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    • 1. 发明申请
    • EXPANDABLE PARTICULATE POLYMER COMPOSITION
    • 可膨胀的聚合物组合物
    • US20090203808A1
    • 2009-08-13
    • US12350987
    • 2009-01-09
    • Paul E. ArchJennifer ChenWillem van LiemtRick Salvador
    • Paul E. ArchJennifer ChenWillem van LiemtRick Salvador
    • C08J9/16
    • C08J9/146C08J9/18C08J2351/06
    • An expandable particulate interpenetrating network polymer composition that includes as an expansion agent pentafluorobutane and optionally a minor amount of heptafluoropropane is described. The expandable particulate interpenetrating network polymer, more particularly, includes a particulate interpenetrating network polymer that includes: (i) a polyolefin polymer present in an amount of from 10 percent by weight to 80 percent by weight; and (ii) a vinyl aromatic polymer present in an amount of from 20 percent by weight to 90 percent by weight, in each case based on total weight of the particulate interpenetrating network polymer. The expansion agent resides (or is impregnated) within the particulate interpenetrating network polymer. The pentafluorobutane may be 1,1,1,3,3-pentafluorobutane, and the heptafluoropropane may be 1,1,1,2,3,3,3-heptafluoropropane. In an embodiment, the expansion agent consists of 1,1,1,3,3-pentafluorobutane, and is substantially free of any other expansion agents. The expandable particulate interpenetrating network polymer compositions of the present invention have improved expansion agent retention values, relative to comparative expandable particulate interpenetrating network polymer compositions (e.g., containing isopentane as an expansion agent).
    • 描述了包含五氟丁烷和任选的少量七氟丙烷作为膨胀剂的可膨胀颗粒互穿网络聚合物组合物。 可膨胀颗粒互穿网络聚合物,更具体地,包括颗粒互穿网络聚合物,其包括:(i)以10重量%至80重量%的量存在的聚烯烃聚合物; 和(ii)基于颗粒互穿网络聚合物的总重量,乙烯基芳族聚合物的存在量为20重量%至90重量%。 膨胀剂驻留(或浸渍)在颗粒互穿网络聚合物内。 五氟丁烷可以是1,1,1,3,3-五氟丁烷,七氟丙烷可以是1,1,1,2,3,3,3-七氟丙烷。 在一个实施方案中,膨胀剂由1,1,1,3,3-五氟丁烷组成,并且基本上不含任何其它膨胀剂。 相对于比较可膨胀颗粒互穿网络聚合物组合物(例如,含有异戊烷作为膨胀剂),本发明的可膨胀颗粒互穿网络聚合物组合物具有改进的膨胀剂保留值。
    • 4. 发明授权
    • Method and composition for enhancing the activity of an enzyme
    • 提高酶活性的方法和组合物
    • US06323014B1
    • 2001-11-27
    • US09596998
    • 2000-06-20
    • Greta Johanna BreelDaniel ConventsWillem Van LiemtTon SwarthoffRobin Stefan Twisker
    • Greta Johanna BreelDaniel ConventsWillem Van LiemtTon SwarthoffRobin Stefan Twisker
    • C12N996
    • C11D3/26C11D3/30C11D3/349C11D3/38609C11D3/3942
    • There is provided a process for enhancing the activity of a phenol oxidizing enzyme, comprising adding to the enzyme, as an enhancer for the activity of the enzyme, one or more compounds having the formula: wherein: A is an optionally substituted electron-withdrawing group, chosen from the group consisting of nitrile, carboxyl, and esters and salts thereof, amides, aldehydes, ketones, sulfoxides, sulfones, or sulphonates, and B is an optionally substituted electron-donating group, chosen from the group consisting of the oxide anion, sulfide anion, oxides, amines, imines, hydroxides, sulfides, ethers, carboxylic acids, and halogen substituents, and R1-R5 may each independently represent hydrogen, hydroxy, halogen, nitroso, formyl, carboxyl, and esters and salts thereof, carbamoyl, sulfo, and esters and salts hereof, sulfamoyl, nitro, amino, phenyl, C1-C20 alkyl, C1-C8 alkoxy, carbonyl-C1-C6-alkoxy, aryl-C1-C6-alkyl, and R2 and R5 together may form an alkylene group or an alkenylene group.
    • 提供了一种增强酚氧化酶的活性的方法,包括向酶中加入作为酶活性的增强剂,一种或多种具有下式的化合物:其中:A是任选取代的吸电子基团 选自腈,羧基及其酯和盐,酰胺,醛,酮,亚砜,砜或磺酸盐,B是任选取代的给电子基团,其选自氧化物阴离子, 硫化物阴离子,氧化物,胺,亚胺,氢氧化物,硫化物,醚,羧酸和卤素取代基,R 1 -R 5可各自独立地表示氢,羟基,卤素,亚硝基,甲酰基,羧基及其酯和盐,氨基甲酰基, ,和其酯和盐,氨磺酰,硝基,氨基,苯基,C 1 -C 20烷基,C 1 -C 8烷氧基,羰基-C 1 -C 6 - 烷氧基,芳基-C 1 -C 6烷基和R 2和R 5一起可以形成亚烷基 基团或亚烯基。