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1. 发明授权

US5985961A Monofilament 失效
标题翻译：单丝
公开(公告)号：US5985961A
公开(公告)日：1999-11-16
申请号：US877783
申请日：1997-06-17
申请人： Bernard C. Dailey , Daniel J. Scharf , Klaus Keck-Antoine
发明人： Bernard C. Dailey , Daniel J. Scharf , Klaus Keck-Antoine
IPC分类号： D06M15/687 , C08K3/04 , C08K5/00 , C08K5/3435 , C08K5/3475 , C08L67/02 , D01F6/62 , D01F6/92 , D01F8/14 , D06M13/02 , D06M13/322 , D06M13/35 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/32 , C08K5/34
CPC分类号： C08K5/3435 , C08K3/04 , C08K5/005 , C08K5/3475 , C08L67/025 , Y10T428/31786
摘要： Elastomeric monofilament exhibiting improved long term retention of strength and elongation after exposure to test conditions described by SAE J-1885 are disclosed. The monofilaments comprise in specified amounts as weight percents on weight of monofilament:(1) at least one elastomeric copolyester polymer, and a stabilizing system comprising:(2) at least 1% carbon black,(3) at least one antioxidant,(4) an oligomeric hindered piperidinyl (HALS) compound having a pK.sub.a of less than 7 or a pK.sub.a from 7 to 12 in combination with an acid scavenger, and(5) a UV stabilizer other than a hindered piperidinyl (HALS) compound.The preferred embodiment is a heterofilament wherein the sheath copolyester has a lower melting point than the core and contains (4) according to: ##STR1## as specified.
摘要翻译：公开了在暴露于SAE J-1885描述的试验条件之后显示改进的长期强度和伸长率的弹性单丝。单丝的重量百分数包括单丝重量的重量百分比：（1）至少一种弹性体共聚酯聚合物和稳定体系，其包含：（2）至少1％的炭黑，（3）至少一种抗氧化剂，（4））pKa小于7的低聚受阻哌啶基（HALS）化合物或7至12的pKa与酸清除剂的组合，和（5）除受阻哌啶（HALS）化合物以外的UV稳定剂。优选的实施方案是异丝，其中所述鞘共聚多酯具有比所述芯更低的熔点，并且包含根据如下所述的（4）。

2. 发明授权

US07875663B2 Colour stabilised polyolefins 有权
标题翻译：颜色稳定的聚烯烃
公开(公告)号：US07875663B2
公开(公告)日：2011-01-25
申请号：US11993641
申请日：2006-07-26
申请人： Klaus Keck-Antoine , Claude Totelin , Bruno Dejolier
发明人： Klaus Keck-Antoine , Claude Totelin , Bruno Dejolier
IPC分类号： C08K5/34
CPC分类号： C08K5/005 , C08L23/10 , C08L71/00 , C08L2201/08 , E04F21/18 , E04G21/16 , E04G21/167 , E04G21/168 , C08L23/02 , C08L2666/22
摘要： A polyolefin composition which comprises: (a) a polyolefin containing transition metal catalyst residue (excluding metallic co-catalyst residues) at a level below 5 ppm based on the weight of the polyolefin; (b) optionally a first stabilizing component consisting of a phenolic antioxidant or mixture of phenolic antioxidants; (c) optionally a second stabilizing component consisting of a phosphite antioxidant or a mixture of phosphite antioxidants; and (d) a third stabilizing component which acts also as a color suppressant and which is a polyfunctional alcohol, amine or amide or mixtures thereof, with at least one of (b) and (c) present and with the proviso that if the phosphite antioxidant is trilauryl phosphite it must be used in combination with another phosphite. The preferred stabilizing components (b) is 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6 dimethyl,benzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione or mixed tocopherols. The preferred stabilizing component (c) is Tris(mono-nonylphenyl)phosphite, Tris(2,4-di-t-butylphenyl)phosphite or bis(2,4-di-t-butyl phenyl)pentaerythritol diphosphite. The preferred stabilizing component (d) which also acts as a color suppressant component (d) is dipentaerythritol or tri-isopropanol amine. The preferred polyolefins are polypropylene and polyethylene. The polyolefin composition also may contain a hindered amine stabilizer (HAS) and an acid scavenger (e.g. calcium stearate).
摘要翻译：一种聚烯烃组合物，其包含：（a）基于聚烯烃的重量，含量低于5ppm的含聚烯烃的过渡金属催化剂残余物（不包括金属助催化剂残余物）; （b）任选的由酚类抗氧化剂或酚类抗氧化剂混合物组成的第一稳定组分; （c）任选的由亚磷酸酯抗氧化剂或亚磷酸酯抗氧化剂的混合物组成的第二稳定组分; 和（d）还具有作为抑色剂的第三稳定组分，并且其是具有（b）和（c）中的至少一种的多官能醇，胺或酰胺或其混合物，条件是如果亚磷酸酯抗氧化剂是亚磷酸三月桂酯，它必须与另一种亚磷酸酯组合使用。优选的稳定化组分（b）是1,3,5-三（4-叔丁基-3-羟基-2,6-二甲基苄基）-1,3,5-三嗪-2,4,6-（1H ，3H，5H） - 三酮或混合的生育酚。优选的稳定化组分（c）是亚磷酸三（单壬基苯基）酯，亚磷酸三（2,4-二叔丁基苯基）酯或双（2,4-二叔丁基苯基）季戊四醇二亚磷酸酯。还用作抑色剂组分（d）的优选的稳定组分（d）是二季戊四醇或三异丙醇胺。优选的聚烯烃是聚丙烯和聚乙烯。聚烯烃组合物还可以含有受阻胺稳定剂（HAS）和酸清除剂（例如硬脂酸钙）。

3. 发明授权

US5852159A Plastic with reduced sulfur uptake rate 失效
标题翻译：具有降低硫吸收速率的塑料
公开(公告)号：US5852159A
公开(公告)日：1998-12-22
申请号：US646679
申请日：1996-05-10
申请人： Matthias Zah , Gerhard Pfahler , Karl Gaa , Klaus Keck-Antoine
发明人： Matthias Zah , Gerhard Pfahler , Karl Gaa , Klaus Keck-Antoine
IPC分类号： C08J5/18 , C08K5/00 , C08K5/17 , C08K5/34 , C08K5/3432 , C08K5/3435 , C08K5/3477 , C08K5/3492 , C08K5/357 , C08L23/00 , C08L23/02 , C08L87/00 , C08L101/00 , D01F6/04 , C08G63/44
CPC分类号： C08K5/3492 , C08K5/34926
摘要： The present invention relates to plastics comprising a high molecular weight, sterically hindered amine, wherein the sterically hindered amine is at least one amine from the group consisting of I: oligomerized 2,2,4,4-tetramethyl-20(oxiranylmethyl)-7-oxa-3,20-diazadispiro�5.1.11.2!heneicosan-21-one, II: condensation product of 2-chloro-4,6-di(4-n-butylamino-1,2,2,6,6-pentamethylpiperidyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane, and III: condensation product of 1-hydroxyethyl-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid. These plastics exhibit a reduced rate of uptake of sulfur compounds. The invention further relates to shaped articles made from these plastics.
摘要翻译：本发明涉及包含高分子量空间位阻胺的塑料，其中空间位阻胺是至少一种由I组成的组的胺：低聚的2,2,4,4-四甲基-20（环氧乙烷基甲基）-7 - 恶唑-3,20-二氮杂螺[5.1.11.2]聚氧乙烯二酮-21-酮，II：2-氯-4,6-二（4-正丁基氨基-1,2,2,6,6- 五甲基哌啶基）-1,3,5-三嗪和1,2-双（3-氨基丙基氨基）乙烷，以及III：1-羟乙基-2,2,6,6-四甲基-4-羟基哌啶与琥珀酸的缩合产物。这些塑料表现出降低硫化合物的吸收速率。本发明还涉及由这些塑料制成的成型制品。

4. 发明申请

US20090264567A1 Stabilized Cross-Linked Polyolefin Compositions 审中-公开
标题翻译：稳定的交联聚烯烃组合物
公开(公告)号：US20090264567A1
公开(公告)日：2009-10-22
申请号：US11887309
申请日：2006-04-25
申请人： Anne-Marie Prins , Klaus Keck-Antoine , Jonathan Simon Hill , Joachim Bayer , Brian W. Johnson
发明人： Anne-Marie Prins , Klaus Keck-Antoine , Jonathan Simon Hill , Joachim Bayer , Brian W. Johnson
IPC分类号： C08K5/375 , C08K5/13 , C08K5/37
CPC分类号： C08K5/14 , C08K5/005 , C08L23/06 , C08L2666/78
摘要： A composition is disclosed that includes at least one polyolefin, at least one organic peroxide, and an antioxidant mixture of a composition of at least one polyolefin, at least one organic peroxide, and an antioxidant mixture. The antioxidant mixture has at least one fast radical scavenger selected from the group consisting of low hindered phenols, low hindered thiophenols, low hindered thiobisphenols, aliphatic amines, aromatic amines, NOR HALS, hydroxylamines, and mixtures thereof, and at least one long term stabilizer selected from the group consisting of low hindered phenols, highly hindered phenols, thiosynergists, aliphatic amines, aromatic amines, HALS, hydroxylamines, and mixtures thereof. The preferred polyolefin is a homopolymer of ethylene or a copolymer of ethylene and the compositions are useful in insulating media for medium and high voltage wire and cable applications.
摘要翻译：公开了包含至少一种聚烯烃，至少一种有机过氧化物和至少一种聚烯烃，至少一种有机过氧化物和抗氧化剂混合物的组合物的抗氧化剂混合物的组合物。抗氧化剂混合物具有至少一种选自低位阻酚，低位阻硫酚，低位阻硫二苯醚，脂族胺，芳香胺，NOR HALS，羟胺及其混合物的快速自由基清除剂，以及至少一种长期稳定剂选自低位阻酚，高度受阻酚，硫代增效剂，脂族胺，芳族胺，HALS，羟胺及其混合物。优选的聚烯烃是乙烯的均聚物或乙烯的共聚物，并且该组合物可用于中高压电线和电缆应用的绝缘介质中。

5. 发明申请

US20100081741A1 COLOUR STABILISED POLYOLEFINS 有权
标题翻译：颜色稳定的聚烯烃
公开(公告)号：US20100081741A1
公开(公告)日：2010-04-01
申请号：US11993641
申请日：2006-07-26
申请人： Klaus Keck-Antoine , Claude Totelin , Bruno Dejolier
发明人： Klaus Keck-Antoine , Claude Totelin , Bruno Dejolier
IPC分类号： C08K5/52 , C08K5/3492 , C08K5/1545
CPC分类号： C08K5/005 , C08L23/10 , C08L71/00 , C08L2201/08 , E04F21/18 , E04G21/16 , E04G21/167 , E04G21/168 , C08L23/02 , C08L2666/22
摘要： A polyolefin composition which comprises: (a) a polyolefin containing transition metal catalyst residue (excluding metallic co-catalyst residues) at a level below 5 ppm based on the weight of the polyolefin; (b) optionally a first stabilising component consisting of a phenolic antioxidant or mixture of phenolic antioxidants; (c) optionally a second stabilising component consisting of a phosphite antioxidant or a mixture of phosphite antioxidants; and (d) a third stabilising component which acts also as a colour suppressant and which is a polyfunctional alcohol, amine or amide or mixtures thereof, with at least one of (b) and (c) present and with the proviso that if the phosphite antioxidant is trilauryl phosphite it must be used in combination with another phosphite. The preferred stabilising components (b) is 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6 dimethy-benzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione or mixed tocopherols. The preferred stabilising component (c) is Tris(mono-nonylphenyl)phosphite, Tris(2,4-di-t-butylphenyl)phosphite or bis(2,4-di-t-butyl phenyl)pentaerythritol diphosphite. The preferred stabilising component (d) which also acts as a colour suppressant component (d) is dipentaerythritol or tri-isopropanol amine. The preferred polyolefins are polypropylene and polyethylene. The polyolefin composition also may contain a hindered amine stabiliser (HAS) and an acid scavenger (e.g. calcium stearate).
摘要翻译：一种聚烯烃组合物，其包含：（a）基于聚烯烃的重量，含量低于5ppm的含聚烯烃的过渡金属催化剂残余物（不包括金属助催化剂残余物）; （b）任选的由酚类抗氧化剂或酚类抗氧化剂混合物组成的第一稳定组分; （c）任选的由亚磷酸酯抗氧化剂或亚磷酸酯抗氧化剂的混合物组成的第二稳定组分; 和（d）还具有作为抑色剂的第三稳定组分，并且其是具有（b）和（c）中的至少一种的多官能醇，胺或酰胺或其混合物，条件是如果亚磷酸酯抗氧化剂是亚磷酸三月桂酯，它必须与另一种亚磷酸酯组合使用。优选的稳定化组分（b）是1,3,5-三（4-叔丁基-3-羟基-2,6-二甲基 - 苄基）-1,3,5-三嗪-2,4,6-（1H ，3H，5H） - 三酮或混合的生育酚。优选的稳定化组分（c）是亚磷酸三（单壬基苯基）酯，亚磷酸三（2,4-二叔丁基苯基）酯或双（2,4-二叔丁基苯基）季戊四醇二亚磷酸酯。还用作抑色剂组分（d）的优选的稳定组分（d）是二季戊四醇或三异丙醇胺。优选的聚烯烃是聚丙烯和聚乙烯。聚烯烃组合物还可以含有受阻胺稳定剂（HAS）和酸清除剂（例如硬脂酸钙）。

6. 发明申请

US20050288403A1 Stabilised polypropylene 审中-公开
标题翻译：稳定聚丙烯
公开(公告)号：US20050288403A1
公开(公告)日：2005-12-29
申请号：US10516169
申请日：2003-05-27
申请人： Monica de la Cruz , Cindy Doumen , Klaus Keck-Antoine , Brian Johnson
发明人： Monica de la Cruz , Cindy Doumen , Klaus Keck-Antoine , Brian Johnson
IPC分类号： C08L23/12 , C08K5/13 , C08K5/3435 , C08K5/524 , C08L23/10 , C08L35/00 , D01F6/46 , C08K5/34
CPC分类号： C08K5/3435 , C08K5/13 , C08K5/524 , C08L23/10 , C08L35/00 , C08L2201/08 , C08L23/12 , C08L2666/04
摘要： A polypropylene composition comprises: (a) a first stabilising component consisting of 100 ppm or less based on the weight of the polypropylene of a phenolic antioxidant or a mixture of phenolic antioxidants; (b) a second stabilising component consisting of 500 to 1000 ppm based on the weight of the polypropylene of a phosphite antioxidant or a mixture of phosphite antioxidants; and optionally (c) a third stabilising component consisting of 100 ppm to 5000 ppm based on the weight of the polypropylene of a hindered amine light stabiliser or a mixture of such stabilisers. The polypropylene composition advantageously is in the form of fibres. A preferred phenolic antioxidant is 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6 dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H, 3H, 5H)-trione (Lowinox 1790). A preferred phosphite antioxidant is tris(2,4-di-t-butylphenyl) phosphite (Alkanox 240). A preferred optional hindered amine light stabiliser is dimethyl succinate polymer with 4-hydroxy-2,2,6,6-tetramethyl-1-piperidine (Lowilite 62).
摘要翻译：聚丙烯组合物包含：（a）基于酚类抗氧化剂的聚丙烯或酚类抗氧化剂的混合物的重量为100ppm或更少的第一稳定组分; （b）基于亚磷酸酯抗氧化剂的聚丙烯或亚磷酸酯抗氧化剂的混合物的重量的500至1000ppm的第二稳定组分; 和任选地（c）由受阻胺光稳定剂的聚丙烯的重量或这种稳定剂的混合物的100ppm至5000ppm组成的第三稳定组分。聚丙烯组合物有利地是纤维的形式。优选的酚类抗氧化剂是1,3,5-三（4-叔丁基-3-羟基-2,6-二甲基苄基）-1,3,5-三嗪-2,4,6-（1H，3H，5H ）-trione（Lowinox 1790）。优选的亚磷酸酯抗氧化剂是三（2,4-二叔丁基苯基）亚磷酸酯（Alkanox 240）。优选的可选受阻胺光稳定剂是具有4-羟基-2,2,6,6-四甲基-1-哌啶（Lowilite 62）的琥珀酸二甲酯聚合物。

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