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1. 发明授权

US4841060A Vapor-phase intramolecular dehydration reaction of alkanolamines 失效
标题翻译：烷醇胺的气相分子内脱水反应
公开(公告)号：US4841060A
公开(公告)日：1989-06-20
申请号：US183474
申请日：1988-04-15
申请人： Youichi Hino , Yuuji Shimasaki , Michio Ueshima
发明人： Youichi Hino , Yuuji Shimasaki , Michio Ueshima
IPC分类号： B01J23/02 , B01J23/04 , B01J23/06 , B01J23/10 , B01J23/14 , C07D203/02 , C07D295/023
CPC分类号： C07D295/023 , B01J23/02 , B01J23/04 , B01J23/06 , B01J23/10 , B01J23/14 , C07D203/02
摘要： Catalytic vapor phase intramolecular dehydration reaction of an alkanolamine represented by the general formula ##STR1## wherein each of R and R' is selected from hydrogen, a methyl group and an ethyl group, and n is an integer of 2 to 5, to convert it into a cyclic amine represented by the general formula ##STR2## wherein R, R' and n are as defined above. The catalyst is an oxide composition represented by the following formulaSi.sub.a X.sub.x Y.sub.y O.sub.bwherein Si is silicon, X is at least one element selected from alkali metals and alkaline earth metals, Y is at least one element selected from B, Al, Ti, Zr, Sn, Zn and Ce, and O is oxygen; and the suffixes a, x, y and b represent the atomic ratios of the elements Si, X, Y and O respectively, and when a=1, x=0.0005-1 and y=0-1, and b is a value determined by a, x and y.
摘要翻译：由通式（I）表示的链烷醇胺的催化气相分子内脱水反应，其中R和R'各自选自氢，甲基和乙基，n为2〜5的整数，将其转化成由通式（II）表示的环胺，其中R，R'和n如上定义。催化剂是由下式SiaXxYyOb表示的氧化物组合物，其中Si是硅，X是选自碱金属和碱土金属中的至少一种元素，Y是选自B，Al，Ti，Zr，Sn， Zn和Ce，O是氧; 并且后缀a，x，y和b分别表示元素Si，X，Y和O的原子比，并且当a = 1，x = 0.0005-1和y = 0-1时，b是确定的值由a，x和y。

2. 发明授权

US5801252A Process for production of cyclic N-vinyl carboxylic acid amide 失效
标题翻译：环状N-乙烯基羧酸酰胺的制备方法
公开(公告)号：US5801252A
公开(公告)日：1998-09-01
申请号：US820283
申请日：1997-03-18
申请人： Hitoshi Yano , Yuuji Shimasaki
发明人： Hitoshi Yano , Yuuji Shimasaki
IPC分类号： C07D211/76 , B01J23/02 , B01J23/04 , C07B61/00 , C07D207/26 , C07D207/267 , C07D207/27 , C07D207/40 , C07D207/404 , C07D211/88 , C07D207/408
CPC分类号： C07D207/267 , B01J23/02 , C07D207/27 , C07D207/404
摘要： There is provided a process for producing a cyclic N-vinyl carboxylic acid amide stably in safety and low cost, using, as starting raw materials, a cyclic carboxylic acid ester and monoethanolamine both available inexpensively and easily. The process comprises subjecting a cyclic carboxylic acid ester and monoethanolamine to an intermolecular dehydration reaction (a first-step reaction) in a liquid phase to produce a cyclic N-(2-hydroxyethyl) carboxylic acid amide and then subjecting the cyclic N-(2-hydroxyethyl) carboxylic acid amide to an intramolecular dehydration reaction (a second-step reaction) in a gas phase in the presence of an oxide catalyst containing an alkali metal element and/or an alkaline earth metal element and silicon, to produce a cyclic N-vinyl carboxylic acid amide.
摘要翻译：提供了以廉价且容易的方式使用环状羧酸酯和单乙醇胺作为起始原料，以安全且低成本稳定地制备环状N-乙烯基羧酸酰胺的方法。该方法包括使环状羧酸酯和单乙醇胺在液相中进行分子间脱水反应（第一步反应），生成环状的N-（2-羟乙基）羧酸酰胺，然后使环状的N-（2- - 羟乙基）羧酸酰胺在含有碱金属元素和/或碱土金属元素和硅的氧化物催化剂存在下在气相中进行分子内脱水反应（第二步反应），以产生环状N - 乙烯基羧酸酰胺。

3. 发明授权

US5700946A Process for production of N-vinyl compound 失效
标题翻译： N-乙烯基化合物的制备方法
公开(公告)号：US5700946A
公开(公告)日：1997-12-23
申请号：US633469
申请日：1996-04-17
申请人： Yuuji Shimasaki , Hideyuki Kanbe , Akira Kurusu
发明人： Yuuji Shimasaki , Hideyuki Kanbe , Akira Kurusu
IPC分类号： B01J23/02 , B01J23/04 , B01J23/648 , B01J27/02 , B01J27/16 , B01J27/18 , B01J27/182 , B01J27/195 , C07B43/00 , C07B61/00 , C07C269/06 , C07C271/12 , C07C271/16 , C07D207/26 , C07D207/267 , C07D263/22 , C07D263/04
CPC分类号： C07D207/267 , B01J27/1806 , C07B43/00 , C07C269/06 , C07D263/22
摘要： The present invention provides a process for producing an N-vinyl compound, which comprises subjecting an N-(-alkoxyalkyl) compound to gas phase intramolecular alcohol elimination to convert said compound to an N-vinyl compound directly in one step, wherein a solid oxide containing phosphorus and an alkali metal and/or an alkaline earth metal is used as a catalyst. This process need not use any solvent or any auxiliary raw material and consequently can produce an N-vinyl compound simply and safely without generating any waste material derived from the auxiliary raw material.
摘要翻译：本发明提供一种N-乙烯基化合物的制造方法，其特征在于，使N - （ - 烷氧基烷基）化合物进行气相分子内醇消除，在一个步骤中直接将所述化合物转化为N-乙烯基化合物，其中，固体氧化物使用含磷和碱金属和/或碱土金属作为催化剂。该方法不需要使用任何溶剂或任何辅助原料，因此可以简单，安全地生产N-乙烯基化合物，而不产生源自辅助原料的任何废料。

4. 发明授权

US5326903A Process for preparing isocyanates using sintered oxides 失效
标题翻译：使用烧结氧化物制备异氰酸酯的方法
公开(公告)号：US5326903A
公开(公告)日：1994-07-05
申请号：US997394
申请日：1992-12-28
申请人： Yuuji Shimasaki , Hideyuki Kanbe , Masako Hokazono
发明人： Yuuji Shimasaki , Hideyuki Kanbe , Masako Hokazono
IPC分类号： C07C263/04
CPC分类号： C07C263/04 , C07C2101/14
摘要： A method for preparing isocyanates by the thermal decomposition of carbamates in the presence of a sintered oxide as catalyst under gaseous phase condition. The sintered oxide is composed of at least one element selected from the group consisting of boron, aluminum, silicon, tin, lead, antimony, zinc, yttrium, lanthanum, titanium, zirconium, niobium, tungsten, and iron. The sintered oxide may be composed of at least one element selected from the group consisting of phosphorus, alkali metal element, and alkaline earth metal element.
摘要翻译：在气相氧化物作为催化剂存在下，通过氨基甲酸酯的热分解制备异氰酸酯的方法。烧结氧化物由选自硼，铝，硅，锡，铅，锑，锌，钇，镧，钛，锆，铌，钨和铁中的至少一种元素组成。烧结氧化物可以由选自磷，碱金属元素和碱土金属元素中的至少一种元素组成。

5. 发明授权

US5262570A Method of producing ethylenediamines 失效
标题翻译：生产乙二胺的方法
公开(公告)号：US5262570A
公开(公告)日：1993-11-16
申请号：US2904
申请日：1993-01-11
申请人： Yuuji Shimasaki , Hideaki Tsuneki , Youichi Hino , Tetsuro Hayashi , Michio Ueshima
发明人： Yuuji Shimasaki , Hideaki Tsuneki , Youichi Hino , Tetsuro Hayashi , Michio Ueshima
IPC分类号： C07C209/60 , C07C209/62
CPC分类号： C07C209/60
摘要： A method of producing ethylenediamines represented by the general formula ##STR1## wherein R represents a hydrogen atom, or a methyl or ethyl group, which comprises reacting an aziridine compound of the general formula ##STR2## wherein R is as defined, with ammonia in the gaseous phase in the presence of a solid acid catalyst. In another aspect, a method of producing ethylenediamines of the general formula (I), which comprises reacting a reaction product containing an aziridine compound of the general formula (II), obtained by the gaseous phase intramolecular dehydration reaction of an alkanolamine represented by the general formula ##STR3## wherein X represents the OH group or the NH.sub.2 group, Y represents the NH.sub.2 group when X is the OH group and the OH group when X is the NH.sub.2 group, and R is as defined,in the presence of a catalyst A, with ammonia in the gaseous phase in the presence of a solid acid catalyst (catalyst B).
摘要翻译：制备由通式（I）表示的乙二胺的方法，其中R表示氢原子或甲基或乙基，其包括使通式为（II）的氮丙啶化合物（其中R为：在固体酸催化剂存在下，在气相中用氨气。另一方面，制备通式（I）的亚乙基二胺的方法，该方法包括使含有由通式（II）表示的链烷醇胺的气态分子内脱水反应获得的通式（II）的氮丙啶化合物的反应产物式（III）其中X表示OH基团或NH2基团，当X为OH基团时，Y表示NH2基团，当X为NH2基团时为OH基团，R为定义，R为催化剂A，在固体酸催化剂（催化剂B）的存在下，在气相中具有氨。

6. 发明授权

US4774218A Catalyst for vapor-phase intramolecular dehydration reaction of alkanolamines 失效
标题翻译：烷醇胺气相分子内脱水反应催化剂
公开(公告)号：US4774218A
公开(公告)日：1988-09-27
申请号：US943085
申请日：1986-12-18
申请人： Yuuji Shimasaki , Hideaki Tuneki , Youichi Hino , Hitoshi Yano , Michio Ueshima
发明人： Yuuji Shimasaki , Hideaki Tuneki , Youichi Hino , Hitoshi Yano , Michio Ueshima
IPC分类号： B01J27/18 , B01J27/182 , B01J27/188 , B01J27/19 , B01J27/195 , C07D203/08 , C07D205/04 , C07D211/02 , C07D295/023 , B01J27/16
CPC分类号： C07D203/08 , B01J27/1802 , B01J27/1804 , B01J27/182 , B01J27/188 , B01J27/19 , B01J27/195 , C07D205/04 , C07D211/02 , C07D295/023
摘要： A catalyst for the vapor phase intramolecular dehydration reaction of an alkanolamine represented by the general formula ##STR1## wherein each of R and R' is selected from hydrogen, a methyl group and an ethyl group, and n is an integer of 2 to 5, to convert it into a cyclic amine represented by the general formula ##STR2## wherein R, R' and n are as defined above. The catalyst is an oxide composition represented by the following formulaX.sub.a P.sub.b Y.sub.c O.sub.dwherein X is at least one element selected from alkali metals and alkaline earth metals, P is phosphorus, Y is at least one element selected from B, Al, Si, S, Sc, Ti, Cu, Y, Zr, Nb, Mo, Sn, Sb, La, Ce, Ta, W, Tl, Pb, Bi and Th, O is oxygen, the suffixes a, b, c and d represent the atomic ratios of the elements X, P, Y and O, and when a=1, b=0.01-3 and c=0-100, and d is a value determined by a, b and c and the state of bonding of the constituent elements.
摘要翻译：由通式（I）表示的链烷醇胺的气相分子内脱水反应的催化剂，其中R和R'各自选自氢，甲基和乙基，n为整数2 至5，将其转化为由通式（II）表示的环胺，其中R，R'和n如上所定义。催化剂是由下式XaPbYcOd表示的氧化物组合物，其中X是选自碱金属和碱土金属中的至少一种元素，P是磷，Y是选自B，Al，Si，S，Sc中的至少一种元素， Ti，Cu，Y，Zr，Nb，Mo，Sn，Sb，La，Ce，Ta，W，Tl，Pb，Bi和Th，O是氧，后缀a，b，c和d表示元素X，P，Y和O以及当a = 1时，b = 0.01-3和c = 0-100，d是由a，b和c确定的值以及组成元素的结合状态。

7. 发明授权

US06489515B2 Gas-phase dehydration reaction process 失效
标题翻译：气相脱水反应过程
公开(公告)号：US06489515B2
公开(公告)日：2002-12-03
申请号：US09769442
申请日：2001-01-26
申请人： Hideyuki Kambe , Shukichi Ugamura , Yuuji Shimasaki , Shinji Takasaki
发明人： Hideyuki Kambe , Shukichi Ugamura , Yuuji Shimasaki , Shinji Takasaki
IPC分类号： C07C4109
CPC分类号： C07D207/267 , C07B35/06 , C07C41/09 , C07C41/18 , C07D203/02 , C07C43/16 , C07C43/23
摘要： Here is provided a process capable of efficiently carrying out a gas-phase dehydration reaction comprising contacting a raw material gas with a solid oxide catalyst containing an alkali metal element to allow reaction to progress by inhibiting decomposition of the raw material and the objective product. This process comprises using a sintered oxide comprising an alkali metal element and silica and/or alumina as a loading material for preheating of the raw material gas and/or as a supporting material for fixation of the position of the catalyst.
摘要翻译：提供一种能够有效地进行气相脱水反应的方法，包括使原料气体与含有碱金属元素的固体氧化物催化剂接触，以通过抑制原料和目标产物的分解来进行反应。该方法包括使用包含碱金属元素和二氧化硅和/或氧化铝的烧结氧化物作为用于预热原料气体的负载材料和/或用作固定催化剂位置的支撑材料。

8. 发明授权

US06436243B1 Process for recovering N-vinyl-2-pyrrolidone 有权
标题翻译：回收N-乙烯基-2-吡咯烷酮的方法
公开(公告)号：US06436243B1
公开(公告)日：2002-08-20
申请号：US09690846
申请日：2000-10-18
申请人： Yoshinari Yamaguchi , Hitoshi Yano , Akira Kurusu , Yuuji Shimasaki
发明人： Yoshinari Yamaguchi , Hitoshi Yano , Akira Kurusu , Yuuji Shimasaki
IPC分类号： B01D342
CPC分类号： C07D207/267 , C07D207/27
摘要： A process for recovering N-vinyl-2-pyrrolidone is provided which allows to recover N-vinyl-2-pyrrolidone efficiently and steadily and in high purity by continuous distillation from a mixed liquid containing N-vinyl-2-pyrrolidone, N-(2-hydroxyethyl)-2-pyrrolidone, compounds having a higher boiling point than N-vinyl-2-pyrrolidone and water. The process includes continuously distilling the mixed liquid using a distilling column, controlling the temperature of the bottom liquid of the distilling column at 180° C. or less.
摘要翻译：提供了一种回收N-乙烯基-2-吡咯烷酮的方法，其通过连续蒸馏从含有N-乙烯基-2-吡咯烷酮，N-（乙烯基-2-吡咯烷酮，N-乙烯基-2-吡咯烷酮的混合液体）中有效且稳定且高纯度地回收N-乙烯基-2-吡咯烷酮， 2-羟乙基）-2-吡咯烷酮，沸点高于N-乙烯基-2-吡咯烷酮和水的化合物。该方法包括使用蒸馏塔连续蒸馏混合液，将蒸馏塔的底部液体的温度控制在180℃以下。

9. 发明授权

US5650544A Process for production of unsaturated ether and catalyst used for production of unsaturated ether 失效
标题翻译：用于生产不饱和醚的不饱和醚和催化剂的生产方法
公开(公告)号：US5650544A
公开(公告)日：1997-07-22
申请号：US528859
申请日：1995-09-15
申请人： Kimio Ariyoshi , Yuuji Shimasaki
发明人： Kimio Ariyoshi , Yuuji Shimasaki
IPC分类号： B01J23/04 , B01J27/182 , C07C41/18 , C07C41/28
CPC分类号： C07C41/18 , B01J23/04 , B01J27/182
摘要： The present invention provides a process for producing an unsaturated ether, which comprises subjecting a glycol ether to intramolecular dehydration in a gas phase in the presence of a catalyst to convert the glycol ether into an unsaturated ether directly in a one-step reaction. As the catalyst, an oxide containing, for example, silicon and an alkali metal is used. The process, which uses no auxiliary raw material, can produce an unsaturated ether (a vinyl ether and/or an allyl ether) simply and safely without generating any waste material derived from the auxiliary raw material.
摘要翻译：本发明提供一种不饱和醚的制造方法，其特征在于，在催化剂存在下，使二醇醚进行气相分子内脱水，直接在一步反应中将二醇醚转化为不饱和醚。作为催化剂，使用含有例如硅和碱金属的氧化物。不使用辅助原料的方法可以简单，安全地生产不饱和醚（乙烯基醚和/或烯丙基醚），而不产生源自辅助原料的任何废料。

10. 发明授权

US5625076A Catalyst for production of tertiary N-alkenyl carboxylic acid amide, and process for production of tertiary N-alkenyl carboxylic acid amide using said catalyst 失效
标题翻译：用于制备叔N-链烯基羧酸酰胺的催化剂，以及使用所述催化剂制备叔N-链烯基羧酸酰胺的方法
公开(公告)号：US5625076A
公开(公告)日：1997-04-29
申请号：US529324
申请日：1995-09-18
申请人： Yuuji Shimasaki , Hitoshi Yano , Kimio Ariyoshi
发明人： Yuuji Shimasaki , Hitoshi Yano , Kimio Ariyoshi
IPC分类号： B01J23/02 , B01J23/04 , B01J27/182 , C07C231/12 , C07D207/26 , C07D207/267
CPC分类号： C07D207/267 , B01J23/02 , B01J23/04 , B01J27/182 , C07C231/12
摘要： The present invention provides a catalyst which is an oxide comprising silicon and at least one element selected from the group consisting of alkali metals and alkaline earth metals and which is used for gas-phase intramolecular dehydration of a tertiary N-(2-hydroxyalkyl) carboxylic acid amide to synthesize a tertiary N-alkenyl carboxylic acid amide. This catalyst enables continuous and efficient production of a tertiary N-alkenyl carboxylic acid amide from a tertiary N-(2-hydroxyalkyl) carboxylic acid amide without using any auxiliary raw material, and consequently allows for simple and safe production of a tertiary N-alkenyl carboxylic acid amide without generating any by-product (waste product) derived from the auxiliary raw material.
摘要翻译：本发明提供一种催化剂，其是包含硅和至少一种选自碱金属和碱土金属的元素的氧化物，其用于三次N-（2-羟基烷基）羧酸的气相分子内脱水酰胺，合成叔N-链烯基羧酸酰胺。该催化剂能够在不使用任何辅助原料的情况下从叔N-（2-羟基烷基）羧酸酰胺连续且有效地制备叔N-链烯基羧酸酰胺，从而允许简单和安全地生产叔N-烯基不产生源自辅助原料的任何副产物（废物）。

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