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1. 发明授权

US6166225A Processes for producing dialdehyde monoacetals 失效
标题翻译：制备二醛单缩醛的方法
公开(公告)号：US6166225A
公开(公告)日：2000-12-26
申请号：US403215
申请日：1999-10-15
申请人： Yasutaka Tanaka , Hiroaki Uenakai , Giichi Shimada
发明人： Yasutaka Tanaka , Hiroaki Uenakai , Giichi Shimada
IPC分类号： C07D317/26 , C07D321/00
CPC分类号： C07D317/26
摘要： In a method of producing a dialdehyde monoacetal(s) (III) from dialdehyde(s) (I) and diol(s) (II), the present invention provides a method comprising a first step wherein said dialdehyde(s) (I) and said diol(s) (II) are reacted to produce dialdehyde bisacetal(s) (IV), the amount by mole of said diol(s) (II) being at least twice the amount by mole of said dialdehyde (I) and a second step wherein said dialdehyde bisacetal(s) (IV) is reacted with said dialdehyde (I). The present invention also provides a method of producing a glutaraldehyde monoacetal via reacting 2-Y-3, 4-dihydro-2H-pyran or a ring-substituted derivative thereof with diol. This method comprises a second step reaction wherein glutaraldehyde (iv) which is one of the by-products of the first step reaction is reacted with glutaraldehyde bisacetal (v) which is another by-product of said first reaction. According to the present invention, in the above-mentioned method of producing a glutaraldehyde monoacetal (iii), after the end of the first step reaction, the crude reaction solution is heated at a temperature of from 100.degree. C. to 200.degree. C. to produce the glutaraldehyde monoacetal (iii) from the by-products, low boiling-point components produced from the substituant group Y being removed via distillation.
摘要翻译： PCT No.PCT / JP99 / 00692 Sec。 371 1999年10月15日第 102（e）日期1999年10月15日PCT提交1999年2月17日PCT公布。出版物WO99 / 41249 日期1999年8月19日在从二醛（I）和二醇（II）制备二醛单缩醛（III）的方法中，本发明提供了一种包括第一步骤的方法，其中所述二醛 s）（I）和所述二醇（II）反应生成二醛双缩醛（IV），所述二醇（II）的摩尔量为所述二醇（II）的摩尔量的至少两倍，二醛（I）和第二步，其中所述二醛双缩醛（Ⅳ）与所述二醛（I）反应。本发明还提供了通过使2-Y-3,4-二氢-2H-吡喃或其环取代的衍生物与二醇反应制备戊二醛单缩醛的方法。该方法包括第二步反应，其中作为第一步反应的副产物之一的戊二醛（iv）与作为所述第一反应的另一副产物的戊二醛双缩醛（v）反应。根据本发明，在上述戊二醛单缩醛（ⅲ）的制造方法中，在第一步反应结束后，将粗反应溶液在100℃〜200℃的温度下加热。从副产物生产戊二醛单缩醛（ⅲ）时，通过蒸馏除去由取代基Y产生的低沸点成分。

2. 发明授权

US5258541A Process for producing carbonic acid ester 失效
标题翻译：生产碳酸酯的方法
公开(公告)号：US5258541A
公开(公告)日：1993-11-02
申请号：US844982
申请日：1992-02-27
申请人： Shigeru Yokota , Yasutaka Tanaka , Hiroto Miyake
发明人： Shigeru Yokota , Yasutaka Tanaka , Hiroto Miyake
IPC分类号： C07C68/00 , C07C69/96
CPC分类号： C07C68/005
摘要： A carbonic acid ester is produced by reacting an alcohol with carbon monoxide and oxygen in the presence of a catalyst comprising a cupric salt of a weak acid and/or a cupric halide and an alkaline earth metal salt of a weak acid and/or an alkaline earth metal halide.
摘要翻译：在含有弱酸和/或二卤化铜的铜盐和弱酸和/或碱的碱土金属盐的催化剂存在下，使醇与一氧化碳和氧气反应制备碳酸酯地球金属卤化物。

3. 发明授权

US5091563A Process for preparing .alpha.-phenylpropionic acid derivative 失效
标题翻译：制备（ALPHA） - 苯基丙酸衍生物的方法
公开(公告)号：US5091563A
公开(公告)日：1992-02-25
申请号：US453154
申请日：1989-12-11
申请人： Yasutaka Tanaka , Hidetaka Kojima , Yasuo Tsuji
发明人： Yasutaka Tanaka , Hidetaka Kojima , Yasuo Tsuji
IPC分类号： B01J27/13 , B01J27/00 , C07B61/00 , C07C51/00 , C07C51/12 , C07C51/48 , C07C57/30 , C07C67/00
CPC分类号： C07C51/12 , Y02P20/584
摘要： A process for preparing an .alpha.-phenylpropionic acid derivative wherein an .alpha.-phenylethyl alcohol derivative is reacted with carbon monoxide in the presence of a catalyst to give an .alpha.-phenylpropionic acid derivative, which comprises carrying out the reaction in either one of the following manners (I), (II) and (III):(I) effecting said reaction in the presence of a rhodium catalyst, as said catalyst, together with an iodine compound in such an amount as to give a Rh to I ratio on an atomic basis of 1:0.5 to 1:6; adjusting the concentration of water in the reaction mixture to a level of 2 mol/l or below; and employing a reaction temperature of 130.degree. C. or below,(II) employing a mixture of a hydrocarbon and an oxygen-containing organic compound as a solvent, or(III) effecting said reaction in the presence of a rhodium catalyst, as said catalyst, and an iodine compound; adding water optionally together with an oxygen-containing organic compound as an extraction solvent to the resulting reaction mixture to thereby separate the same into two layers, i.e., a layer containing the reaction product and an aqueous layer; and repeatedly using the rhodium catalyst contained in said aqueous layer.

4. 发明申请

US20120196187A1 Solvent for Electrolyte Solution, Electrolyte Solution, and Gel-like Electrolyte 有权
标题翻译：电解液，电解液和凝胶状电解质溶剂
公开(公告)号：US20120196187A1
公开(公告)日：2012-08-02
申请号：US13498422
申请日：2010-09-28
申请人： Tatsuo Fujinami , Yasutaka Tanaka , Yasutoshi Iriyama
发明人： Tatsuo Fujinami , Yasutaka Tanaka , Yasutoshi Iriyama
IPC分类号： H01M10/0564
CPC分类号： H01M10/0565 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M2300/0034 , H01M2300/0037 , H01M2300/0085 , Y02E60/122 , Y02T10/7011
摘要： The invention provides a solvent for an electrolyte solution, an electrolyte solution, and a gel-like electrolyte superior in oxidation resistance and flame resistance. A solvent for an electrolyte solution comprising at least one boric ester represented by the following formula (I), and a boric ester represented by the following formula (II): B(ORf)3 (I); B(OCH2CH2CN)3 (II) wherein, in formula (I), each Rf independently represents CH2(CF2)nCF3 or CH(CF3)2, n is an integer from 0 to 6, and at least a part of each of —ORf and —OCH2CH2CN included in the boric esters is transesterified.
摘要翻译：本发明提供了电解质溶液，电解质溶液和耐氧化性和阻燃性优异的凝胶状电解质的溶剂。一种包含至少一种由下式（I）表示的硼酸酯的电解质溶液和由下式（II）表示的硼酸酯：B（ORf）3（I）; B（OCH 2 CH 2 CN）3（II）其中，在式（I）中，每个Rf独立地表示CH 2（CF 2）n CF 3或CH（CF 3）2，n为0至6的整数，包含在硼酸酯中的OR f和-OCH 2 CH 2 CN被酯交换。

5. 发明授权

US5952258A Process for the preparation of pyridine using zeolite catalysts 失效
标题翻译：使用沸石催化剂制备吡啶的方法
公开(公告)号：US5952258A
公开(公告)日：1999-09-14
申请号：US638729
申请日：1996-04-29
申请人： Morihito Saitoh , Yasutaka Tanaka
发明人： Morihito Saitoh , Yasutaka Tanaka
IPC分类号： B01J29/06 , B01J29/40 , B01J29/48 , B01J29/04 , C07D213/08
CPC分类号： B01J29/061 , B01J29/40 , B01J29/405 , B01J29/48
摘要： Disclosed is a process for the preparation of pyridine bases by a reaction of an aliphatic aldehyde and/or ketone with ammonia under gaseous phase using a specified catalyst in which a specified metal or combined metals are carried in or onto specified zeolites, for example, such as zeolites having a specified specific density range.
摘要翻译：公开了一种通过脂族醛和/或酮与氨在气相下使用特定的催化剂制备吡啶碱的方法，其中特定的金属或组合的金属在特定的沸石中载带，例如，作为具有特定比密度范围的沸石。

6. 发明申请

US20180337429A1 NON-AQUEOUS ELECTROLYTE STORAGE ELEMENT 审中-公开
公开(公告)号：US20180337429A1
公开(公告)日：2018-11-22
申请号：US15979767
申请日：2018-05-15
申请人： Yuka ARAKI , Naoto ABE , Yoshio ITOH , Tatsuya DAN , Shuhei TAKESHITA , Yasutaka TANAKA
发明人： Yuka ARAKI , Naoto ABE , Yoshio ITOH , Tatsuya DAN , Shuhei TAKESHITA , Yasutaka TANAKA
IPC分类号： H01M10/0567 , H01M10/0525 , H01M10/0568 , H01M4/587
CPC分类号： H01M10/0525 , H01M4/587 , H01M10/0568 , H01M10/0569 , H01M2300/0037
摘要： Provided is a non-aqueous electrolyte electricity-storage element, which includes: a positive electrode including a positive-electrode active material capable of inserting and eliminating anions; a negative electrode including a negative-electrode active material; a non-aqueous electrolyte;and a separator that is disposed between the positive electrode and the negative electrode and retains the non-aqueous electrolyte, wherein the non-aqueous electrolyte includes a dinitrile compound, and an amount of the dinitrile compound is 33% by mass or less relative to the non-aqueous electrolyte.

7. 发明授权

US5973151A Aromatic condensation compounds useful as optically active building blocks 失效
标题翻译：用作光学活性结构单元的芳族缩合化合物
公开(公告)号：US5973151A
公开(公告)日：1999-10-26
申请号：US32081
申请日：1998-02-27
申请人： Yasutaka Tanaka , Akemi Sekita , Hiroshi Suzuki , Akiyoshi Torii
发明人： Yasutaka Tanaka , Akemi Sekita , Hiroshi Suzuki , Akiyoshi Torii
IPC分类号： B01J27/138 , C07B57/00 , C07B61/00 , C07D471/04 , C07D471/02
CPC分类号： C07D471/04
摘要： Disclosed are aromatic condensation compounds useful as building blocks for construction of various types of optically active substances and reagent, wherein the aromatic condensation compounds are represented by general formula (1) below and capable of forming enantiomeric isomers. In the formula, two Rs are the same or different functional groups and selected from among linear, branched and cyclic hydrocarbon groups of 1-16 carbon atoms, either of which R may be hydrogen. A portion of the aromatic nucleus may be reduced, or at least one of the two nitrogen atoms may be quaternary. The aromatic condensation compounds can be produced by heating and reacting N,N'-diphenyl-p-phenylenediamine with a carboxylic acid represented by the general formula --RCOOH in an amount of at least 2 molar equivalents with respect to the diamine, at 180-210.degree. C. in the presence of a Lewis acid such as zinc chloride. ##STR1##
摘要翻译：公开了用作构建各种光学活性物质和试剂的结构单元的芳族缩合化合物，其中芳族缩合化合物由下述通式（1）表示并能够形成对映体异构体。在该式中，两个R 5是相同或不同的官能团，并且选自1-16个碳原子的直链，支链和环状烃基，其中R可以是氢。芳族核的一部分可以被还原，或者两个氮原子中的至少一个可以是四价的。芳香缩合化合物可以通过加热和反应N，N'-二苯基对苯二胺与通式-RCOOH表示的羧酸相对于二胺在至少2摩尔当量的量下，在路易斯酸如氯化锌存在下，在210℃下进行。

8. 发明授权

US5914428A Process for preparation of isocyanate compounds 失效
标题翻译：异氰酸酯化合物的制备方法
公开(公告)号：US5914428A
公开(公告)日：1999-06-22
申请号：US560517
申请日：1995-11-16
申请人： Toyokazu Yagii , Teruo Itokazu , Kenji Oka , Yasutaka Tanaka , Hidetaka Kojima , Kiyokazu Murata
发明人： Toyokazu Yagii , Teruo Itokazu , Kenji Oka , Yasutaka Tanaka , Hidetaka Kojima , Kiyokazu Murata
IPC分类号： C07C68/00 , C07C263/04 , C07C265/10 , C07C265/14 , C07C269/04 , C07C263/00 , C07C261/00
CPC分类号： C07C269/04 , C07C263/04 , C07C68/005 , C07C2101/12
摘要： An aliphatic diisocyanate compound is prepared in a high yield by reacting dimethyl carbonate with an aliphatic diamine in the presence of an alkali catalyst to produce a corresponding urethane compound; and, within 48 hours after the completion of the preparation of the urethane compound, thermally decomposing the urethane compound under a reduced pressure of 1 to 700 Torr in a high-boiling-point solvent.
摘要翻译：通过在碱催化剂的存在下使碳酸二甲酯与脂族二胺反应，以高收率制备脂族二异氰酸酯化合物，生成相应的氨基甲酸酯化合物; 在氨基甲酸酯化合物的制备完成后48小时内，在高沸点溶剂中，在1〜700乇的减压下热分解氨基甲酸酯化合物。

9. 发明授权

US5789614A Process for preparation of aliphatic diisocyanate compounds 失效
标题翻译：脂族二异氰酸酯化合物的制备方法
公开(公告)号：US5789614A
公开(公告)日：1998-08-04
申请号：US940364
申请日：1997-09-30
申请人： Toyokazu Yagii , Teruo Itokazu , Kenji Oka , Yasutaka Tanaka , Hidetaka Kojima
发明人： Toyokazu Yagii , Teruo Itokazu , Kenji Oka , Yasutaka Tanaka , Hidetaka Kojima
IPC分类号： C07C269/04 , C07C263/00
CPC分类号： C07C269/04
摘要： An aliphatic diisocyante compound is prepared in a high yield by reacting dimethyl carbonate with an aliphatic diamine in the presence of an alkali catalyst to produce a corresponding urethene compound; and, within 48 hours after the completion of the preparation of the urethane compound, thermally decomposing the urethane compound under a reduced pressure of 1 to 700 Torr in a high-boiling-point solvent.
摘要翻译：通过在碱催化剂的存在下使碳酸二甲酯与脂肪族二胺反应，以高产率制备脂族二异氰酸酯化合物，生成相应的脲基化合物; 在氨基甲酸酯化合物的制备完成后48小时内，在高沸点溶剂中，在1〜700乇的减压下热分解氨基甲酸酯化合物。

10. 发明授权

US5182246A Catalyst for hydrogenation, dehydrosilylation or hydrosilylation and use thereof 失效
标题翻译：催化剂用于氢化，脱氢硅烷基化或氢化反应及其用途
公开(公告)号：US5182246A
公开(公告)日：1993-01-26
申请号：US752646
申请日：1991-08-23
申请人： Takamasa Fuchikami , Yumiko Ubukata , Yasutaka Tanaka
发明人： Takamasa Fuchikami , Yumiko Ubukata , Yasutaka Tanaka
IPC分类号： B01J31/20 , C07C5/03 , C07C5/05 , C07C5/08 , C07C5/09 , C07C29/145 , C07C29/17 , C07C37/00 , C07C45/62 , C07C51/36 , C07C67/31 , C07C209/48 , C07C209/52 , C07C231/12 , C07F7/08 , C07F7/18
CPC分类号： B01J31/20 , C07C209/48 , C07C209/52 , C07C231/12 , C07C29/145 , C07C29/172 , C07C45/62 , C07C5/03 , C07C5/05 , C07C5/08 , C07C5/09 , C07C51/36 , C07C67/31 , C07F7/0801 , C07F7/0829 , C07F7/0896 , C07F7/1868 , C07F7/188 , B01J2231/323 , B01J2231/643 , B01J2231/645 , B01J2531/60 , C07C2531/20
摘要： A catalyst for hydrogenation, dehydrosilylation of ketones, or hydrosililation of dienes or acetylenes, comprising a complex represented the the formula:A.sup.+ [M.sub.2 H(C)).sub.10 ].sup.-wherein A.sup.+ represents an alkali metal cation, an ammonium cation, an iminium cation, or a phosphonium cation; and M represents a chromium atom, a molybdenum atom, or a tungsten atom; anda process for producing dehydrosilylation products of ketones or hydrosilylation products of dienes or acetylenes, which is characterized by using the complex as a catalyst.
摘要翻译： PCT No.PCT / JP90 / 01708 Sec。 371日期1991年8月23日 102（e）日期1991年8月23日PCT 1990年12月26日PCT PCT。公开号WO91 / 09674 日期：1991年7月11日。用于氢化，酮的脱氢硅烷化或二烯或乙炔的氢化硅烷化的催化剂，其包含由下式表示的配合物：A + [M2H（C））10] - 其中A +表示碱金属阳离子，铵阳离子，亚铵阳离子或鏻阳离子; M表示铬原子，钼原子或钨原子; 以及二烯或乙炔的酮或氢化硅烷化产物的脱氢硅烷化产物的方法，其特征在于使用该络合物作为催化剂。

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