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    • 1. 发明授权
    • Process for the electrolysis of alkali metal chloride solutions
    • 电解碱金属氯化物溶液的方法
    • US4790915A
    • 1988-12-13
    • US2142
    • 1987-01-12
    • August WinselRudolf StaabNikolaj Medic
    • August WinselRudolf StaabNikolaj Medic
    • C25B1/46C25B11/04C25B1/00
    • C25B11/0489C25B1/46
    • A process is described for electrolyzing aqueous alkali metal chloride solutions in a membrane cell which contains an anode chamber with the anode and a cathode chamber with the cathode, the two chambers being separated from one another by a cation exchanger membrane. The cathode is porous and foil-like. The cathode and cation exchanger membrane form the actual cathode chamber filled with catholyte and the cathode and cell wall form a gas space. Water is fed into the cathode chamber and alkali metal hydroxide solution is withdrawn from it, hydrogen is withdrawn from the cathode chamber and gas space, and aqueous alkali metal chloride solution is fed into the anode chamber and gaseous chlorine, together with depleted alkali metal chloride solution, is withdrawn from it. A direct voltage which is at least the same as the decomposition voltage is applied to the cathode and anode. A higher pressure is established in the cathode chamber than in the gas space.
    • 描述了一种用于在包含具有阳极的阳极室和具有阴极的阴极室的膜电池中电解碱金属氯化物水溶液的方法,两个室通过阳离子交换膜彼此分离。 阴极是多孔的和箔状的。 阴极和阳离子交换膜形成填充阴极电解液的实际阴极室,阴极和细胞壁形成气体空间。 将水进入阴极室,从其中取出碱金属氢氧化物溶液,从阴极室和气体空间中取出氢气,将碱金属氯化物水溶液与贫化的碱金属氯化物一起进入阳极室和气态氯 解决方案,从中撤出。 将至少与分解电压相同的直流电压施加到阴极和阳极。 在阴极室中建立的压力高于气体空间。
    • 2. 发明授权
    • Pump cylinder and method of collecting pasty materials, liquids, gases and/or mobile objects
    • 泵筒和收集糊状材料,液体,气体和/或移动物体的方法
    • US06568922B1
    • 2003-05-27
    • US09979977
    • 2001-11-29
    • August Winsel
    • August Winsel
    • F04B1700
    • F04B35/00F04B17/00F04B19/20F04B37/10G01N1/14G01N2001/1093H01M12/00
    • A pump cylinder in which a pump plunger is guided which divides the cylinder into a forward and a rearward subspace, which, in the forward subspace, has a connection for taking in the fluid medium to be delivered, the rearward subspace of the pump cylinder containing one or several electrochemical gas consumption cells for a consumption gas, an electric circuit being provided which is constantly or temporarily connected with the electrodes of the gas consumption cell, is characterized in that the rearward part of the pump cylinder is filled with an electrochemical consumption gas, and the electric circuit is designed for causing a gas consumption current so that the pump cylinder forms a device for implementing a process for collecting pasty masses, liquids, gases and mobile objects for a previously determinable time period.
    • 泵柱体,其中泵柱塞被引导,其将气缸分成向前和向后的子空间,其在向前的子空间中具有用于吸入待输送的流体介质的连接,泵缸的后向子空间包含 用于消耗气体的一个或几个电化学气体消耗电池,提供与气体消耗电池的电极不断或临时连接的电路,其特征在于,泵筒的后部填充有电化学消耗气体 并且电路被设计成引起气体消耗电流,使得泵气缸形成用于实现用于在先前可确定的时间段内收集糊状物质,液体,气体和移动物体的过程的装置。
    • 3. 发明授权
    • Galvanic primary element
    • 电镀主要元素
    • US4363855A
    • 1982-12-14
    • US169960
    • 1980-07-18
    • August Winsel
    • August Winsel
    • H01M12/04H01M12/02
    • H01M12/04
    • A galvanic primary element of the system Li/H.sub.2 O.sub.2 comprises a gas diffusion electrode which separates the lithium electrode from the cathode space which is filled with aqueous H.sub.2 O.sub.2 solution. In the working layer which is flanked by capillary active cover layers of the gas diffusion electrode, automatically drawn-in H.sub.2 O.sub.2 is decomposed into H.sub.2 O.sub.2 and O.sub.2 catalytically until the gas pressure is in equilibrium with capillary forces and thereby interrupts the access of additional H.sub.2 O.sub.2 solution to the working layer. Short circuiting of the cell or connection of a load causes a reduction of the gas pressure due to electrochemical reaction of the O.sub.2 with the lithium so that fresh reactant solution can flow in. A reaction regime matching the current draw becomes possible because of the property of polyurethane to gel in aqueous H.sub.2 O.sub.2 by virtue of the fact that the H.sub.2 O.sub.2 is slowly pressed out of the gel as out of a sponge by means of a ram toward the gas diffusion electrode.
    • 系统Li / H 2 O 2的原始元素包括气体扩散电极,其将锂电极与填充有H 2 O 2水溶液的阴极空间分离。 在气体扩散电极的毛细作用覆盖层侧面的工作层中,自动吸入的H 2 O 2被催化分解成H 2 O 2和O 2,直到气体压力与毛细管力平衡,从而中断了另外的H 2 O 2溶液的进入 工作层。 电池的短路或负载的连接导致由于O2与锂的电化学反应引起的气体压力的降低,使得新鲜的反应物溶液可以流入。与电流汲取匹配的反应方案可能是因为 聚氨酯在H 2 O 2水溶液中凝胶化,这是因为H 2 O 2借助于冲头朝向气体扩散电极被缓慢地从凝胶中挤出出海绵状物。
    • 5. 发明授权
    • Recombination system for storage batteries
    • 蓄电池组合系统
    • US4378413A
    • 1983-03-29
    • US246705
    • 1981-03-23
    • August WinselKonstantin LedjeffBernd-Udo Bopp
    • August WinselKonstantin LedjeffBernd-Udo Bopp
    • H01M10/52H01M2/00
    • H01M10/52
    • A recombination system for catalytic oxidation of hydrogen in storage battery gases includes a gas supply duct which makes it possible for the combustible gas flowing through it to aspirate from the ambient the necessary combustion air, following the principle of a Bunsen burner, and to entrain it to the recombination catalyst. In case of over-supply of gas, an acid separator positioned in the gas supply pipe counteracts the gas aspiration by means of its flow impedance and thereby makes the recombination system safe from overload. It can also be connected following a conventional recombiner, thereby increasing its effectiveness, by receiving the excess hydrogen from same and reacting it with the aid of the air aspiration.
    • 用于存储电池气体中的氢的催化氧化的重组系统包括气体供应管道,其使得流过其中的可燃气体可以按照本生灯原理从周围排出所需的燃烧空气,并夹带 到重组催化剂。 在气体过量供给的情况下,位于气体供给管中的酸分离器通过其流动阻抗来抵消气体吸入,从而使复合系统免于过载。 它也可以在常规重组器之后连接,从而通过从其中接收过量的氢并借助于空气抽吸使其反应而增加其有效性。
    • 7. 发明授权
    • Electrochemical gas sensor
    • 电化学气体传感器
    • US06428665B1
    • 2002-08-06
    • US09425677
    • 1999-10-12
    • Dejan IlicKonrad HollJoachim HelmkeHans-Joachim KohnkeAugust Winsel
    • Dejan IlicKonrad HollJoachim HelmkeHans-Joachim KohnkeAugust Winsel
    • G01N27404
    • G01N27/4045
    • An electrochemical gas sensor has a first gas diffusion electrode for a first reaction gas, which is inactive with respect to a second reaction gas at least in a first potential window, and a second gas diffusion electrode for the second reaction gas, which is active with respect to the second reaction gas at least in a second potential window for measuring two different gases in gas mixtures in a casing. The two gas diffusion electrodes are electronically isolated from one another, but electrically connected electrolytically to a reversibly loadable electrode and have contacts for connecting external closing circuits for adjusting the cell currents. The gas mixture is fed to the gas diffusion electrodes in series or parallel. The casing containing the electrodes is, in particular, in the form of a button cell. The reversibly loadable electrode is a Cu/CuO, Zn/ZnO or hydrogen electrode. The gas diffusion electrodes have a porous structure based on carbon or have a porous silver structure.
    • 电化学气体传感器具有用于第一反应气体的第一气体扩散电极,其至少在第一电位窗中相对于第二反应气体是无活性的,以及用于第二反应气体的第二气体扩散电极,其与 至少在用于测量套管中的气体混合物中的两种不同气体的第二电势窗中的第二反应气体。 两个气体扩散电极彼此电子隔离,但是电解电连接到可逆负载的电极,并且具有用于连接用于调节电池电流的外部闭合电路的触点。 将气体混合物串联或并联地供给到气体扩散电极。 包含电极的外壳特别是按钮式电池的形式。 可逆负载电极是Cu / CuO,Zn / ZnO或氢电极。 气体扩散电极具有基于碳的多孔结构或具有多孔银结构。
    • 8. 发明授权
    • Device for electrochemical generation of gases for the transportation of
fluids and similar mediums
    • 用于输送流体和类似介质的气体的电化学生成装置
    • US5242565A
    • 1993-09-07
    • US727877
    • 1991-07-10
    • August Winsel
    • August Winsel
    • A61M5/142F16N11/10H01M6/00H01M6/26
    • F16N11/10H01M6/00H01M6/26A61M2005/14204
    • The device according to the present invention comprises a galvanic cell including a gas generating electrode, a counter electrode and an aqueous electrolyte enclosed in a housing. The device has one or more openings, by which the generated gas is released to the environment. The device also contains means for electrically connecting said gas generating electrode and said counter electrode and for establishing a current flow between said gas generating electrode and said counter electrode for generating a predetermined quantity of gas by said gas generating electrode for release from said opening of said galvanic cell. The objective of the cell is to generate and release oxygen or hydrogen gas, thereby defining a new type of cell. The device is referred to as a "gas generator cell."
    • 根据本发明的装置包括一个电池,包括气体发生电极,对电极和封闭在壳体中的含水电解质。 该装置具有一个或多个开口,通过该开口将产生的气体释放到环境中。 该装置还包括用于电气连接所述气体发生电极和所述对电极并用于在所述气体发生电极和所述对电极之间建立电流的装置,用于由所述气体发生电极产生预定量的气体,以从所述气体发生电极和所述对电极的所述开口释放 原电池。 电池的目的是产生和释放氧气或氢气,从而限定新型电池。 该装置被称为“气体发生器电池”。
    • 9. 发明授权
    • Lithium peroxide primary element
    • 过氧化锂原料
    • US4504561A
    • 1985-03-12
    • US169953
    • 1980-07-18
    • August Winsel
    • August Winsel
    • H01M6/04H01M12/04H01M6/22
    • H01M6/04H01M12/04
    • In a galvanic primary element of the system Li/H.sub.2 O.sub.2, the aqueous cathode depolarizer H.sub.2 O.sub.2 is fixated as a polyurethane gel. It can thereby be controlled and caused to react with the anode metal in accordance with the current drain requirements. This is accomplished using a ram to press the gel toward a conductor which covers the lithium anode, which may take the form of a metal grid and/or a gas diffusion electrode. The oxygen which forms in the working layer through catalytic decomposition of hydrogen peroxide creates a gas bubble when the current is interrupted or the ram is stopped, thereby interrupting the further supply of hydrogen peroxide to the catalyst.
    • 在系统Li / H 2 O 2的原始元素中,水性阴极去极化器H 2 O 2固定为聚氨酯凝胶。 因此可以根据电流消耗要求来控制并使其与阳极金属反应。 这可以使用压头将凝胶压向覆盖锂阳极的导体,该阳极可以采取金属网格和/或气体扩散电极的形式。 通过过氧化氢的催化分解在工作层中形成的氧气在电流中断或冲头停止时产生气泡,从而中断向催化剂进一步供应过氧化氢。