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1. 发明申请

US20080236659A1 Photoelectric conversion electrode, manufacturing method of the same, and dye-sensitized solar cell 审中-公开
标题翻译：光电转换电极及其制造方法以及染料敏化太阳能电池
公开(公告)号：US20080236659A1
公开(公告)日：2008-10-02
申请号：US12078041
申请日：2008-03-26
申请人： Atsushi Monden , Tokuhiko Handa
发明人： Atsushi Monden , Tokuhiko Handa
IPC分类号： H01L31/0224 , H01L31/04 , C25D5/10
CPC分类号： H01G9/2027 , H01G9/2059 , H01L51/0006 , H01L51/4233 , Y02E10/542 , Y02P70/521
摘要： There are disclosed a photoelectric conversion electrode having a large amount of a dye to be supported and an excellent dye replacement property and capability of improving a mechanical strength and a photoelectric conversion efficiency. In a photoelectric conversion electrode 11 according to the present invention, on a substrate 12 having a conductive surface 12a, an underlayer 13 containing a metal oxide and a porous metal oxide layer 14 including a metal oxide and a dye can be prepared by an electrolytic deposition process, and an electrolysis potential of the underlayer 13 is set to a potential or less of a flection point having a minimum potential among a plurality of flection points observed in a range of 0 to −1.5 V (vs. Ag/AgCl) in a current-potential profile during electrolytic deposition, whereby the underlayer is formed so that pointed crystal particles 13a of the metal oxide are piled up in a layer thickness direction.
摘要翻译：公开了一种具有大量待负载染料的光电转换电极，并且具有优异的染料替代性和提高机械强度和光电转换效率的能力。在根据本发明的光电转换电极11中，在具有导电表面12a的基板12上，含有金属氧化物的底层13和包含金属氧化物的多孔金属氧化物层14和染料可以通过电解沉积工艺，并且底层13的电解电位被设定为在0至-1.5V（相对于Ag / AgCl）的范围内观察到的多个反射点中具有最小电位的反射点的电位或更小的电位电解沉积期间的电流 - 电位分布，由此形成底层，使得金属氧化物的尖晶体颗粒13a在层厚度方向上堆积。

2. 发明授权

US07245479B2 Electrolytic capacitor and method of manufacturing the same 有权
公开(公告)号：US07245479B2
公开(公告)日：2007-07-17
申请号：US11634126
申请日：2006-12-06
申请人： Masaaki Kobayashi , Atsushi Monden , Tokuhiko Handa
发明人： Masaaki Kobayashi , Atsushi Monden , Tokuhiko Handa
IPC分类号： H01G9/00
CPC分类号： H01G9/042 , H01G9/0032 , H01G9/15 , Y10T29/41 , Y10T29/417
摘要： The present invention provides an electrolytic capacitor manufacturing method capable of manufacturing an electrolytic capacitor having the PTC function as easy as possible. A main electrode layer in a cathode is formed so as to have the PTC function. Different from a conventional electrolytic capacitor manufacturing method of connecting a PTC thermistor to a capacitor element to give the PTC function to an electrolytic capacitor so that an electrolytic capacitor manufacturing process is complicated and the number of manufacturing processes is increased by the amount corresponding to the PTC thermistor connecting process, the process of connecting the PTC thermistor to the capacitor element is unnecessary. Consequently, complication of the electrolytic capacitor manufacturing process and increase in the number of manufacturing processes caused by the PTC thermistor connecting process can be prevented.

3. 发明申请

US20090320918A1 Photoelectric conversion device 审中-公开
标题翻译：光电转换装置
公开(公告)号：US20090320918A1
公开(公告)日：2009-12-31
申请号：US12457686
申请日：2009-06-18
申请人： Masahiro Tsuchiya , Tokuhiko Handa , Atsushi Monden , Junji Tanabe , Masahiro Shinkai
发明人： Masahiro Tsuchiya , Tokuhiko Handa , Atsushi Monden , Junji Tanabe , Masahiro Shinkai
IPC分类号： H01L31/00
CPC分类号： H01G9/2009 , H01G9/2031 , H01G9/2059 , Y02E10/542 , Y02E10/549
摘要： The present invention provides a photoelectric conversion device capable of improving durability without using particular material. The photoelectric conversion device includes a working electrode in which dye is carried by a metal oxide semiconductor layer and a facing electrode having a conductive layer, and a semi-solid electrolyte containing layer supported between the working electrode and the facing electrode. The electrolyte containing layer contains an electrolyte solution in which a solid electrolyte salt is dissolved in an organic solvent, and a particle. Thereby, liquid leakage or the like hardly occurs even under a high-temperature environment in comparison with the case where the electrolyte containing layer does not contain a particle.
摘要翻译：本发明提供能够在不使用特定材料的情况下提高耐久性的光电转换装置。光电转换装置包括工作电极，其中染料由金属氧化物半导体层和具有导电层的对置电极承载，并且半固体电解质包含层被支撑在工作电极和对置电极之间。含电解质层含有固体电解质盐溶解在有机溶剂中的电解质溶液和粒子。因此，与含电解质层不含颗粒的情况相比，即使在高温环境下也难以发生液体渗漏等。

4. 发明申请

US20070081300A1 Electrolytic capacitor and method of manufacturing the same 有权
公开(公告)号：US20070081300A1
公开(公告)日：2007-04-12
申请号：US11634126
申请日：2006-12-06
申请人： Masaaki Kobayashi , Atsushi Monden , Tokuhiko Handa
发明人： Masaaki Kobayashi , Atsushi Monden , Tokuhiko Handa
IPC分类号： H01G9/00
CPC分类号： H01G9/042 , H01G9/0032 , H01G9/15 , Y10T29/41 , Y10T29/417
摘要： The present invention provides an electrolytic capacitor manufacturing method capable of manufacturing an electrolytic capacitor having the PTC function as easy as possible. A main electrode layer in a cathode is formed so as to have the PTC function. Different from a conventional electrolytic capacitor manufacturing method of connecting a PTC thermistor to a capacitor element to give the PTC function to an electrolytic capacitor so that an electrolytic capacitor manufacturing process is complicated and the number of manufacturing processes is increased by the amount corresponding to the PTC thermistor connecting process, the process of connecting the PTC thermistor to the capacitor element is unnecessary. Consequently, complication of the electrolytic capacitor manufacturing process and increase in the number of manufacturing processes caused by the PTC thermistor connecting process can be prevented.

5. 发明申请

US20050219802A1 Electrolytic capacitor and method of manufacturing the same 有权
标题翻译：电解电容器及其制造方法
公开(公告)号：US20050219802A1
公开(公告)日：2005-10-06
申请号：US11089227
申请日：2005-03-25
申请人： Masaaki Kobayashi , Atsushi Monden , Tokuhiko Handa
发明人： Masaaki Kobayashi , Atsushi Monden , Tokuhiko Handa
IPC分类号： H01G9/00 , H01G9/042 , H01G9/15
CPC分类号： H01G9/042 , H01G9/0032 , H01G9/15 , Y10T29/41 , Y10T29/417
摘要： The present invention provides an electrolytic capacitor manufacturing method capable of manufacturing an electrolytic capacitor having the PTC function as easy as possible. A main electrode layer in a cathode is formed so as to have the PTC function. Different from a conventional electrolytic capacitor manufacturing method of connecting a PTC thermistor to a capacitor element to give the PTC function to an electrolytic capacitor so that an electrolytic capacitor manufacturing process is complicated and the number of manufacturing processes is increased by the amount corresponding to the PTC thermistor connecting process, the process of connecting the PTC thermistor to the capacitor element is unnecessary. Consequently, complication of the electrolytic capacitor manufacturing process and increase in the number of manufacturing processes caused by the PTC thermistor connecting process can be prevented.
摘要翻译：本发明提供一种电解电容器制造方法，其能够制造尽可能容易地具有PTC功能的电解电容器。阴极中的主电极层形成为具有PTC功能。与将PTC热敏电阻连接到电容器元件以将PTC功能连接到电解电容器的常规电解电容器制造方法不同，使得电解电容器制造工艺复杂并且制造工艺的数量增加了对应于PTC的量热敏电阻连接工艺，不需要将PTC热敏电阻连接到电容器元件的过程。因此，可以防止电解电容器制造工艺的复杂化和由PTC热敏电阻连接工艺引起的制造工艺数量的增加。

6. 发明申请

US20100243060A1 Electrode for photoelectric conversion elements, manufacturing method of the same, and dye-sensitized solar cell 审中-公开
标题翻译：用于光电转换元件的电极，其制造方法和染料敏化太阳能电池
公开(公告)号：US20100243060A1
公开(公告)日：2010-09-30
申请号：US12659741
申请日：2010-03-19
申请人： Tokuhiko Handa , Atsushi Monden
发明人： Tokuhiko Handa , Atsushi Monden
IPC分类号： H01L31/00 , H01L31/04 , H01L31/18
CPC分类号： H01G9/204 , H01G9/2059 , H01L51/0026 , H01L51/0064 , Y02E10/542 , Y02P70/521
摘要： An electrode for photoelectric conversion elements having high initial characteristics and excellent durability, a manufacturing method of the electrode for photoelectric conversion elements, and a dye-sensitized solar cell are provided. An electrode for photoelectric conversion elements according to the present invention has a structure in which a metal oxide layer containing zinc oxide is provided on a base. The metal oxide layer has a plurality of bump-like protrusions formed so as to protrude radially from the base side, and also has an emission peak in a region of 350 to 400 nm in cathodoluminescence measurement. The metal oxide layer is preferably heat treated at 220 to 500° C.
摘要翻译：提供具有高初始特性和优异耐久性的光电转换元件用电极，用于光电转换元件的电极的制造方法和染料敏化太阳能电池。根据本发明的用于光电转换元件的电极具有在基底上设置含有氧化锌的金属氧化物层的结构。金属氧化物层具有形成为从基底侧径向突出的多个凸起状突起，并且在阴极发光测定中也具有350〜400nm的区域的发光峰。金属氧化物层优选在220〜500℃下热处理。

7. 发明申请

US20090038676A1 Photoelectric conversion electrode, manufacturing method of the same, and dye-sensitized solar cell 审中-公开
标题翻译：光电转换电极及其制造方法以及染料敏化太阳能电池
公开(公告)号：US20090038676A1
公开(公告)日：2009-02-12
申请号：US12078042
申请日：2008-03-26
申请人： Atsushi Monden , Tokuhiko Handa
发明人： Atsushi Monden , Tokuhiko Handa
IPC分类号： H01L31/00 , C25D5/00 , C25D5/48
CPC分类号： H01G9/204 , H01G9/2004 , H01G9/2059 , H01L2251/306 , Y02E10/542 , Y02P70/521
摘要： There are disclosed a photoelectric conversion electrode having a large amount of a dye to be supported and an excellent dye replacement property and having a capability of improving a photoelectric conversion efficiency, a manufacturing method of the photoelectric conversion electrode and the like. A photoelectric conversion electrode 11 according to the present invention can be manufactured by laminating a porous metal oxide layer 14 including a metal oxide and a dye on a substrate 12 having a conductive surface 12a, and the metal oxide layer 14 has a specific surface area of 70 to 250 m2/g and a void ratio of 50 to 75%. Specifically, the metal oxide layer 14 can be formed by a cathode electrolytic deposition process using an electrolyte containing a metal salt and 80 to 500 μM of template dye, the template dye co-adsorbed on the metal oxide layer 14 is desorbed, and a sensitizing dye different from the template dye is more preferably re-adsorbed.
摘要翻译：公开了具有大量待负载的染料和优异的染料替代性能并且具有提高光电转换效率的能力的光电转换电极，光电转换电极的制造方法等。根据本发明的光电转换电极11可以通过在具有导电表面12a的基板12上层压包含金属氧化物和染料的多孔金属氧化物层14，并且金属氧化物层14的比表面积 70〜250m 2 / g，空隙率为50〜75％。具体地说，金属氧化物层14可以通过使用含有金属盐的电解质和80〜500μm的模板染料的阴极电解沉积法形成，共吸附在金属氧化物层14上的模板染料被解吸，与模板染料不同的染料更优选被再吸附。

8. 发明申请

US20080236658A1 Electrode, manufacturing method of the same, and dye-sensitized solar cell 审中-公开
标题翻译：电极，其制造方法和染料敏化太阳能电池
公开(公告)号：US20080236658A1
公开(公告)日：2008-10-02
申请号：US12078040
申请日：2008-03-26
申请人： Tokuhiko Handa , Atsushi Monden
发明人： Tokuhiko Handa , Atsushi Monden
IPC分类号： H01L31/0224 , H01L31/04 , B05D1/00 , C25D5/00
CPC分类号： C25D15/02 , C25D9/08 , H01G9/2027 , H01G9/2059 , Y02E10/542 , Y02P70/521
摘要： There are disclosed an electrode having a large amount of a dye to be supported, having an excellent dye replacement property and having a capability of improving a photoelectric conversion efficiency, a manufacturing method of the electrode and a dye-sensitized solar cell including the electrode. An electrode 11 according to the present invention includes a dye-supported layer 14 laminated on a substrate 12 and including zinc oxide and a dye. The dye-supported layer 14 has at least a plurality of bump-like protrusions formed so that zinc oxide protrudes radially from the substrate 12, or satisfies represented by the following formula (1): 2≦I002/I101≦12, in which I002 is a peak intensity attributed to a zinc oxide (002) face in X-ray diffraction measurement of the dye-supported layer 14, and I101 is a peak intensity attributed to a zinc oxide (101) face in the X-ray diffraction measurement.
摘要翻译：公开了具有大量待负载的染料，具有优异的染料替代性并具有提高光电转换效率的能力的电极，电极的制造方法和包括该电极的染料敏化太阳能电池。根据本发明的电极11包括层叠在基板12上并包含氧化锌和染料的染料负载层14。染料负载层14具有形成为使得氧化锌从基板12径向突出的多个凸起状突起，或满足下式（1）所示的2个以上的隆起状突起：2 <= 1 002 染料负载型的X射线衍射测定中归属于氧化锌（002）面的峰强度为/ 层14和I 101是在X射线衍射测量中归因于氧化锌（101）面的峰强度。

9. 发明授权

US07218506B2 Electrolytic capacitor and method of manufacturing the same 有权
标题翻译：电解电容器及其制造方法
公开(公告)号：US07218506B2
公开(公告)日：2007-05-15
申请号：US11089227
申请日：2005-03-25
申请人： Masaaki Kobayashi , Atsushi Monden , Tokuhiko Handa
发明人： Masaaki Kobayashi , Atsushi Monden , Tokuhiko Handa
IPC分类号： H01G9/00
CPC分类号： H01G9/042 , H01G9/0032 , H01G9/15 , Y10T29/41 , Y10T29/417
摘要： The present invention provides an electrolytic capacitor manufacturing method capable of manufacturing an electrolytic capacitor having the PTC function as easy as possible. A main electrode layer in a cathode is formed so as to have the PTC function. Different from a conventional electrolytic capacitor manufacturing method of connecting a PTC thermistor to a capacitor element to give the PTC function to an electrolytic capacitor so that an electrolytic capacitor manufacturing process is complicated and the number of manufacturing processes is increased by the amount corresponding to the PTC thermistor connecting process, the process of connecting the PTC thermistor to the capacitor element is unnecessary. Consequently, complication of the electrolytic capacitor manufacturing process and increase in the number of manufacturing processes caused by the PTC thermistor connecting process can be prevented.
摘要翻译：本发明提供一种电解电容器制造方法，其能够制造尽可能容易地具有PTC功能的电解电容器。阴极中的主电极层形成为具有PTC功能。与将PTC热敏电阻连接到电容器元件以将PTC功能连接到电解电容器的常规电解电容器制造方法不同，使得电解电容器制造工艺复杂并且制造工艺的数量增加了对应于PTC的量热敏电阻连接工艺，不需要将PTC热敏电阻连接到电容器元件的过程。因此，可以防止电解电容器制造工艺的复杂化和由PTC热敏电阻连接工艺引起的制造工艺数量的增加。

10. 发明授权

US07943849B2 Photoelectric conversion device 有权
标题翻译：光电转换装置
公开(公告)号：US07943849B2
公开(公告)日：2011-05-17
申请号：US12078154
申请日：2008-03-27
申请人： Junji Tanabe , Masahiro Tsuchiya , Hidenori Shinohara , Atsushi Monden , Masahiro Shinkai , Tokuhiko Handa
发明人： Junji Tanabe , Masahiro Tsuchiya , Hidenori Shinohara , Atsushi Monden , Masahiro Shinkai , Tokuhiko Handa
IPC分类号： H01L31/00 , H01L31/042 , H01L29/08 , H01L29/12 , H01L27/14
CPC分类号： C09B23/0066 , C09B23/02 , C09B23/04 , C09B23/06 , C09B23/083 , C09B23/086 , H01G9/2031 , H01G9/2059 , H01L51/0064 , Y02E10/542
摘要： Provided is a photoelectric conversion device capable of improving a conversion efficiency. In a dye-sensitized photoelectric conversion device including a working electrode and a facing electrode, and an electrolyte inclusion, a dye is carried on a metal-oxide semiconductor layer of the working electrode. The dye includes cyanine dye having a benzyl group and an indolenine skeleton. Therefore, crystallization of the dye on the surface of the metal-oxide semiconductor layer is suppressed.
摘要翻译：提供能够提高转换效率的光电转换装置。在包括工作电极和对置电极以及电解质夹杂物的染料敏化光电转换装置中，在工作电极的金属氧化物半导体层上载持染料。染料包括具有苄基和吲哚宁骨架的花青染料。因此，抑制了金属氧化物半导体层的表面上的染料的结晶化。

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