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1. 发明授权

US07662883B2 Rubbery block polymers containing polylactone and rubber compounds including the same 失效
标题翻译：含有聚内酯和包含它们的橡胶化合物的橡胶嵌段聚合物
公开(公告)号：US07662883B2
公开(公告)日：2010-02-16
申请号：US11617342
申请日：2006-12-28
申请人： Adel Farhan Halasa , Abderrahim Khadir , Wen-Liang Hsu , John Robert Zuppo, III , Marc Weydert
发明人： Adel Farhan Halasa , Abderrahim Khadir , Wen-Liang Hsu , John Robert Zuppo, III , Marc Weydert
IPC分类号： C08K3/36 , C08K3/00 , C08L53/02 , C08L53/00
CPC分类号： C08F297/04 , C08F297/044 , C08K3/36 , C08K5/548 , C08L53/02 , Y10S152/905 , C08L2666/02 , C08L2666/14
摘要： The present invention is directed to rubbery block polymers containing a polylactone, such as polycaprolactone, methods of making the same, and to rubber compounds containing those block polymers. The rubbery block polymer is an anionically polymerized block polymer defined by A-B, wherein A includes at least one type of polymerized conjugated diene monomer, a polymerized vinyl aromatic monomer, or a mixture thereof and wherein B is a polylactone, such as polycaprolactone, which is hydroxy terminated. The rubbery block polymer may be compounded so to provide, for example, a tire tread with desirable properties for use in an automobile tire. Such rubber compound, for example, can include the rubbery block polymer, an organosilane coupling agent, such as a bis(trialkoxysilyl) alkane, bis(trialkoxysilylalkyl) polysulfide, or mixtures thereof, and silica filler in specified amounts.
摘要翻译：本发明涉及含有聚内酯如聚己酸内酯的橡胶嵌段聚合物，其制备方法以及含有这些嵌段聚合物的橡胶化合物。橡胶嵌段聚合物是由AB定义的阴离子聚合的嵌段聚合物，其中A包括至少一种聚合的共轭二烯单体，聚合的乙烯基芳族单体或其混合物，其中B是聚内酯，例如聚己内酯，羟基封端。可以将橡胶状嵌段聚合物复合以提供例如具有用于汽车轮胎的期望性能的轮胎胎面。例如，这种橡胶化合物可以包括橡胶嵌段聚合物，有机硅烷偶联剂，例如双（三烷氧基甲硅烷基）烷烃，双（三烷氧基甲硅烷基烷基）多硫化物或其混合物，以及指定量的二氧化硅填料。

2. 发明授权

US06558805B2 Functionalized rubbery polymer containing polysiloxane 失效
标题翻译：含有聚硅氧烷的官能化橡胶状聚合物
公开(公告)号：US06558805B2
公开(公告)日：2003-05-06
申请号：US09970110
申请日：2001-10-03
申请人： Abderrahim Khadir , Adel Farhan Halasa , Wen-Liang Hsu
发明人： Abderrahim Khadir , Adel Farhan Halasa , Wen-Liang Hsu
IPC分类号： B32B904
CPC分类号： C08G77/442 , Y10T152/10495 , Y10T428/31663
摘要： The present invention relates to an anionic polymerization technique for synthesizing functionalized rubbery polymers containing polysiloxane that have excellent characteristics for utilization in (a) tire tread compounds that are highly loaded with silica, (b) shiny tire side-wall compounds, and (c) tire building bladders having improved mold release characteristics. The rubbery polymers of this invention can optionally be coupled with tin halides or silicon halides to further improve the characteristics of the rubber for use in tire tread compounds. The present invention more specifically discloses a process for synthesizing a rubbery polymer that comprises (1) polymerizing at least one conjugated diolefin monomer to produce a living rubbery polymer, wherein said polymerization is optionally carried out in the presence of a polar modifier, wherein said polymerization is an anionic polymerization that is initiated with an alkylsilyloxy protected functional lithium initiator having a structural formula selected from the group consisting: wherein X represents a group IVa element selected from the group consisting of carbon, silicon, germanium, and tin, wherein Y represents phosphorous or nitrogen, wherein R represents alkyl groups that can be the same or different, wherein the alkyl groups contain from 1 to about 8 carbon atoms, and wherein A represents an alkylene group containing from 1 to about 8 carbon atoms; (2) adding a hexaalkylcyclotrisiloxane monomer to the living rubbery polymer; (3) allowing the hexaalkylcyclotrisiloxane monomer to polymerize to produce a living polysiloxane containing rubber; and optionally, (4) reacting the living polysiloxane containing rubber with a coupling agent selected from the group consisting of tin halides and silicon halides to produce a coupled polysiloxane containing rubber.
摘要翻译：本发明涉及一种用于合成含有聚硅氧烷的官能化橡胶聚合物的阴离子聚合技术，其具有优异的（a）高度负载二氧化硅的轮胎胎面胶料，（b）有光泽的轮胎侧壁化合物，（c）具有改善脱模特性的轮胎成型气囊。本发明的橡胶状聚合物可以任选与锡卤化物或卤化硅偶联，以进一步改善用于轮胎胎面胶料的橡胶的特性。本发明更具体地公开了一种合成橡胶状聚合物的方法，其包括（1）聚合至少一种共轭二烯单体以制备活性橡胶状聚合物，其中所述聚合反应任选在极性改性剂存在下进行，其中所述聚合是由具有选自以下的结构式的烷基甲硅烷氧基保护的官能锂引发剂引发的阴离子聚合：其中X表示选自碳，硅，锗和锡的IVa族元素，其中Y表示磷或氮，其中R表示可以相同或不同的烷基，其中烷基含有1至约8个碳原子，并且其中A表示含有1至约8个碳原子的亚烷基; （2）向活性橡胶状聚合物中加入六烷基环三硅氧烷单体; （3）使六烷基环三硅氧烷单体聚合以制备含有活性聚硅氧烷的橡胶; 和（4）使含有活性聚硅氧烷的橡胶与选自卤化锡和卤化硅的偶合剂反应，生成含有橡胶的偶联聚硅氧烷。

3. 发明申请

US20080161489A1 RUBBERY BLOCK POLYMERS CONTAINING POLYLACTONE AND RUBBER COMPOUNDS INCLUDING THE SAME 失效
标题翻译：包含聚合物和橡胶化合物的橡胶块聚合物包括它们
公开(公告)号：US20080161489A1
公开(公告)日：2008-07-03
申请号：US11617342
申请日：2006-12-28
申请人： Adel Farhan Halasa , Abderrahim Khadir , Wen-Liang Hsu , John Robert Zuppo , Mark Weydert
发明人： Adel Farhan Halasa , Abderrahim Khadir , Wen-Liang Hsu , John Robert Zuppo , Mark Weydert
IPC分类号： C08K3/36
CPC分类号： C08F297/04 , C08F297/044 , C08K3/36 , C08K5/548 , C08L53/02 , Y10S152/905 , C08L2666/02 , C08L2666/14
摘要： The present invention is directed to rubbery block polymers containing a polylactone, such as polycaprolactone, methods of making the same, and to rubber compounds containing those block polymers. The rubbery block polymer is an anionically polymerized block polymer defined by A-B, wherein A includes at least one type of polymerized conjugated diene monomer, a polymerized vinyl aromatic monomer, or a mixture thereof and wherein B is a polylactone, such as polycaprolactone, which is hydroxy terminated. The rubbery block polymer may be compounded so to provide, for example, a tire tread with desirable properties for use in an automobile tire. Such rubber compound, for example, can include the rubbery block polymer, an organosilane coupling agent, such as a bis(trialkoxysilyl) alkane, bis(trialkoxysilylalkyl) polysulfide, or mixtures thereof, and silica filler in specified amounts.
摘要翻译：本发明涉及含有聚内酯如聚己酸内酯的橡胶嵌段聚合物，其制备方法以及含有这些嵌段聚合物的橡胶化合物。橡胶嵌段聚合物是由AB定义的阴离子聚合的嵌段聚合物，其中A包括至少一种聚合的共轭二烯单体，聚合的乙烯基芳族单体或其混合物，其中B是聚内酯，例如聚己内酯，羟基封端。可以将橡胶状嵌段聚合物复合以提供例如具有用于汽车轮胎的期望性能的轮胎胎面。例如，这种橡胶化合物可以包括橡胶嵌段聚合物，有机硅烷偶联剂，例如双（三烷氧基甲硅烷基）烷烃，双（三烷氧基甲硅烷基烷基）多硫化物或其混合物，以及指定量的二氧化硅填料。

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