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    • 1. 发明授权
    • Methods of etching platinum group metal film and forming lower electrode of capacitor
    • 蚀刻铂族金属膜并形成电容器的下电极的方法
    • US06169009A
    • 2001-01-02
    • US09203337
    • 1998-12-02
    • Byong-sun JuHyoun-woo KimChang-jin KangJoo-tae MoonByeong-yun Nam
    • Byong-sun JuHyoun-woo KimChang-jin KangJoo-tae MoonByeong-yun Nam
    • H01L2120
    • C23F4/00H01L21/32136H01L28/60
    • A method of etching a platinum group metal film uses a gas mixture containing argon (Ar), oxygen (O2) and halogen gases and a method of forming a lower electrode of a capacitor uses the etching method. The gas mixture contains O2, Ar, and a third component, preferably a halogen, e.g., chlorine (Cl2) or hydrogen bromide (HBr). In the method of forming a lower electrode, a conductive film containing a metal belonging to a platinum (Pt) group is formed on a semiconductor substrate, a hard mask partially exposing the conductive film is then formed on the conductive film. Then, the exposed conductive film is dry-etched using the hard mask as an etching mask and a three-component gas mixture containing argon (Ar) and oxygen (O2), to form a conductive film pattern beneath the hard mask, and the hard mask is then removed.
    • 蚀刻铂族金属膜的方法使用包含氩(Ar),氧(O 2)和卤素气体的气体混合物,并且形成电容器的下电极的方法使用蚀刻方法。 气体混合物含有O 2,Ar和第三组分,优选卤素,例如氯(Cl 2)或溴化氢(HBr)。 在形成下电极的方法中,在半导体衬底上形成含有属于铂(Pt)基团的金属的导电膜,然后在导电膜上形成部分地暴露导电膜的硬掩模。 然后,使用硬掩模作为蚀刻掩模和含有氩(Ar)和氧(O 2)的三组分气体混合物来干燥暴露的导电膜,以在硬掩模下形成导电膜图案,并且硬 然后取下面具。
    • 4. 发明授权
    • Method for manufacturing a photoresist pattern defining a small opening and method for manufacturing semiconductor device using the same
    • 用于制造限定小开口的光致抗蚀剂图案的方法和使用其制造半导体器件的方法
    • US06284438B1
    • 2001-09-04
    • US09420555
    • 1999-10-19
    • Sang-jun ChoiYool KangSi-hyeung LeeJoo-tae Moon
    • Sang-jun ChoiYool KangSi-hyeung LeeJoo-tae Moon
    • G03F726
    • G03F7/40G03F7/0045G03F7/039
    • A method for manufacturing a photoresist pattern that defines an opening having a small size, and a method for manufacturing a semiconductor device using the same are provided. A photoresist pattern defining the opening can be formed using a photoresist composition that includes either polymer mixture I containing a polymer A in which an acid-labile di-alkyl malonate group is pendant to the polymer backbone, and a polymer B in which a group that thermally decomposes at a temperature lower than the glass transition temperature of the polymer B itself is pendant to the polymer backbone, or polymer mixture II containing the polymer B and a polymer C including a (meth)acrylate as a monomer, as a main component. The size of the opening then can be reduced by thermal flowing the photoresist pattern. It is possible to form the photoresist pattern defining an opening having a small size since the photoresist composition comprises the polymer mixture which has advantageous characteristics, such as high contrast, and in which the flow rate of the composition upon thermal flowing can easily be controlled.
    • 提供了限定具有小尺寸的开口的光致抗蚀剂图案的制造方法以及使用其的半导体装置的制造方法。 可以使用光致抗蚀剂组合物形成限定开口的光致抗蚀剂图案,该光致抗蚀剂组合物包括含有聚合物A的聚合物混合物I,其中酸不稳定的二烷基丙二酸酯基团悬挂于聚合物主链,聚合物B, 在低于聚合物B本身的玻璃化转变温度的温度下热分解为聚合物主链,或含有聚合物B的聚合物混合物II和包含(甲基)丙烯酸酯作为单体的聚合物C作为主要成分。 然后可以通过光致抗蚀剂图案的热流动来减小开口的尺寸。 可以形成限定具有小尺寸的开口的光致抗蚀剂图案,因为光致抗蚀剂组合物包含聚合物混合物,其具有诸如高对比度的有利特征,并且其中组合物在热流动时的流速可以容易地被控制。
    • 6. 发明授权
    • Methods for forming line patterns in semiconductor substrates
    • 在半导体衬底中形成线图案的方法
    • US06485895B1
    • 2002-11-26
    • US09533770
    • 2000-03-23
    • Sang-jun ChoiYool KangJoo-tae MoonJeong-hee ChungSang-gyun Woo
    • Sang-jun ChoiYool KangJoo-tae MoonJeong-hee ChungSang-gyun Woo
    • G03F740
    • G03F7/40
    • A method for forming a fine pattern in a semiconductor substrate, comprises the steps of (a) coating a target layer to be etched on a semiconductor substrate with a resist composition comprising at least one compound capable of forming a photoresist pattern by a photolithography process, and a free radical initiator, wherein the free radical initiator is one which is capable of being decomposed by a thermal process at a temperature equal to or higher than the glass transition temperature of the at least one compound, wherein said coating step results in forming a resist compound layer comprising the resist composition; (b) performing a lithography process on the resist compound layer to form a photoresist pattern of at least one opening having a first width, wherein the target layer is exposed through the first width; and (c) heating the resist compound layer having the photoresist pattern formed therein to a temperature equal to or higher than the glass transition temperature of the at least one compound, and wherein a partial cross-linking reaction in the resist composition occurs by the free radicals produced from the free radical initiator resulting in a modified photoresist pattern having at least one opening having a second width which exposes the target layer, wherein the second width is smaller than the first width.
    • 一种用于在半导体衬底中形成精细图案的方法,包括以下步骤:(a)用包含至少一种能够通过光刻工艺形成光致抗蚀剂图案的化合物的抗蚀剂组合物在半导体衬底上涂覆待蚀刻的靶层, 和自由基引发剂,其中所述自由基引发剂是能够在等于或高于所述至少一种化合物的玻璃化转变温度的温度下通过热处理分解的引发剂,其中所述涂布步骤导致形成 抗蚀剂化合物层,其包含抗蚀剂组合物; (b)对抗蚀剂化合物层进行光刻处理以形成具有第一宽度的至少一个开口的光致抗蚀剂图案,其中目标层通过第一宽度暴露; 和(c)将其中形成有光致抗蚀剂图案的抗蚀剂化合物层加热到等于或高于至少一种化合物的玻璃化转变温度的温度,并且其中抗蚀剂组合物中的部分交联反应通过自由基 由自由基引发剂产生的自由基导致具有至少一个具有暴露目标层的第二宽度的开口的改性光致抗蚀剂图案,其中第二宽度小于第一宽度。
    • 7. 发明授权
    • Methods for forming line patterns in semiconductor substrates
    • 在半导体衬底中形成线图案的方法
    • US06803176B2
    • 2004-10-12
    • US10227067
    • 2002-08-23
    • Sang-jun ChoiYool KangJoo-tae MoonJeong-hee ChungSang-gyun Woo
    • Sang-jun ChoiYool KangJoo-tae MoonJeong-hee ChungSang-gyun Woo
    • G03F740
    • G03F7/40
    • A method for forming a fine pattern in a semiconductor substrate, by coating a target layer to be etched on a semiconductor substrate with a resist composition including at least one compound capable of forming a photoresist pattern by a photolithography process, and a free radical initiator. The free radical initiator is capable of being decomposed by a thermal process at a temperature equal to or higher than the glass transition temperature of the at least one compound. A lithography process is performed on the resist compound layer to form a photoresist pattern. The resist compound layer having the photoresist pattern formed therein is heated to a temperature equal to or higher than the glass transition temperature of the at least one compound, and wherein a partial cross-linking reaction in the resist composition occurs.
    • 一种在半导体衬底中形成精细图案的方法,其中通过用光刻工艺将包含至少一种能形成光致抗蚀剂图案的化合物的抗蚀剂组合物涂覆在半导体衬底上的待蚀刻靶材层和自由基引发剂。 自由基引发剂能够在等于或高于至少一种化合物的玻璃化转变温度的温度下被热处理分解。 在抗蚀剂化合物层上进行光刻工艺以形成光致抗蚀剂图案。 将其中形成有光致抗蚀剂图案的抗蚀剂化合物层加热到等于或高于至少一种化合物的玻璃化转变温度的温度,并且其中发生抗蚀剂组合物中的部分交联反应。