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    • 1. 发明授权
    • Crosslinked water-soluble polymer dispersions
    • 交联的水溶性聚合物分散体
    • US5840804A
    • 1998-11-24
    • US816900
    • 1997-03-13
    • Joachim CarlPeter QuisManfred BraumWolfram Desch
    • Joachim CarlPeter QuisManfred BraumWolfram Desch
    • B01D21/01C02F1/56C08F2/10C08F2/18C08F2/20D21H17/45D21H21/10C08L33/08
    • D21H21/10B01D21/01C02F1/56C08F2/10D21H17/455
    • A method of producing low-viscosity water-based water-soluble polymer dispersions having a high concentration of the principal substance is achieved by polymerizing the following monomer components, (a1) 50-99.999 wt. % of at least one water-soluble monomer; (a2) 0.001-1 wt. % of at least one crosslinking monomer with at least two ethylenically unsaturated radically polymerizable groups; (a3) 0-30 wt. %, particularly 1-25 wt. %, of at least one hydrophobic monomer; and (a4) 0-25 wt. %, particularly 0.1-15 wt. %, of at least one amphiphilic monomer, in aqueous solution, in the presence of at least one polymer dispersant, to form a polymer (A), where the sum of the amounts of the components represented by the monomers (a1), (a2), (a3), and (a4) is 100 wt. % of the monomers, the weight average molecular weight of the resulting polymer (A) is at least 500,000 Dalton, and polymer (A) is incompatible with the dispersant.
    • 通过聚合下列单体组分,可以得到具有高浓度主要物质的低粘度水溶性聚合物分散体的方法:(a1)50-99.999重量% %的至少一种水溶性单体; (a2)0.001-1重量% 至少一种具有至少两个烯属不饱和自由基聚合基团的交联单体的% (a3)0-30重量% %,特别是1-25wt。 %,至少一种疏水性单体; 和(a4)0-25wt。 %,特别是0.1-15wt。 %的至少一种两亲性单体,在水溶液中,在至少一种聚合物分散剂的存在下,形成聚合物(A),其中由单体(a1),(a2 ),(a3)和(a4)为100重量%。 %的单体,所得聚合物(A)的重均分子量为至少500,000道尔顿,聚合物(A)与分散剂不相容。