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    • 1. 发明授权
    • Materials for use as proton conducting membranes for fuel cells
    • 用作燃料电池质子导电膜的材料
    • US07473714B2
    • 2009-01-06
    • US11119353
    • 2005-05-02
    • Brian R. EinslaJames E. McGrath
    • Brian R. EinslaJames E. McGrath
    • B01J49/00B01J39/20
    • C08J5/2256C08G65/48C08G75/23C08J2371/12C08J2381/06
    • A family of polymers having pendent sulfonate moieties connected to polymeric main chain phenyl groups are described. These polymers are prepared by the steps of polymerization (using a monomer with a phenyl with an alkoxy substitution), deportation by converting the alkoxy to a hydroxyl, and functionalization of the polymer with a pendant sulfonate group. As an example, sulfonated poly(arylene ether sulfone) copolymers with pendent sulfonic acid groups are synthesized by the direct copolymerization of methoxy-containing poly(arylene ether sulfone)s, then converting the methoxy groups to the reactive hydroxyl form, and finally functionalizing the hydroxyl form with proton-conducting sites through nucleophilic substitution. The family of polymers may have application in proton exchange membranes and in other applications.
    • 描述了具有连接到聚合主链苯基的侧链磺酸酯部分的聚合物族。 这些聚合物通过聚合(使用具有烷氧基取代基的苯基)的单体,通过将烷氧基转化为羟基而进行递送的步骤,以及用磺酸侧基官能化聚合物来制备。 作为例子,通过直接共聚含甲氧基的聚(亚芳基醚砜),然后将甲氧基转化为反应性羟基,合成具有侧链磺酸基的磺化聚(亚芳基醚砜)共聚物,最后使 羟基与质子传导位点通过亲核取代。 聚合物族可以用于质子交换膜和其它应用中。