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    • 1. 发明授权
    • Method for forming an electrochemical sensor
    • 电化学传感器的形成方法
    • US6068745A
    • 2000-05-30
    • US305101
    • 1999-05-04
    • Willi Zeidler
    • Willi Zeidler
    • G01N27/36C03B23/049C03C27/08
    • C03C27/08C03B23/0493
    • A method of producing a medium-tight connection between interior and exterior concentrically-arranged glass tubes includes the steps of providing a longitudinally extending electrical conductor strip between the interior and exterior tubes, forming a bulge extending radially outwardly from the interior tube by heating the tube, inserting the interior tube into the exterior tube, and forming a constriction in the exterior tube which extends radially inwardly and connects with the radially outwardly extending bulge to form a closure area, whereby the conductor strip passes through the closure area. An electrochemical sensor for measuring pH values or redox potentials formed according to this method includes an elongated housing which contains an interior chamber defined by the interior tube, a glass membrane cap, and a closure member, and an annular exterior chamber defined by the interior and exterior tubes. The interior chamber contains a buffer solution which covers at least a portion of a working electrode, the working electrode being further connected with an electrical line which passes through the closure member for connection with a connection point located outside of the interior chamber. The exterior chamber contains a reference solution which covers at least a portion of a reference electrode, the reference electrode being connected with an electrical line which extends from the exterior chamber through the medium-tight connection area formed in accordance with the invention to a connection point located outside of the exterior chamber.
    • 在内外同心配置的玻璃管之间制造中密连接的方法包括以下步骤:在内管和外管之间提供纵向延伸的电导体条,形成从内管径向向外延伸的凸起,通过加热管 将内管插入外管中,并且在外管中形成径向向内延伸并且与径向向外延伸的凸起连接以形成封闭区域,由此导体条通过封闭区域。 用于测量根据该方法形成的pH值或氧化还原电位的电化学传感器包括细长壳体,其包含由内管限定的内部室,玻璃膜盖和封闭构件,以及由内部限定的环形外部室 外管。 所述内部室包含覆盖工作电极的至少一部分的缓冲溶液,所述工作电极进一步与通过所述封闭构件的电线连接,以与位于所述内部室外部的连接点连接。 所述外部室包含覆盖参考电极的至少一部分的参考溶液,所述参考电极与从所述外部室通过根据本发明形成的中密封连接区域延伸到连接点的电线连接 位于外部室外。
    • 2. 发明授权
    • Electrochemical sensor
    • 电化学传感器
    • US6033543A
    • 2000-03-07
    • US991617
    • 1997-12-16
    • Willi Zeidler
    • Willi Zeidler
    • G01N27/36C03B23/049C03C27/08
    • C03C27/08C03B23/0493
    • A method of producing a medium-tight connection between interior and exterior concentrically-arranged glass tubes includes the steps of providing a longitudinally extending electrical conductor strip between the interior and exterior tubes, forming a bulge extending radially outwardly from the interior tube by heating the tube, inserting the interior tube into the exterior tube, and forming a constriction in the exterior tube which extends radially inwardly and connects with the radially outwardly extending bulge to form a closure area, whereby the conductor strip passes through the closure area. An electrochemical sensor for measuring pH values or redox potentials formed according to this method includes an elongated housing which contains an interior chamber defined by the interior tube, a glass membrane cap, and a closure member, and an annular exterior chamber defined by the interior and exterior tubes. The interior chamber contains a buffer solution which covers at least a portion of a working electrode, the working electrode being further connected with an electrical line which passes through the closure member for connection with a connection point located outside of the interior chamber. The exterior chamber contains a reference solution which covers at least a portion of a reference electrode, the reference electrode being connected with an electrical line which extends from the exterior chamber through the medium-tight connection area formed in accordance with the invention to a connection point located outside of the exterior chamber.
    • 在内外同心配置的玻璃管之间制造中密连接的方法包括以下步骤:在内管和外管之间提供纵向延伸的电导体条,形成从内管径向向外延伸的凸起,通过加热管 将内管插入外管中,并且在外管中形成径向向内延伸并且与径向向外延伸的凸起连接以形成封闭区域,由此导体条通过封闭区域。 用于测量根据该方法形成的pH值或氧化还原电位的电化学传感器包括细长壳体,其包含由内管限定的内部室,玻璃膜盖和封闭构件,以及由内部限定的环形外部室 外管。 所述内部室包含覆盖工作电极的至少一部分的缓冲溶液,所述工作电极进一步与通过所述封闭构件的电线连接,以与位于所述内部室外部的连接点连接。 所述外部室包含覆盖参考电极的至少一部分的参考溶液,所述参考电极与从所述外部室通过根据本发明形成的中密封连接区域延伸到连接点的电线连接 位于外部室外。