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1. 发明授权

US09394424B2 Flame-protected, partially aromatic polyamide molding compounds 有权
标题翻译：火焰保护的部分芳族聚酰胺模塑料
公开(公告)号：US09394424B2
公开(公告)日：2016-07-19
申请号：US13376167
申请日：2009-06-05
申请人： Andreas Bayer , Nikolai Lamberts
发明人： Andreas Bayer , Nikolai Lamberts
IPC分类号： C08K5/098 , C08K5/3492 , C08K5/5313
CPC分类号： C08K5/098 , C08K5/34928 , C08K5/5313 , C08L77/06
摘要： The invention relates to a flame-retardant polyamide molding composition based on semicrystalline polyamides. This polyamide molding composition is based on (A) from 30 to 92% by weight of at least one aliphatic or semiaromatic, semicrystalline polyamide with melting point (Tm) in the range from 240° C. to 340° C.; (B) from 0 to 50% by weight of at least one filler and reinforcing agent; (C) from 8 to 18% by weight of at least one halogen-free flame retardant; (D) from 0 to 2.0% by weight of at least one barium carboxylate; (E) from 0 to 5% by weight of at least one additive; wherein the percentages by weight of components (A) to (E) give a total of 100%, and with the proviso that if the proportion of component (D) is in the range from 0 to 0.1% by weight the halogen-free flame retardant of component (C) is based on a barium phosphinate. The invention further relates to the use of barium carboxylate in a polyamide molding composition using a halogen-free flame retardant for inhibiting corrosive action during processing. The molding compositions comply with fire-protection class UL 94 V-0, and have no, or only slight, corrosive action with respect to the machine components used in thermoplastic processing, and exhibit good mechanical properties. They are suitable for producing, in particular, thin-walled moldings for the electrical and electronics industry, examples being housings, housing components, and connectors.
摘要翻译：本发明涉及一种基于半结晶聚酰胺的阻燃聚酰胺模塑组合物。该聚酰胺模塑组合物基于（A）30至92重量％的至少一种脂族或半芳族半结晶聚酰胺，熔点（Tm）在240℃至340℃的范围内。（B）0至50重量％的至少一种填料和增强剂; （C）8至18重量％的至少一种无卤阻燃剂; （D）0至2.0重量％的至少一种羧酸钡; （E）0至5重量％的至少一种添加剂; 其中组分（A）至（E）的重量百分比总计为100％，条件是如果组分（D）的比例在0至0.1重量％的范围内，则不含卤素的火焰组分（C）的阻燃剂基于次膦酸钡。本发明还涉及在使用无卤阻燃剂在加工过程中抑制腐蚀作用的聚酰胺模塑组合物中使用羧酸钡。模塑组合物符合防火等级UL 94 V-0，并且对于热塑性加工中使用的机器部件没有或只有轻微的腐蚀作用，并且具有良好的机械性能。它们特别适用于制造电气和电子工业的薄壁模制件，例如壳体，外壳部件和连接器。

2. 发明申请

US20120321829A1 SEMIAROMATIC MOLDING COMPOUNDS AND USES THEREOF 有权
标题翻译：半自动模塑化合物及其用途
公开(公告)号：US20120321829A1
公开(公告)日：2012-12-20
申请号：US13481451
申请日：2012-05-25
申请人： Andreas Bayer , Nikolai Lamberts , Botho Hoffmann , Manfred Hewel
发明人： Andreas Bayer , Nikolai Lamberts , Botho Hoffmann , Manfred Hewel
IPC分类号： C08L77/10 , B32B1/08 , C08K5/098
CPC分类号： C08L77/06 , C08G69/36 , C08K3/014 , C08K5/005 , C08K7/14 , C08L77/02 , C08L2205/02 , Y10T428/1352 , Y10T428/1372 , Y10T428/139 , Y10T428/24994 , Y10T428/249945 , Y10T428/249946 , Y10T428/31725 , Y10T428/31739
摘要： Disclosed is a polyamide molding compound having heat aging resistance for use as automobile or electrical components and composed of: (A) 27-84.99 wt % of a polyamide mixture consisting of (A1) at least one semiaromatic, semicrystalline polyamide having a melting point of 255° C. to 330° C., (A2) at least one caprolactam-containing polyamide that is different from (A1) and that has a caprolactam content of at least 50 wt %, where the total caprolactam content is 22-30 wt %, with respect to the polyamide mixture, (B) 15-65 wt % of at least one filler and reinforcing agent, (C) 0.01-3.0 wt % of at least one thermal stabilizer, and (D) 0-5.0 wt % of at least one additive, where the components (A)-(D) add up to 100 wt %.
摘要翻译：公开了一种具有耐热老化性的聚酰胺模塑料，其用作汽车或电气部件，并由以下组成：（A）由（A1）至少一种半芳族半结晶聚酰胺组成的聚酰胺混合物27-84.99重量％ 255℃至330℃，（A2）不同于（A1）并且具有至少50重量％的己内酰胺含量的至少一种含己内酰胺的聚酰胺，其中总己内酰胺含量为22-30重量％％，相对于聚酰胺混合物，（B）15-65重量％的至少一种填料和增强剂，（C）0.01-3.0重量％的至少一种热稳定剂，和（D）0-5.0重量％的至少一种添加剂，其中组分（A） - （D）加到100重量％。

3. 发明授权

US08383244B2 Semiaromatic molding compounds and uses thereof 有权
标题翻译：半芳族成型化合物及其用途
公开(公告)号：US08383244B2
公开(公告)日：2013-02-26
申请号：US13481451
申请日：2012-05-25
申请人： Andreas Bayer , Nikolai Lamberts , Botho Hoffmann , Manfred Hewel
发明人： Andreas Bayer , Nikolai Lamberts , Botho Hoffmann , Manfred Hewel
IPC分类号： B32B27/08
CPC分类号： C08L77/06 , C08G69/36 , C08K3/014 , C08K5/005 , C08K7/14 , C08L77/02 , C08L2205/02 , Y10T428/1352 , Y10T428/1372 , Y10T428/139 , Y10T428/24994 , Y10T428/249945 , Y10T428/249946 , Y10T428/31725 , Y10T428/31739
摘要： Disclosed is a polyamide molding compound having heat aging resistance for use as automobile or electrical components and composed of: (A) 27-84.99 wt % of a polyamide mixture consisting of (A1) at least one semiaromatic, semicrystalline polyamide having a melting point of 255° C. to 330° C., (A2) at least one caprolactam-containing polyamide that is different from (A1) and that has a caprolactam content of at least 50 wt %, where the total caprolactam content is 22-30 wt %, with respect to the polyamide mixture, (B) 15-65 wt % of at least one filler and reinforcing agent, (C) 0.01-3.0 wt % of at least one thermal stabilizer, and (D) 0-5.0 wt % of at least one additive, where the components (A)-(D) add up to 100 wt %.
摘要翻译：公开了一种具有耐热老化性的聚酰胺模塑料，其用作汽车或电气部件，并由以下组成：（A）由（A1）至少一种半芳族半结晶聚酰胺组成的聚酰胺混合物27-84.99重量％ 255℃至330℃，（A2）不同于（A1）并且具有至少50重量％的己内酰胺含量的至少一种含己内酰胺的聚酰胺，其中总己内酰胺含量为22-30重量％％，相对于聚酰胺混合物，（B）15-65重量％的至少一种填料和增强剂，（C）0.01-3.0重量％的至少一种热稳定剂，和（D）0-5.0重量％的至少一种添加剂，其中组分（A） - （D）加到100重量％。

4. 发明申请

US20120083558A1 FLAME-PROTECTED, PARTIALLY AROMATIC POLYAMIDE MOLDING COMPOUNDS 有权
标题翻译：防火保护，部分芳族聚酰胺模塑化合物
公开(公告)号：US20120083558A1
公开(公告)日：2012-04-05
申请号：US13376167
申请日：2009-06-05
申请人： Andreas Bayer , Nikolai Lamberts
发明人： Andreas Bayer , Nikolai Lamberts
IPC分类号： C08L77/06 , C08K5/529 , C08K7/14 , C08K5/098 , C08K5/5313
CPC分类号： C08K5/098 , C08K5/34928 , C08K5/5313 , C08L77/06
摘要： The invention relates to a flame-retardant polyamide molding composition based on semicrystalline polyamides. This polyamide molding composition is based on (A) from 30 to 92% by weight of at least one aliphatic or semiaromatic, semicrystalline polyamide with melting point (Tm) in the range from 240° C. to 340° C.; (B) from 0 to 50% by weight of at least one filler and reinforcing agent; (C) from 8 to 18% by weight of at least one halogen-free flame retardant; (D) from 0 to 2.0% by weight of at least one barium carboxylate; (E) from 0 to 5% by weight of at least one additive; wherein the percentages by weight of components (A) to (E) give a total of 100%, and with the proviso that if the proportion of component (D) is in the range from 0 to 0.1% by weight the halogen-free flame retardant of component (C) is based on a barium phosphinate. The invention further relates to the use of barium carboxylate in a polyamide molding composition using a halogen-free flame retardant for inhibiting corrosive action during processing. The molding compositions comply with fire-protection class UL 94 V-0, and have no, or only slight, corrosive action with respect to the machine components used in thermoplastic processing, and exhibit good mechanical properties. They are suitable for producing, in particular, thin-walled moldings for the electrical and electronics industry, examples being housings, housing components, and connectors.
摘要翻译：本发明涉及一种基于半结晶聚酰胺的阻燃聚酰胺模塑组合物。该聚酰胺模塑组合物基于（A）30至92重量％的至少一种脂族或半芳族半结晶聚酰胺，熔点（Tm）在240℃至340℃的范围内。（B）0至50重量％的至少一种填料和增强剂; （C）8至18重量％的至少一种无卤阻燃剂; （D）0至2.0重量％的至少一种羧酸钡; （E）0至5重量％的至少一种添加剂; 其中组分（A）至（E）的重量百分比总计为100％，条件是如果组分（D）的比例在0至0.1重量％的范围内，则不含卤素的火焰组分（C）的阻燃剂基于次膦酸钡。本发明还涉及在使用无卤阻燃剂在加工过程中抑制腐蚀作用的聚酰胺模塑组合物中使用羧酸钡。模塑组合物符合防火等级UL 94 V-0，并且对于热塑性加工中使用的机器部件没有或只有轻微的腐蚀作用，并且具有良好的机械性能。它们特别适用于制造电气和电子工业的薄壁模制件，例如壳体，外壳部件和连接器。

5. 发明授权

US08859662B2 Polyamide moulding material and use thereof for production of LED housing components 有权
标题翻译：聚酰胺成型材料及其用于生产LED外壳部件的用途
公开(公告)号：US08859662B2
公开(公告)日：2014-10-14
申请号：US13096374
申请日：2011-04-28
申请人： Nikolai Lamberts , Andreas Bayer , Manfred Hewel , Heinz Hoff
发明人： Nikolai Lamberts , Andreas Bayer , Manfred Hewel , Heinz Hoff
IPC分类号： C08K3/26 , C08K3/22 , C08K7/14
CPC分类号： C08K3/26 , C08K3/22 , C08K7/14 , C08L77/06
摘要： What is described is a polyamide molding material based on semicrystalline polyamides for production of LED housings or housing components with high strength, high long-term reflectivity and low blistering tendency. The polyamide moulding material proposed consists of the following components (A) 40 to 80% by weight of at least one semiaromatic polyamide based on at least 70 mol % of aromatic dicarboxylic acids and at least 70 mol % of aliphatic diamines having 4 to 18 carbon atoms and having a melting temperature in the range from 270° C. to 340° C. (B) 10 to 30% by weight of titanium dioxide particles (C) 5 to 20% by weight of glass fibres (D) 5-30% by weight of calcium carbonate. The percentages by weight of components (A) to (D) together add up to 100%, with the proviso that components (B), (C) and (D) meet the following conditions: (B)+(C)+(D)=20 to 60% by weight; weight ratio of (C)/(D) in the range from 0.25 to 1.5, where the polyamide molding material may optionally comprise customary additives (E) in addition to components (A) to (D), and where the amount thereof is in addition to the sum of components (A) to (D).
摘要翻译：描述的是用于生产具有高强度，高长期反射率和低起泡倾向的LED壳体或壳体部件的半结晶聚酰胺的聚酰胺模塑材料。提出的聚酰胺成型材料由以下组分（A）40至80重量％的至少一种基于至少70摩尔％的芳族二羧酸和至少70摩尔％的具有4至18个碳原子的脂族二胺的半芳族聚酰胺原子并且具有在270℃至340℃范围内的熔融温度。（B）10至30重量％的二氧化钛颗粒（C）5至20重量％的玻璃纤维（D）5-30 重量％的碳酸钙。组分（A）至（D）的重量百分比一起加起来为100％，条件是组分（B），（C）和（D）满足以下条件：（B）+（C）+（ D）= 20〜60重量％（C）/（D）的重量比在0.25至1.5的范围内，其中除了组分（A）至（D）之外，聚酰胺模塑材料可任选地包含常规添加剂（E），并且其量在（A）至（D）的总和除外。

6. 发明申请

US20110105655A1 FILLED POLYAMIDE MOLDING MATERIALS 有权
标题翻译：填充聚酰胺模塑材料
公开(公告)号：US20110105655A1
公开(公告)日：2011-05-05
申请号：US12742881
申请日：2008-11-12
申请人： Philipp Harder , Nikolai Lamberts
发明人： Philipp Harder , Nikolai Lamberts
IPC分类号： C08K5/529 , C08K5/52
CPC分类号： C08L77/02 , C08J5/08 , C08J2377/00 , C08K5/0066 , C08K5/34922 , C08K5/5313 , C08K7/14 , C08L77/06 , C08L2205/02 , C08L2666/20
摘要： Filled polyamide molding compounds which, in addition to a selected polymer mixture comprising polyamides and a flameproofing agent, contain glass fibers with non-circular cross-sections, the use of such molding compounds for the production of molded articles, and the molded articles themselves.
摘要翻译：填充的聚酰胺模塑料除了所选择的包含聚酰胺和防火剂的聚合物混合物之外，还包含具有非圆形横截面的玻璃纤维，这些模塑料用于制造模塑制品以及模制品本身。

7. 发明申请

US20070249789A1 Transparent polyamide molding compositions 审中-公开
标题翻译：透明聚酰胺成型组合物
公开(公告)号：US20070249789A1
公开(公告)日：2007-10-25
申请号：US11785842
申请日：2007-04-20
申请人： Friedrich Severin Buehler , Nikolai Lamberts , Ralf Hala , Botho Hoffmann
发明人： Friedrich Severin Buehler , Nikolai Lamberts , Ralf Hala , Botho Hoffmann
IPC分类号： C08G69/48
CPC分类号： C08L77/00 , C08L77/02 , C08L77/06 , C08L77/12 , C08L2205/02 , C08L2666/20
摘要： A polyamide molding composition is described, comprising at least one transparent homopolyamide and/or copolyamide in a proportion by weight of from 70 to 99% by weight; at least one further polymer in a proportion by weight of from 1 to 30% by weight; and also optionally further dyes and/or additives. The polyamide molding composition is one wherein the further polymer is a polyesteramide, and wherein the light transmittance to ASTM D1003 of a sheet of thickness 2 mm produced from the polyamide molding composition is at least 88%, and preferably wherein the notched impact resistance of an article produced therefrom is at least 14 kJ/m2.
摘要翻译：描述了一种聚酰胺模塑组合物，其包含至少一种重量比为70-99％（重量）的透明均聚酰胺和/或共聚酰胺; 至少一种重量比为1至30％的另外的聚合物; 以及任选地进一步的染料和/或添加剂。聚酰胺模塑组合物是其中聚合物为聚酯酰胺的组合物，其中由聚酰胺模塑组合物制成的厚度为2mm的片材对ASTM D1003的透光率至少为88％，优选其中由此产生的制品为至少14kJ / m 2。

8. 发明授权

US07993755B2 Photochromic molding compositions and articles produced therefrom 有权
标题翻译：光致变色成型组合物和由其制备的制品
公开(公告)号：US07993755B2
公开(公告)日：2011-08-09
申请号：US12174430
申请日：2008-07-16
申请人： Ralf Hala , Botho Hoffmann , Nikolai Lamberts
发明人： Ralf Hala , Botho Hoffmann , Nikolai Lamberts
IPC分类号： C08G69/26
CPC分类号： G02B1/04 , C08K5/357 , C08L77/02 , C08L77/12 , C08L101/00 , C08L2205/02 , G02B5/23 , Y10T428/261 , Y10T428/29 , Y10T428/2967 , Y10T428/2969 , Y10T428/31504 , Y10T428/31678 , Y10T428/31725 , C08L77/00 , C08L2666/02 , C08L2666/20
摘要： A polyamide molding composition is described, comprising at least one transparent polyesteramide in a proportion by weight of from 70 to 99.99% by weight; at least one further polymer in a proportion by weight of from 0 to 30% by weight; at least one photochromic dye in a proportion by weight of from 0.01 to 2% by weight; and also optionally further dyes and/or additives. The invention further encompasses articles manufactured therefrom, e.g. foils, for the coating of photochromic ophthalmic lenses, or the like.
摘要翻译：描述了一种聚酰胺模塑组合物，其包含至少一种重量比为70-99.99％（重量）的透明聚酯酰胺; 至少一种按重量计0至30％重量比的其它聚合物; 至少一种光致变色染料，其重量比为0.01至2重量％; 以及任选地进一步的染料和/或添加剂。本发明还包括由其制造的制品，例如。箔，用于光致变色眼镜片的涂层等。

9. 发明授权

US09878490B2 Laser beam welding method and molded components fabricated thereby 有权
公开(公告)号：US09878490B2
公开(公告)日：2018-01-30
申请号：US13553068
申请日：2012-07-19
申请人： Jens Butzke , Stefan Würthner , Nikolai Lamberts , Pierre Dübon , Sabine Bertram , Heinz Caviezel
发明人： Jens Butzke , Stefan Würthner , Nikolai Lamberts , Pierre Dübon , Sabine Bertram , Heinz Caviezel
IPC分类号： B29C65/16 , B29C65/00 , B29K105/00
CPC分类号： B29C65/1616 , B29C65/1635 , B29C65/1638 , B29C65/1654 , B29C65/1674 , B29C66/1122 , B29C66/30223 , B29C66/305 , B29C66/47 , B29C66/472 , B29C66/474 , B29C66/71 , B29C66/7332 , B29C66/73365 , B29C66/73366 , B29C66/7352 , B29C66/73771 , B29C66/73772 , B29C66/73773 , B29C66/73774 , B29C66/73776 , B29C66/7392 , B29C66/73921 , B29C66/836 , B29C66/9161 , B29C66/919 , B29C66/929 , B29C66/934 , B29C66/939 , B29K2105/0032 , B29K2105/0079 , B29K2995/0026 , Y10T428/1352 , Y10T428/24851 , B29K2033/08 , B29K2023/00 , B29K2077/00 , B29K2079/085 , B29K2071/12 , B29K2069/00 , B29K2081/06 , B29K2067/00 , B29K2071/00 , B29K2059/00 , B29K2025/06 , B29K2027/06 , B29K2031/04 , B29K2033/12 , B29K2079/08 , B29K2055/02 , B29K2025/08 , B29K2021/003
摘要： The invention relates to a method for laser welding two plastic components A, B brought into contact at least in the joining area, wherein component B facing away from the laser radiation consists of a plastic matrix with a white pigmentation of 1.5 5-20 wt.-%, and component A facing the laser radiation, through which the laser beam passes in the welding process, exhibits a plastic matrix. For a given laser wavelength the travel distance of the laser beam through the component A measures at most 10 mm, and given a white pigmentation of the component A in wt.-%, the product of the travel distance of the laser 10 beam through the component A in mm and white pigmentation in wt.-% is less than 1.25, and the travel distance of the laser beam through the component A measures at most 1 mm.

10. 发明授权

US08324307B2 High-temperature polyamide molding compounds reinforced with flat glass fibers 有权
标题翻译：用平板玻璃纤维增强的高温聚酰胺模塑料
公开(公告)号：US08324307B2
公开(公告)日：2012-12-04
申请号：US12198002
申请日：2008-08-25
申请人： Philipp Harder , Thomas Jeltsch , Nikolai Lamberts
发明人： Philipp Harder , Thomas Jeltsch , Nikolai Lamberts
IPC分类号： C08K3/40 , C08K3/00 , C08G18/34 , C08L77/02 , C08L77/04
CPC分类号： C08G69/26 , C08G69/265 , C08G69/36 , C08K7/14 , C08K2201/016 , C08L77/06 , C08L2205/16
摘要： The present invention relates to reinforced polyamide molding compounds containing high-melting partially aromatic polyamides and flat glass fibers, in particular with a rectangular cross section, i.e., glass fibers with a noncircular cross-sectional area and a dimension ratio of the main cross-sectional axis to the secondary cross-sectional axis of 2 to 6, in particular 3 to 6, most especially preferably from 3.5 to 5.0. The present invention also relates to a method for manufacturing polyamide molding compounds and molded articles manufactured therefrom, i.e., in particular injection-molded parts. The inventive molded parts have a high transverse stiffness and transverse strength.
摘要翻译：本发明涉及含有高熔点部分芳族聚酰胺和扁平玻璃纤维的增强聚酰胺模塑料，特别是具有矩形横截面，即具有非圆形横截面积的玻璃纤维和主横截面的尺寸比轴的次级横截面轴为2至6，特别是3至6，最特别优选为3.5至5.0。本发明还涉及一种用于制造由其制造的聚酰胺模塑料及其模塑制品的方法，特别是注模部件。本发明的模制件具有高横向刚度和横向强度。

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