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1. 发明授权

US07081484B2 Anion exchange membrane, process for its production and solution treating apparatus 有权
标题翻译：阴离子交换膜，其生产和溶液处理设备的工艺
公开(公告)号：US07081484B2
公开(公告)日：2006-07-25
申请号：US09909898
申请日：2001-07-23
申请人： Yoshio Sugaya , Hiroshi Toda , Yukio Matsumura , Hirohisa Kubota
发明人： Yoshio Sugaya , Hiroshi Toda , Yukio Matsumura , Hirohisa Kubota
IPC分类号： C08J5/20
CPC分类号： B01D67/0093 , B01D69/10 , B01D69/141 , B01D71/28 , B01D71/82 , C08J5/2243 , C08J2325/04
摘要： An anion exchange membrane comprising a resin phase which contains from 20 to 96 mass % of a polymer having repeating units represented by the following formula (1): wherein A is a C3-8 alkylene group or an alkyleneoxyalkyl group having a total carbon number of from 4 to 9, each of R1, R2 and R3 is a hydrogen atom, a C1-6 alkyl group or a hydroxyalkyl group, and X− is an anion, and wherein any hydrogen atom bonded to the benzene ring may be substituted by an alkyl group or a halogen atom, and from 4 to 80 mass % of a thermoplastic polymer having no ion exchange groups, substantially uniformly.
摘要翻译：一种阴离子交换膜，其含有含有20〜96质量％的具有下述式（1）表示的重复单元的聚合物的树脂相：其中A为C 3〜8亚烷基或总碳数为4〜9的烷氧基烷基，R 1，R 2和R 3各自为氢原子， C 1-6烷基或羟烷基，X -O - 是阴离子，并且其中与苯环键合的任何氢原子可以被烷基或卤素原子和4〜80质量％的不具有离子交换基团的热塑性聚合物，基本均匀。

2. 发明授权

US5300228A Method for separating and recovering an acid 失效
标题翻译：分离和回收酸的方法
公开(公告)号：US5300228A
公开(公告)日：1994-04-05
申请号：US894642
申请日：1992-06-05
申请人： Yoshio Sugaya , Misaki Kanazawa , Haruhisa Miyake
发明人： Yoshio Sugaya , Misaki Kanazawa , Haruhisa Miyake
IPC分类号： B01D61/24 , C01B7/07 , C01B7/19 , C01B17/90 , C01B21/46 , C08J5/22
CPC分类号： B01D61/243 , C01B17/902 , C01B21/46 , C01B7/0706 , C01B7/198 , C08J5/2275 , C08J2327/18
摘要： A method for separating and recovering an acid, which comprises contacting to one side of a diffusion dialysis membrane an acid solution containing an acid having an acid radical with a formula weight of at most 200 and impurities and to the other side of the membrane water or a dilute acid solution, to separate and recover the acid in the solution, wherein the diffusion dialysis membrane comprises a cation exchange membrane having certain specific properties or comprises a main layer of an anion exchanger and a surface layer of the cation exchange membrane having certain specific properties formed on the main layer at the side of which is contact with the acid solution.
摘要翻译：一种用于分离和回收酸的方法，其包括使扩散透析膜的一侧与含有至多200个酸重量的酸基和杂质的酸溶液和膜的另一侧接触，或者稀酸溶液，以分离和回收溶液中的酸，其中扩散透析膜包含具有某些特定性质的阳离子交换膜或包含阴离子交换剂的主层和阳离子交换膜的表面层，其具有特定的在主层上形成的与酸溶液接触的性质。

3. 发明授权

US06569301B2 Cation exchange membrane selectively permeable to monovalent cations and method for its production 有权
公开(公告)号：US06569301B2
公开(公告)日：2003-05-27
申请号：US09964518
申请日：2001-09-28
申请人： Yoshio Sugaya , Motoo Fukui , Yoshiharu Aoki
发明人： Yoshio Sugaya , Motoo Fukui , Yoshiharu Aoki
IPC分类号： C25B1300
CPC分类号： C08J5/2231 , B01D61/52 , B01J47/12 , C02F1/42 , C08J5/2287 , C08J2389/00
摘要： The present invention provides a cation exchange membrane which has excellent durability, a high limiting current density, a low direct current membrane resistance and excellent selectivity to monovalent cations. In the present invention, a cation exchange membrane excellent in selective permeability to monovalent cations is produced by bringing high molecular cations into contact with a surface of a cation exchange membrane in the presence of anions of an oxyacid or anions of an organic sulfonic acid.

4. 发明授权

US06471867B2 Electro-regenerating type apparatus for producing deionized water 有权
标题翻译：用于生产去离子水的电再生型装置
公开(公告)号：US06471867B2
公开(公告)日：2002-10-29
申请号：US09731792
申请日：2000-12-08
申请人： Yoshio Sugaya , Yukio Matsumura , Hiroshi Toda
发明人： Yoshio Sugaya , Yukio Matsumura , Hiroshi Toda
IPC分类号： B01D1706
CPC分类号： C02F1/4695 , B01D61/48 , B01J49/30 , C02F1/42 , C02F1/4604 , C02F2201/46115
摘要： An electro-regenerating type apparatus for producing deionized water, which comprises an electrodialyzer having cation exchange membranes and anion exchange membranes alternately arranged between an anode compartment provided with an anode and a cathode compartment provided with a cathode, demineralizing compartments compartmentalized with the anion exchange membranes on the anode side and compartmentalized with the cation exchange membranes on the cathode side, and concentrating compartments compartmentalized with the cation exchange membranes on the anode side and compartmentalized with the anion exchange membranes on the cathode side, the electrodialyzer having ion exchangers accommodated in the demineralizing compartments, wherein a porous anion exchanger layer having a porosity of from 20 to 95%, a maximum pore size of from 0.01 to 500 &mgr;m and a thickness of at least five times the maximum pore size and from 10 &mgr;m to 10 mm, is provided on the anode side of each anion exchange membrane.
摘要翻译：一种用于生产去离子水的电再生型装置，其包括具有阳离子交换膜的电渗析器和交替布置在设置有阳极的阳极室和设置有阴极的阴极室之间的阴离子交换膜，所述阳离子隔室与阴离子交换膜隔开在阳极侧并与阴极侧的阳离子交换膜分隔开，并且在阳极侧与阳离子交换膜间隔的浓缩隔室与阴极侧的阴离子交换膜分隔开，电离渗析器具有容纳在脱矿质中的离子交换器隔室，其中提供孔隙率为20至95％，最大孔径为0.01至500μm，厚度为至少5倍最大孔径和10mum至10mm的多孔阴离子交换剂层在每个阴离子交换膜的阳极侧 rane。

5. 发明授权

US5889572A Liquid crystal display device 失效
标题翻译：液晶显示装置
公开(公告)号：US5889572A
公开(公告)日：1999-03-30
申请号：US720416
申请日：1996-09-30
申请人： Hiroyuki Takahashi , Takayuki Iura , Yoshio Sugaya
发明人： Hiroyuki Takahashi , Takayuki Iura , Yoshio Sugaya
IPC分类号： G02F1/1333 , G02F1/13 , G02F1/1345 , H05K1/14 , H05K3/36
CPC分类号： G02F1/13452 , H05K1/147 , H05K1/14 , H05K1/148 , H05K3/361
摘要： A liquid crystal display device which reduces the width of the frame and effectively utilizes the corner of the device. The liquid crystal display device comprises a liquid crystal display element; printed circuit boards arranged along at least two adjoining sides of the liquid crystal display element and mounting electronic components to drive the liquid crystal display element; a case to accommodate the liquid crystal display element and the printed circuit boards; and an interconnect board provided at the corner made by the two sides of the liquid crystal display element to electrically connect the printed circuit boards, the interconnect board being arranged to overlap the liquid crystal display element.
摘要翻译：一种液晶显示装置，其减小框架的宽度并有效地利用装置的角部。液晶显示装置包括液晶显示元件; 印刷电路板沿着液晶显示元件的至少两个相邻侧布置并安装电子部件以驱动液晶显示元件; 用于容纳液晶显示元件和印刷电路板的壳体; 以及设置在由液晶显示元件的两侧制成的角部以将印刷电路板电连接的互连板，所述互连板布置成与液晶显示元件重叠。

6. 发明授权

US5128378A Cation exchanger 失效
标题翻译：阳离子交换器
公开(公告)号：US5128378A
公开(公告)日：1992-07-07
申请号：US591810
申请日：1990-10-02
申请人： Yoshio Sugaya , Josho Kashiwame , Ichiro Terada
发明人： Yoshio Sugaya , Josho Kashiwame , Ichiro Terada
IPC分类号： C08L81/00 , B01J39/18 , B01J45/00 , C08G75/00 , C08G75/02 , C08G75/23 , C08J5/22 , C08K5/00 , C08L81/06
CPC分类号： B01J39/18 , C08G75/02
摘要： A cation exchanger of polysulfone polymer consisting essentially of a sulfonated product of a polysulfone polymer having at least one chloromethyl (--CH.sub.2 Cl) or mercapto (--SH) group per molecule, or a cured product thereof, and having an ion exchange capacity of from 0.5 to 3.5 meq/g dry resin.
摘要翻译：聚砜聚合物的阳离子交换剂，其主要由每分子具有至少一个氯甲基（-CH 2 Cl）或巯基（-SH）基团的聚砜聚合物的磺化产物或其固化产物组成，离子交换容量为0.5 至3.5meq / g干树脂。

7. 发明授权

US5039382A Method for producing an alkali metal hydroxide 失效
标题翻译：碱金属氢氧化物的制造方法
公开(公告)号：US5039382A
公开(公告)日：1991-08-13
申请号：US309731
申请日：1989-02-03
申请人： Koji Suzuki , Yoshio Sugaya , Atsushi Watakabe , Tetsugi Shimohira
发明人： Koji Suzuki , Yoshio Sugaya , Atsushi Watakabe , Tetsugi Shimohira
IPC分类号： C08J5/22 , C25B1/46
CPC分类号： C25B1/46 , C08J5/2281 , C08J2327/18 , C08J2371/12
摘要： A method for producing an alkali metal hydroxide by electrolysis in an electrolytic cell comprising an anode compartment and a cathode compartment, which comprises supplying an aqueous alkali metal chloride solution to the anode compartment and withdrawing an aqueous alkali metal hydroxide solution from the cathode compartment, wherein a fluorine-containing cation exchange membrane comprising a first layer of an alkali resistant cation exchanger with a thickness of at least 5 .mu.m selected from the group consisting of the following (a), (b), and (c), and a second layer of a perfluorocarbon polymer having --CO.sub.2 M groups (wherein M is an alkali metal) and a water content of from 2 to 7% by weight in a 45 wt% NaOH aqueous solution with a thicknesss of at least 5 .mu.m, is disposed with the first layer facing the cathode compartment;(a) a layer of a cation exchanger having alkali resistant inorganic particles or fibrils dispersed therein,(b) a layer of porous material of a cation exchange resin with minimum permability, and(c) a layer of a cation exchanger having an alkali resistant polymer having no ion exchange groups embedded therein.
摘要翻译：一种在包括阳极室和阴极室的电解池中通过电解生产碱金属氢氧化物的方法，包括向阳极室供应碱金属氯化物水溶液并从阴极室中取出碱金属氢氧化物水溶液，其中一种含氟阳离子交换膜，其包含选自以下（a），（b）和（c）中的至少5μm的厚度的耐碱性阳离子交换剂的第一层，和第二层在厚度为至少5μm的45重量％NaOH水溶液中，具有-CO 2 M基团（其中M为碱金属）和含水量为2至7重量％的全氟化碳聚合物层与第一层面向阴极室; （a）具有分散在其中的具有耐碱性无机颗粒或原纤维的阳离子交换剂层，（b）具有最小渗透性的阳离子交换树脂的多孔材料层，和（c）具有耐碱性的阳离子交换剂层没有嵌入离子交换基团的聚合物。

8. 发明授权

US4385150A Organic solution of fluorinated copolymer having carboxylic acid groups 失效
标题翻译：含有羧酸基团的氟化共聚物的有机溶液
公开(公告)号：US4385150A
公开(公告)日：1983-05-24
申请号：US309775
申请日：1981-10-08
申请人： Haruhisa Miyake , Yoshio Sugaya , Tatsuro Asawa
发明人： Haruhisa Miyake , Yoshio Sugaya , Tatsuro Asawa
IPC分类号： C08L27/12 , B01D71/32 , C08F14/00 , C08F14/18 , C08F214/18 , C08J3/09 , C08J3/11 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L101/00 , C08K5/05
CPC分类号： C08J3/09 , C08F214/184 , C08J2327/12
摘要： An organic solution of a fluorinated copolymer having carboxylic acid groups comprises the copolymer of fluorinated ethylenically unsaturated monomer and a functional monomer having carboxylic acid group (--COOH group) dissolved in a hydrophilic organic solvent with a small amount of water.
摘要翻译：具有羧酸基团的含氟共聚物的有机溶液包括氟化烯键式不饱和单体和在亲水性有机溶剂中溶解少量水的具有羧酸基（-COOH基）的官能单体的共聚物。

9. 发明授权

US4298699A Process for producing fluorinated polymer having ion-exchange groups 失效
标题翻译：制备具有离子交换基团的氟化聚合物的方法
公开(公告)号：US4298699A
公开(公告)日：1981-11-03
申请号：US119521
申请日：1980-02-07
申请人： Tatsuro Asawa , Haruhisa Miyake , Masami Yamashita , Yoshio Sugaya
发明人： Tatsuro Asawa , Haruhisa Miyake , Masami Yamashita , Yoshio Sugaya
IPC分类号： C08F214/18 , B01J39/20
CPC分类号： C08F214/184
摘要： A fluorinated copolymer having ion-exchange group is produced by copolymerizing a fluorinated ethylenic unsaturated monomer and a functional monomer having a functional group of carboxylic acid group or a group which can be converted to carboxylic acid group in an aqueous medium in the presence of a polymerization initiator source. The fluorinated copolymer obtained by the copolymerization is treated with an alcohol at higher than 20.degree. C. in the form of particles before a molding. The melt flowability of the fluorinated copolymer is improved.
摘要翻译：具有离子交换基团的氟化共聚物是通过使氟化烯属不饱和单体和具有羧酸基官能团的官能单体或能够在水性介质中转化为羧酸基团的官能单体在聚合反应启动源。通过共聚获得的含氟共聚物在成型前以高于20℃的醇以颗粒的形式进行处理。氟化共聚物的熔体流动性提高。

10. 发明授权

US06780893B2 Anion exchanger and process for producing anion exchange membrane 失效
标题翻译：阴离子交换器和阴离子交换膜的生产工艺
公开(公告)号：US06780893B2
公开(公告)日：2004-08-24
申请号：US10207147
申请日：2002-07-30
申请人： Yoshio Sugaya , Hisao Kawazoe
发明人： Yoshio Sugaya , Hisao Kawazoe
IPC分类号： C08J522
CPC分类号： C08L81/06 , C08G2650/02 , C08J5/2256 , C08J2371/12
摘要： A process for producing an anion exchange membrane, which comprises mixing from 25 to 95 mass % of a polymer having anion exchange groups or active groups convertible to anion exchange groups (hereinafter referred to as polymer 1), and from 5 to 75 mass % of a polymer having no anion exchange groups or no active groups convertible to anion exchange groups (hereinafter referred to as polymer 2), and forming the obtained composition into a membrane, said process including a step of cross-linking an aromatic ring of a repeating unit constituting polymer 1 with an aromatic ring of another repeating unit constituting polymer 1 or with a cross-linkable site of polymer 2, and in a case where polymer 1 is a polymer having active groups convertible to anion exchange groups, a step of converting the active groups to anion exchange groups.
摘要翻译：一种阴离子交换膜的制造方法，其特征在于，将25〜95质量％的具有阴离子交换基团或可转换成阴离子交换基团的活性基团（以下称为聚合物1）的聚合物与5〜75质量％没有阴离子交换基的聚合物或没有可转化成阴离子交换基团的活性基团（以下称为聚合物2），并将所得组合物形成膜，所述方法包括使重复单元的芳香环交联的步骤构成具有构成聚合物1的另一重复单元的芳香环的聚合物1或聚合物2的可交联位点，在聚合物1为具有可转化为阴离子交换基团的活性基团的聚合物的情况下，组成阴离子交换基团。

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