂含有具有衍生自官能芳香族酸的官能性芳香族基团的聚合物。本发明还提供了多组分复合涂料组合物，其包含施加到基材上以形成底漆或底漆的第一成膜组合物，以及施涂在底漆或底涂层顶部上形成顶部的第二成膜组合物涂层，包括上述组合物的面漆。由本发明的可固化组合物制备的涂料组合物表现出优异的光泽和耐酸蚀性能，使其理想地适用于汽车应用。

7. 发明授权

US07794844B2 Dual cure coating compositions, multi-component composite coatings, and related coated substrates 有权
标题翻译：双固化涂料组合物，多组分复合涂料和相关的涂布基材
公开(公告)号：US07794844B2
公开(公告)日：2010-09-14
申请号：US11861703
申请日：2007-09-26
申请人： Roy E. Dean , Charles M. Kania , Cynthia Kutchko , Brian K. Rearick , William H. Retsch, Jr. , John E. Schwendeman , Shengkui Hu
发明人： Roy E. Dean , Charles M. Kania , Cynthia Kutchko , Brian K. Rearick , William H. Retsch, Jr. , John E. Schwendeman , Shengkui Hu
IPC分类号： B32B25/20
CPC分类号： C09D183/04 , C08K5/103 , C08K5/34922 , C09D183/06 , Y10T428/31663
摘要： Disclosed herein are dual cure coating compositions that include a melamine group-containing polyethylenically unsaturated compound and a polysiloxane. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.
摘要翻译：本文公开了包含含三聚氰胺基的多烯属不饱和化合物和聚硅氧烷的双重固化涂料组合物。还公开了相关的多组分复合涂层，涂覆的基底和用于涂覆基底的方法。

8. 发明申请

US20080302273A1 UV CURABLE COATING COMPOSITION AND METHOD OF MAKING 有权
标题翻译： UV可固化涂料组合物及其制备方法
公开(公告)号：US20080302273A1
公开(公告)日：2008-12-11
申请号：US11760215
申请日：2007-06-08
申请人： Charles M. Kania , Debra L. Singer , Diane J. Schillinger
发明人： Charles M. Kania , Debra L. Singer , Diane J. Schillinger
IPC分类号： C08J3/28
CPC分类号： C08G18/423 , C08G18/672 , C08G18/673 , C08G18/792 , C08G2150/20 , C08G18/42
摘要： The present invention relates to solid, particulate free film-forming compositions, multi-layer composite coatings comprising such film-forming compositions and methods of applying such multi-component composite coatings to a substrate. The solvent free film-forming compositions include UV-curable powder coating compositions comprising an amorphous (meth)acrylate terminated poly(ester-urethane) and optionally a second (meth)acrylate terminated polyurethane.
摘要翻译：本发明涉及固体，无颗粒状成膜组合物，包含这种成膜组合物的多层复合涂层以及将这种多组分复合涂层施加到基底上的方法。无溶剂的成膜组合物包括包含无定形（甲基）丙烯酸酯封端的聚（酯 - 氨基甲酸酯）和任选的第二（甲基）丙烯酸酯封端的聚氨酯）的UV固化粉末涂料组合物。

9. 发明授权

US07241830B2 Organic solvent-free film-forming compositions, multi-layer composite coatings, and related methods 失效
标题翻译：有机无溶剂成膜组合物，多层复合涂层及相关方法
公开(公告)号：US07241830B2
公开(公告)日：2007-07-10
申请号：US10841659
申请日：2004-05-07
申请人： Charles M. Kania , Roxalana L. Martin , Carolyn A. K. Novak , Thomas R. Hockswender , Mark A. Tucker , Mary Beth Grolemund , Deirdre Ragan , Alicia Williams
发明人： Charles M. Kania , Roxalana L. Martin , Carolyn A. K. Novak , Thomas R. Hockswender , Mark A. Tucker , Mary Beth Grolemund , Deirdre Ragan , Alicia Williams
IPC分类号： C08K3/20
CPC分类号： C08F212/08 , C08F212/14 , Y10T428/25 , Y10T428/256 , Y10T428/257 , Y10T428/259 , Y10T428/26 , Y10T428/31663
摘要： Provided is a film-forming composition substantially free of organic solvent which includes an aqueous dispersion of polymeric microparticles prepared by emulsion polymerization of a monomeric composition containing (1) at least 10 percent by weight of one or more vinyl aromatic compounds; (2) 0.1 to 10 percent by weight of one or more carboxylic acid functional polymerizable, ethylenically unsaturated monomers; (3) 0 to 10 percent by weight of one or more polymerizable monomers having one or more functional groups capable of reacting to form crosslinks; and (4) one or more polymerizable ethylenically unsaturated monomers. Each of (1), (2), (3) and (4) are different one from the other and at least one of (3) and (4) is present in the monomeric composition. Multi-layer composite coatings and coated substrates also are provided.
摘要翻译：本发明提供一种基本上不含有机溶剂的成膜组合物，其包括通过含有（1）至少10重量％的一种或多种乙烯基芳族化合物的单体组合物的乳液聚合制备的聚合物微粒的水性分散体; （2）0.1至10重量％的一种或多种羧酸官能可聚合的烯属不饱和单体; （3）0〜10重量％的一种或多种具有一个或多个能够反应形成交联的官能团的可聚合单体; 和（4）一种或多种可聚合的烯属不饱和单体。（1），（2），（3）和（4）中的每一个彼此不同，并且（3）和（4）中的至少一个存在于单体组合物中。还提供多层复合涂层和涂覆的基底。

10. 发明授权

US5349006A Azetidinol reaction products used as pigment grind and film forming vehicles 失效
标题翻译：氮杂环丁烷反应产物用作颜料研磨和成膜车辆
公开(公告)号：US5349006A
公开(公告)日：1994-09-20
申请号：US190967
申请日：1994-02-03
申请人： Shanti Swarup , Padmanabhan Sundararaman , Gregory J. McCollum , Charles M. Kania , James A. Claar
发明人： Shanti Swarup , Padmanabhan Sundararaman , Gregory J. McCollum , Charles M. Kania , James A. Claar
IPC分类号： C07D205/04 , C08F8/30 , C08L57/00 , C08L57/12 , C09D133/02 , C09D133/04 , C09D157/12 , C09D175/04
CPC分类号： C08F8/30
摘要： An ungelled reaction product is prepared from a carboxylic acid group containing polymeric material and an azetidinol containing material having one azetidinol moiety per molecule. The ungelled reaction product is particularly useful as a grind vehicle for pigment grind compositions.
摘要翻译：由含羧酸基的聚合物材料和含有氮杂环丁烷的材料每分子制备一个氮杂环丁烷部分制备未凝胶化的反应产物。未凝胶化的反应产物特别可用作用于颜料研磨组合物的研磨载体。

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