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1. 发明授权

US4113592A Trihalogenated hydrocarbons as co-photoinitiators 失效
标题翻译：三卤代烃作为共光引发剂
公开(公告)号：US4113592A
公开(公告)日：1978-09-12
申请号：US568216
申请日：1975-04-14
申请人： Charles B. Rybny , John C. Trebellas , Donald E. Sargent
发明人： Charles B. Rybny , John C. Trebellas , Donald E. Sargent
IPC分类号： C08F2/48 , C08F2/50 , C08F8/00 , C08F2/46
CPC分类号： C08F2/50 , Y10S430/124 , Y10S430/126 , Y10S525/922
摘要： The use of terminal trichlorinated, brominated or iodinated hydrocarbons as co-photoinitiators in combination with standard photoinitiators in ultraviolet curable coating compositions is disclosed.
摘要翻译：公开了在紫外线固化涂料组合物中使用末端三氯化，溴化或碘化烃作为共光引发剂与标准光引发剂的组合。

2. 发明授权

US4130518A Preparation of acrylated or methacrylated polymers utilizing a partially solubilized hydrocarbon fraction as the azeotroping medium 失效
$Preparation of acrylated or methacrylated polymers utilizing a partially solubilized hydrocarbon fraction as the azeotroping medium$
标题翻译：使用部分溶解的烃馏分作为共沸介质制备丙烯酸酯化或甲基丙烯酸酯化的聚合物
公开(公告)号：US4130518A
公开(公告)日：1978-12-19
申请号：US853611
申请日：1977-11-21
申请人： Charles B. Rybny , Eli Levine
发明人： Charles B. Rybny , Eli Levine
IPC分类号： C08F8/14 , G03F7/038 , C08L91/00 , C08G63/12
CPC分类号： G03F7/0388 , C08F8/14
摘要： There is disclosed a process for conveniently preparing polymers having pendant ultraviolet polymerizable groups which involves co-reacting a polymer containing the C-X moiety with a monomer having the general formula ##STR1## wherein X is OH or COOH and Y is OH when X is OH, and OR'OH when X is COOH, wherein R is hydrogen or methyl and R' is C.sub.1 -C.sub.6 alkyl. This process is carried out utilizing a partially solubilized hydrocarbon fraction as the azeotroping medium.
摘要翻译：公开了一种方便地制备具有侧向紫外线可聚合基团的聚合物的方法，其涉及使含有CX部分的聚合物与具有通式“IMAGE”的单体共反应，其中当X是OH时，X是OH或COOH，Y是OH，当X为COOH时为OR'OH，其中R为氢或甲基，R'为C1-C6烷基。该方法使用部分溶解的烃馏分作为共沸介质进行。

3. 发明授权

US09441123B2 Cationic water based polymers for ink, coating, and film applications 有权
标题翻译：用于油墨，涂料和薄膜应用的阳离子水基聚合物
公开(公告)号：US09441123B2
公开(公告)日：2016-09-13
申请号：US13586123
申请日：2012-08-15
申请人： Michael D. Spiegel , Charles B. Rybny
发明人： Michael D. Spiegel , Charles B. Rybny
IPC分类号： C08F255/00 , C08F259/04 , C08F261/04 , C08F263/04 , C08J3/03 , C09D11/00 , C09D11/10 , C09D11/30
CPC分类号： C08F261/04 , C08F259/04 , C08F263/04 , C09D11/10 , C09D11/107 , C09D11/30 , C09D151/003
摘要： The present invention provides a durable, external surfactant free, cationic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable amine-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.
摘要翻译：本发明提供了耐久的外部表面活性剂，阳离子型水基喷墨油墨聚合物，其在配制成喷墨油墨时形成与金属或塑料基材具有优异粘附性的印刷。这种喷墨油墨聚合物是目前商业上使用的溶剂可溶性聚合物的合适的性能替代品。杂化共聚物包含由聚硅氧烷聚合物，聚烯烃聚合物或官能聚乙烯基聚合物组成的疏水官能聚合物主链。杂化共聚物还包括连接到主链上的多个共聚侧链，包含可聚合的含胺不饱和单体和可聚合的不饱和单体。使用本发明的油墨增强了性能标准，例如打印头打开时间，油墨稳定性和对典型的水基清洁剂的耐受性。

4. 发明申请

US20110159421A1 Production of Toner for Use in Printing Applications 有权
标题翻译：生产用于印刷应用的墨粉
公开(公告)号：US20110159421A1
公开(公告)日：2011-06-30
申请号：US12672208
申请日：2009-01-15
申请人： Choung Lai , Ronald W. Schuck , Charles B. Rybny
发明人： Choung Lai , Ronald W. Schuck , Charles B. Rybny
IPC分类号： G03G9/08
CPC分类号： G03G9/0806 , G03G9/09783
摘要： The present invention provides a process for producing a colored toner comprising the steps of: providing a polymer composition comprising at least one polymer wherein the at least one polymer has a softening temperature from about 30° C. to about 160° C.; and a colorant; forming an aqueous mineral suspension of at least one multivalent metal phosphate by contacting a water-soluble salt of the multivalent metal with an aqueous solution comprising: a water-soluble phosphate salt; and at least one crystal growth inhibitor which controls the growth of the at least one multivalent metal phosphate, wherein the pH of the aqueous mineral suspension is from 5.5 to 14; and forming a dispersion of the polymer composition by adding the polymer composition to the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition, wherein the temperature of the aqueous mineral suspension during the dispersing step is at least about 70° C.
摘要翻译：本发明提供一种生产彩色调色剂的方法，包括以下步骤：提供包含至少一种聚合物的聚合物组合物，其中所述至少一种聚合物的软化温度为约30℃至约160℃; 和着色剂; 通过使多价金属的水溶性盐与水溶液接触，形成至少一种多价金属磷酸盐的水性矿物悬浮液，所述水溶液包含：水溶性磷酸盐; 和至少一种控制所述至少一种多价金属磷酸盐生长的晶体生长抑制剂，其中所述含水矿物悬浮液的pH为5.5至14; 以及通过在搅拌下将聚合物组合物加入到水性矿物悬浮液中形成聚合物组合物的分散体，以形成包含聚合物组合物分散颗粒的固体部分，其中分散步骤期间的含水矿物悬浮液的温度为至少约70 C。

5. 发明授权

US08652745B2 Ink toner particles with controlled surface morphology 失效
标题翻译：具有受控表面形态的墨粉调色剂颗粒
公开(公告)号：US08652745B2
公开(公告)日：2014-02-18
申请号：US13554437
申请日：2012-07-20
申请人： Ronald W. Schuck , Charles B. Rybny , Choung Lai
发明人： Ronald W. Schuck , Charles B. Rybny , Choung Lai
IPC分类号： G03G5/00
CPC分类号： G03G9/0804 , G03G9/0819 , G03G9/0821 , G03G9/08711 , G03G9/08753 , G03G9/08755 , G03G9/08764 , G03G9/08795 , G03G9/08797 , G03G9/09708 , G03G9/09725
摘要： The present invention provides a process for producing a colored toner having a textured surface, the process includes forming a polymer composition of at least one polymer and a colorant, where the at least one polymer has a softening temperature from about 60° C. to about 160° C.; forming an aqueous mineral suspension of at least one multivalent metal phosphate; forming a dispersion by combining the polymer composition and the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition; heating the dispersion to a temperature above a glass transition temperature (Tg) of the polymer composition and increasing the pH to above 7.0; cooling the dispersion including the dispersed particles of the polymer composition to a temperature of from about 1° C. to about 89° C.; and recovering the particles.
摘要翻译：本发明提供了一种生产具有纹理表面的着色调色剂的方法，该方法包括形成至少一种聚合物和着色剂的聚合物组合物，其中至少一种聚合物的软化温度为约60℃至约 160℃。形成至少一种多价金属磷酸盐的水性矿物悬浮液; 通过在搅拌下组合聚合物组合物和含水矿物悬浮液以形成包含聚合物组合物的分散颗粒的固体部分来形成分散体; 将分散体加热到高于聚合物组合物的玻璃化转变温度（Tg）的温度并将pH增加至7.0以上; 将包含聚合物组合物的分散颗粒的分散体冷却至约1℃至约89℃的温度; 并回收颗粒。

6. 发明授权

US08247155B2 Production of toner for use in printing applications 有权
标题翻译：生产用于印刷应用的调色剂
公开(公告)号：US08247155B2
公开(公告)日：2012-08-21
申请号：US12672208
申请日：2009-01-15
申请人： Choung Lai , Ronald W. Schuck , Charles B. Rybny
发明人： Choung Lai , Ronald W. Schuck , Charles B. Rybny
IPC分类号： G03G5/00
CPC分类号： G03G9/0806 , G03G9/09783
摘要： The present invention provides a process for producing a colored toner comprising the steps of: providing a polymer composition comprising at least one polymer wherein the at least one polymer has a softening temperature from about 30° C. to about 160° C.; and a colorant; forming an aqueous mineral suspension of at least one multivalent metal phosphate by contacting a water-soluble salt of the multivalent metal with an aqueous solution comprising: a water-soluble phosphate salt; and at least one crystal growth inhibitor which controls the growth of the at least one multivalent metal phosphate, wherein the pH of the aqueous mineral suspension is from 5.5 to 14; and forming a dispersion of the polymer composition by adding the polymer composition to the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition, wherein the temperature of the aqueous mineral suspension during the dispersing step is at least about 70° C.
摘要翻译：本发明提供一种生产彩色调色剂的方法，包括以下步骤：提供包含至少一种聚合物的聚合物组合物，其中所述至少一种聚合物的软化温度为约30℃至约160℃; 和着色剂; 通过使多价金属的水溶性盐与水溶液接触，形成至少一种多价金属磷酸盐的水性矿物悬浮液，所述水溶液包含：水溶性磷酸盐; 和至少一种控制所述至少一种多价金属磷酸盐生长的晶体生长抑制剂，其中所述含水矿物悬浮液的pH为5.5至14; 以及通过在搅拌下将聚合物组合物加入到水性矿物悬浮液中形成聚合物组合物的分散体，以形成包含聚合物组合物分散颗粒的固体部分，其中分散步骤期间的含水矿物悬浮液的温度为至少约70 C。

7. 发明授权

US4194955A Ultraviolet curable self-pigmented coating composition 失效
标题翻译：紫外线固化自色涂料组合物
公开(公告)号：US4194955A
公开(公告)日：1980-03-25
申请号：US960203
申请日：1978-11-13
申请人： Michael T. Nowak , Charles B. Rybny
发明人： Michael T. Nowak , Charles B. Rybny
IPC分类号： C08F2/50 , C08F261/08 , C09D129/14 , C08F8/00 , C08G2/02
CPC分类号： C08F261/08 , C09D129/14 , Y10S525/931 , Y10T428/31627 , Y10T428/31649 , Y10T428/31688 , Y10T428/31692
摘要： This invention provides a substantially transparent curable coating composition which upon curing with ultraviolet radiation converts into a glossy opaque film.The invention ultraviolet radiation curable coating composition comprises a homogeneous blend of (1) polyvinyl butyral, (2) vinyl acetate, (3) trimethylolpropane triacrylate and/or pentaerythritol triacrylate, and (4) a photoinitiator.
摘要翻译：本发明提供了基本上透明的可固化涂料组合物，其在用紫外线辐射固化时转化为光泽不透明膜。本发明紫外线辐射固化涂料组合物包含（1）聚乙烯醇缩丁醛，（2）乙酸乙烯酯，（3）三羟甲基丙烷三丙烯酸酯和/或季戊四醇三丙烯酸酯的均匀混合物，和（4）光引发剂。

8. 发明授权

US3992276A Unsaturated polyesters for ultraviolet curable coatings 失效
标题翻译：用于紫外线固化涂料的不饱和聚酯
公开(公告)号：US3992276A
公开(公告)日：1976-11-16
申请号：US558977
申请日：1975-03-17
申请人： Thomas M. Powanda , Charles B. Rybny , Charles A. DeFazio
发明人： Thomas M. Powanda , Charles B. Rybny , Charles A. DeFazio
IPC分类号： C08F2/48 , C08F265/04 , C08G63/52 , C08F8/00 , C08L33/12 , C08L67/06
CPC分类号： C08G63/52 , C08F265/04 , Y10T428/31681
摘要： An ultraviolet curable coating composition having improved clarity and resin compatability is prepared by co-reacting an acrylate or methacrylate co-polymer containing hydroxy and carboxy groups with added polyol and maleic anhydride to form an unsaturated polyester, and then blending the unsaturated polyester with polyunsaturated monomers, monounsaturated monomers and a photoinitiator, all of which will cure when exposed to ultraviolet radiation.
摘要翻译：通过使含有羟基和羧基的丙烯酸酯或甲基丙烯酸酯共聚物与加成的多元醇和马来酸酐共聚而形成不饱和聚酯，然后将不饱和聚酯与多不饱和单体共混，制备具有改善的透明度和树脂相容性的紫外线固化涂料组合物，单不饱和单体和光引发剂，所有这些都会在暴露于紫外线辐射下固化。

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