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1. 发明授权

US5786110A Alkali-metal-ion conducting electrolytes 失效
标题翻译：碱金属离子导电电解质
公开(公告)号：US5786110A
公开(公告)日：1998-07-28
申请号：US471840
申请日：1995-06-06
申请人： C. Austen Angell , Changle Liu , Kang Xu
发明人： C. Austen Angell , Changle Liu , Kang Xu
IPC分类号： H01B1/06 , H01M6/14 , H01M6/16 , H01M6/18 , H01M10/36
CPC分类号： H01M10/0563 , H01M10/052 , H01M10/0565 , H01M6/14 , H01M6/162 , H01M6/18 , H01M6/181 , H01M2300/0037 , H01M2300/0085 , H01M6/164 , H01M6/166
摘要： High-conductivity alkali-metal-ion containing electrolytes comprising viscous liquid or rubbery solid alkali metal salts which obtain conductivity by the domainate motion of cation ions which, when produced in accordance herewith, remain freely mobile at low temperatures. One embodiment relates to molten alkali metal salt electrolytes comprised of one or more alkali metal salt compositions which are substantially non-crystalline and have glass transition temperatures below room temperature.
摘要翻译：包含粘性液体或橡胶状固体碱金属盐的高电导率碱金属离子的电解质，其通过阳离子离子的结构运动获得导电性，当根据本文生产时，它们在低温下可自由移动。一个实施方案涉及由一种或多种碱金属盐组合物组成的熔融碱金属盐电解质，其基本上非结晶且玻璃化转变温度低于室温。

2. 发明授权

US5484670A Lithium ion conducting ionic electrolytes 失效
标题翻译：锂离子导电离子电解质
公开(公告)号：US5484670A
公开(公告)日：1996-01-16
申请号：US262158
申请日：1994-06-20
申请人： C. Austen Angell , Kang Xu , Changle Liu
发明人： C. Austen Angell , Kang Xu , Changle Liu
IPC分类号： H01B1/06 , H01M6/14 , H01M6/16 , H01M6/18 , H01M10/36
CPC分类号： H01M6/14 , H01M10/052 , H01M10/0563 , H01M10/0565 , H01M6/18 , H01M6/181 , H01M2300/0037 , H01M2300/0085 , H01M6/164 , H01M6/166
摘要： A liquid, predominantly lithium-conducting, ionic electrolyte is described which has exceptionally high conductivity at temperatures of 100.degree. C. or lower, including room temperature. It comprises molten lithium salts or salt mixtures in which a small amount of an anionic polymer lithium salt is dissolved to stabilize the liquid against recrystallization. Further, a liquid ionic electrolyte which has been rubberized by addition of an extra proportion of anionic polymer, and which has good chemical and electrochemical stability, is described. This presents an attractive alternative to conventional salt-in-polymer electrolytes which are not cationic conductors.
摘要翻译：描述了液体，主要是锂导电的离子电解质，其在100℃或更低的温度（包括室温）下具有特别高的导电性。它包括其中溶解少量阴离子聚合物锂盐的熔融锂盐或盐混合物，以稳定液体以防再结晶。此外，描述了通过添加额外比例的阴离子聚合物而被橡胶化并且具有良好的化学和电化学稳定性的液体离子电解质。这对于不是阳离子导体的常规盐 - 聚合物电解质来说是一个有吸引力的替代方案。

3. 发明授权

US5506073A Lithium ion conducting electrolytes 失效
标题翻译：锂离子传导电解质
公开(公告)号：US5506073A
公开(公告)日：1996-04-09
申请号：US901669
申请日：1992-06-22
申请人： C. Austen Angell , Changle Liu
发明人： C. Austen Angell , Changle Liu
IPC分类号： H01B1/06 , H01M6/14 , H01M6/16 , H01M6/18 , H01M10/36
CPC分类号： H01M10/0563 , H01M10/052 , H01M10/0565 , H01M6/14 , H01M6/18 , H01M6/181 , H01M2300/0037 , H01M2300/0085 , H01M6/164 , H01M6/166
摘要： A liquid, predominantly lithium-conducting, ionic electrolyte having exceptionally high conductivity at temperatures of 100.degree. C. or lower, including room temperature, and comprising the lithium salts selected from the group consisting of the thiocyanate, iodide, bromide, chloride, perchlorate, acetate, tetrafluoroborate, perfluoromethane sulfonate, perfluoromethane sulfonamide, tetrahaloaluminate, and heptahaloaluminate salts of lithium, with or without a magnesium-salt selected from the group consisting of the perchlorate and acetate salts of magnesium. Certain of the latter embodiments may also contain molecular additives from the group of acetonitrile (CH.sub.3 CN) succinnonitrile (CH.sub.2 CN).sub.2, and tetraglyme (CH.sub.3 --O--CH.sub.2 --CH.sub.2 --O--).sub.2 (or like solvents) solvated to a Mg.sup.+2 cation to lower the freezing point of the electrolyte below room temperature. Other particularly useful embodiments contain up to about 40, but preferably not more than about 25, mol percent of a long chain polyether polymer dissolved in the lithium salts to provide an elastic or rubbery solid electrolyte of high ambient temperature conductivity and exceptional 100.degree. C. conductivity. Another embodiment contains up to about but not more than 10 mol percent of a molecular solvent such as acetone.
摘要翻译：在100℃或更低的温度（包括室温）下具有特别高导电性的液体，主要为锂导电的离子电解质，并且包含选自硫氰酸盐，碘化物，溴化物，氯化物，高氯酸盐，乙酸盐，四氟硼酸盐，全氟甲烷磺酸盐，全氟甲烷磺酰胺，四卤铝酸盐和锂的七卤铝酸盐，具有或不具有选自镁的高氯酸盐和乙酸盐的镁盐。后一个实施方案中的某些可能还含有溶剂化为Mg + 2的乙腈（CH 3 CN）琥珀腈（CH 2 CN）2和四缩水甘油醚（CH3-O-CH2-CH2-O-）2（或类似溶剂）的分子添加剂阳离子将电解液的凝固点降低到室温以下。其他特别有用的实施方案包含高达约40，但优选不超过约25摩尔％的溶解在锂盐中的长链聚醚聚合物，以提供高环境温度导电性和特殊的100℃的弹性或橡胶状固体电解质。电导率。另一个实施方案含有至多约10摩尔％的分子溶剂如丙酮，但不超过10摩尔％。

4. 发明申请

US20160043431A1 INORGANIC PLASTIC CRYSTAL ELECTROLYTES 审中-公开
标题翻译：无机塑料晶体电解质
公开(公告)号：US20160043431A1
公开(公告)日：2016-02-11
申请号：US14775215
申请日：2014-03-14
申请人： C. Austen ANGELL , Iolanda Santana KLEIN , Telpriore Greg TUCKER
发明人： C. Austen Angell , Iolanda Santana Klein , Telpriore Greg Tucker
IPC分类号： H01M10/0562 , H01M10/0525
CPC分类号： H01M10/0562 , H01M10/0525 , H01M2300/0071 , H01M2300/0091
摘要： Inorganic plastic crystal electrolytes, also referred to herein as inorganic plastic crystal conductors or single ion conductors including [ABx-yCy]y−[M]y+, where A is a tetravalent to hexavalent atom; B is a monovalent ligand; C is an oxyanion; M is an alkali metal; x is 4 when A is tetravalent, x is 5 when A is pentavalent, and x is 6 when A is hexavalent; y is an integer from 1 to x−1 inclusive. [ABx-yCy]y−[M]y+ is rotationally disordered and electrically conductive.
摘要翻译：无机塑料晶体电解质，本文也称为无机塑料晶体导体或包含[ABx-yCy] y- [M] y +的单离子导体，其中A为四价至六价原子; B是一价配体; C是氧阴离子; M是碱金属; 当A为四价时x为4，A为五价时x为5，A为六价时x为6; y为1〜x-1的整数。 [ABx-yCy] y- [M] y +是旋转地无序并导电的。

5. 发明申请

US20180309170A1 BATTERY WITH ALUMINUM-CONTAINING CATHODE 审中-公开
公开(公告)号：US20180309170A1
公开(公告)日：2018-10-25
申请号：US15956630
申请日：2018-04-18
申请人： C. Austen Angell , Leigang Xue
发明人： C. Austen Angell , Leigang Xue
IPC分类号： H01M10/39 , H01M2/16 , H01M4/38
CPC分类号： H01M10/399 , H01M2/1646 , H01M2/1686 , H01M4/381 , H01M2300/0057
摘要： A battery includes an anode chamber configured to contain an anolyte and including an anode, a cathode chamber configured to contain a catholyte including a cathode, and a separator between the anode chamber and the cathode chamber. The anode includes sodium, and the cathode includes aluminum. The battery is configured to be operated above a melting point of the anolyte and the catholyte, such that the anolyte is a molten anolyte and the catholyte is a molten catholyte.

6. 发明申请

US20170237101A1 PHOSPHORIC ACID-BASED ELECTROLYTES AND APPLICATIONS THEREOF 有权
公开(公告)号：US20170237101A1
公开(公告)日：2017-08-17
申请号：US15587107
申请日：2017-05-04
申请人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
发明人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
IPC分类号： H01M8/086
CPC分类号： H01M8/086 , H01B1/06 , H01M8/0289 , H01M8/1016 , H01M8/1048 , H01M2300/0008 , H01M2300/0068 , H01M2300/0085 , H01M2300/0091
摘要： A liquid electrolyte formed by reacting phosphoric acid (H3PO4) in the liquid state with silicon tetrachloride (SiCl4), thereby forming a fluid suspension. The fluid suspension is heated to yield a liquid electrolyte including phosphoric acid (H3PO4), pyrophosphoric acid (H4P2O7), and a particulate solid comprising a silicophosphoric acid, wherein the silicophosphoric acid is an acidic molecular compound including silicon and phosphorus. A concentrated silicophosphoric acid composition prepared by removing most of the liquid from the liquid electrolyte is dissolved in water to yield a homogeneous solution. The homogeneous solution is dried to yield a solid electrolyte. In some cases, the homogenous solution is dried on a substrate to coat at least a portion of the substrate with a proton conductive solid electrolyte. A fuel cell may include the liquid electrolyte, the solid electrolyte, or the coated substrate.

7. 发明申请

US20150270568A1 PHOSPHORIC ACID-BASED ELECTROLYTES AND APPLICATIONS THEREOF 有权
标题翻译：基于磷酸的电解质及其应用
公开(公告)号：US20150270568A1
公开(公告)日：2015-09-24
申请号：US14621707
申请日：2015-02-13
申请人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
发明人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
IPC分类号： H01M8/10 , H01M8/02
CPC分类号： H01M8/086 , H01B1/06 , H01M8/0289 , H01M8/1016 , H01M8/1048 , H01M2300/0008 , H01M2300/0068 , H01M2300/0085 , H01M2300/0091
摘要： A liquid electrolyte formed by reacting phosphoric acid (H3PO4) in the liquid state with silicon tetrachloride (SiCl4), thereby forming a fluid suspension. The fluid suspension is heated to yield a liquid electrolyte including phosphoric acid (H3PO4), pyrophosphoric acid (H4P2O7), and a particulate solid comprising a silicophosphoric acid, wherein the silicophosphoric acid is an acidic molecular compound including silicon and phosphorus. A concentrated silicophosphoric acid composition prepared by removing most of the liquid from the liquid electrolyte is dissolved in water to yield a homogeneous solution. The homogeneous solution is dried to yield a solid electrolyte. In some cases, the homogenous solution is dried on a substrate to coat at least a portion of the substrate with a proton conductive solid electrolyte. A fuel cell may include the liquid electrolyte, the solid electrolyte, or the coated substrate.
摘要翻译：通过使液态磷酸（H 3 PO 4）与四氯化硅（SiCl 4）反应形成的液体电解质，从而形成流体悬浮液。将流体悬浮液加热以产生包括磷酸（H 3 PO 4），焦磷酸（H 4 P 2 O 7）和包含硅磷酸的颗粒固体的液体电解质，其中硅磷酸是包括硅和磷的酸性分子化合物。通过从液体电解质中除去大部分液体而制备的浓缩硅磷酸组合物溶于水中以得到均匀的溶液。将均匀溶液干燥以产生固体电解质。在一些情况下，将均匀的溶液在基材上干燥以用质子传导性固体电解质涂覆至少一部分基材。燃料电池可以包括液体电解质，固体电解质或涂覆的基底。

8. 发明授权

US10686224B2 Battery with aluminum-containing cathode 有权
公开(公告)号：US10686224B2
公开(公告)日：2020-06-16
申请号：US15956630
申请日：2018-04-18
申请人： C. Austen Angell , Leigang Xue
发明人： C. Austen Angell , Leigang Xue
IPC分类号： H01M10/39 , H01M2/16 , H01M4/38
摘要： A battery includes an anode chamber configured to contain an anolyte and including an anode, a cathode chamber configured to contain a catholyte including a cathode, and a separator between the anode chamber and the cathode chamber. The anode includes sodium, and the cathode includes aluminum. The battery is configured to be operated above a melting point of the anolyte and the catholyte, such that the anolyte is a molten anolyte and the catholyte is a molten catholyte.

9. 发明授权

US07867658B2 Ionic liquids and ionic liquid acids with high temperature stability for fuel cell and other high temperature applications, method of making and cell employing same 有权
标题翻译：用于燃料电池和其他高温应用的离子液体和离子液体酸具有高温稳定性，制备方法和使用细胞的方法
公开(公告)号：US07867658B2
公开(公告)日：2011-01-11
申请号：US10555468
申请日：2004-05-03
申请人： C. Austen Angell , Wu Xu , Jean-Philippe Belieres , Masahiro Yoshizawa
发明人： C. Austen Angell , Wu Xu , Jean-Philippe Belieres , Masahiro Yoshizawa
IPC分类号： H01M8/00 , H01M8/08
CPC分类号： H01M8/144 , H01M8/1016 , H01M8/14 , H01M2300/0005 , H01M2300/0022 , H01M2300/0048 , H01M2300/0054 , H01M2300/0062 , H01M2300/0085 , H01M2300/0091 , Y02P70/56
摘要： Disclosed are developments in high temperature fuel cells including ionic liquids with high temperature stability and the storage of inorganic acids as di-anion salts of low volatility. The formation of ionically conducting liquids of this type having conductivities of unprecedented magnitude for non-aqueous systems is described. The stability of the di-anion configuration is shown to play a role in the high performance of the non-corrosive proton-transfer ionic liquids as high temperature fuel cell electrolytes. Performance of simple H2(g) electrolyte/O2(g) fuel cells with the new electrolytes is described. Superior performance both at ambient temperature and temperatures up to and above 200° C. are achieved. Both neutral proton transfer salts and the acid salts with HSO−4 anions, give good results, the bisulphate case being particularly good at low temperatures and very high temperatures. The performance of all electrolytes is improved by the addition of a small amount of involatile base of pKa value intermediate between those of the acid and base that make the bulk electrolyte. The preferred case is the imidazole-doped ethylammonium hydrogensulfate which yields behavior superior in all respects to that of the industry standard phosphoric acid electrolyte.
摘要翻译：公开了高温燃料电池的发展，包括具有高温稳定性的离子液体和无机酸作为低挥发性的二阴离子盐的储存。描述了具有前所未有的非水系统电导率的这种离子导电液体的形成。二阴离子配置的稳定性显示出在非腐蚀性质子转移离子液体作为高温燃料电池电解质的高性能中起作用。描述了具有新电解质的简单H 2（g）电解质/ O 2（g）燃料电池的性能。在环境温度和高于和高于200℃的温度下都能实现卓越的性能。两种中性质子转移盐和与HSO-4阴离子的酸式盐都具有良好的结果，硫酸氢盐的情况在低温和非常高的温度下特别好。所有电解质的性能通过在制造本体电解质的酸和碱之间添加少量pKa值的非挥发性碱而提高。优选的情况是咪唑掺杂的硫酸氢铵，其产生的行为在所有方面都优于工业标准磷酸电解质。

10. 发明授权

US5518970A Nitride glasses and methods of making same 失效
标题翻译：氮化玻璃及其制作方法
公开(公告)号：US5518970A
公开(公告)日：1996-05-21
申请号：US447534
申请日：1995-05-24
申请人： Paul F. McMillan , C. Austen Angell , Tor Grande , John R. Holloway
发明人： Paul F. McMillan , C. Austen Angell , Tor Grande , John R. Holloway
IPC分类号： C03B19/09 , C03C3/32 , C03C3/16
CPC分类号： C03B19/09 , C03C3/328 , C03B2201/70 , C03B2201/80 , Y10S501/901
摘要： The present invention relates generally to a novel and unique class of gly materials and methods of making such materials in which substantially all of the anions are nitride ions, in contrast to the oxide ions of conventional optical glasses, or the fluoride ions of the more recently discovered fluoride optical glasses. The chemical nature of these new glasses dispose the glassy materials to a remarkable combination of desirable properties, including, but not limited to, high hardness, high refractive index and high softening temperature.
摘要翻译：本发明一般涉及一种新颖而独特的玻璃质材料及其制造方法，其中基本上所有的阴离子都是氮化物离子，与传统的光学眼镜的氧化物离子相比，更近的是氟离子发现氟化物光学眼镜。这些新玻璃的化学性质将玻璃状材料配置成所需性能的显着组合，包括但不限于高硬度，高折射率和高软化温度。

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