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1. 发明授权

US5290485A Third-order nonlinear optical element 失效
标题翻译：三阶非线性光学元件
公开(公告)号：US5290485A
公开(公告)日：1994-03-01
申请号：US863483
申请日：1992-04-02
申请人： Tetsuya Gotoh , Tosiyuki Kondoh , Keiichi Egawa , Ken-ichi Kubodera
发明人： Tetsuya Gotoh , Tosiyuki Kondoh , Keiichi Egawa , Ken-ichi Kubodera
IPC分类号： G02F1/35 , C09K9/00 , C30B7/00 , G02F1/355 , G02F1/361 , F21V9/04 , F21V9/00 , G02B6/00
CPC分类号： G02F1/361 , C30B29/54 , C30B7/00
摘要： A third-order nonlinear optical element showing wide employable wave-length range of input light, high speed operation and low light intensity of input light is disclosed. The third-order nonlinear optical element of the present invention has at least two substantially optically smooth surfaces and comprise a charge-transfer complex consisting essentially of (i) at least one electron-accepting component selected from the group consisting of cyano compounds, quinones, nitro compounds, acid anhydride, halogenes, and halogenated carbons; and (ii) at least one electron-donating component selected from the group consisting of unsaturated cyclic hydrocarbon compounds, unsaturated heterocyclic compounds, chalcogen-containing compounds, quarternary unsaturated heterocyclic compounds and metals The charge-transfer complex of nonlinear optical element of the present invention is formed of said at least one electron-accepting component and said at least one electron-donating component in the ground state and at least one of said components is an organic compound having .pi.-conjugated system.
摘要翻译：公开了一种三阶非线性光学元件，其显示出输入光的宽可用波长范围，高速操作和低光强度的输入光。本发明的三阶非线性光学元件具有至少两个基本上光学平滑的表面，并且包含电荷转移络合物，其基本上由（i）至少一种选自氰基化合物，醌类，硝基化合物，酸酐，卤素和卤代碳; 和（ii）至少一种选自不饱和环烃化合物，不饱和杂环化合物，含硫属化合物，三元不饱和杂环化合物和金属的给电子成分本发明的非线性光学元件的电荷转移络合物由所述至少一种受电子成分和所述至少一种处于基态的给电子组分形成，所述组分中的至少一种是具有（π）共轭体系的有机化合物。

2. 发明授权

US4816386A Near-infrared sensitive phthalocyanine-polymer compositions 失效
标题翻译：近红外敏感性酞菁 - 聚合物组合物
公开(公告)号：US4816386A
公开(公告)日：1989-03-28
申请号：US303
申请日：1987-01-05
申请人： Tetsuya Gotoh , Tosiyuki Kondoh , Mutsuo Aoyagi
发明人： Tetsuya Gotoh , Tosiyuki Kondoh , Mutsuo Aoyagi
IPC分类号： G02F1/01 , G11B7/248 , G11B7/24 , G01D9/00 , G03C1/72
CPC分类号： G02F1/0147 , G11B7/248 , Y10S430/145 , Y10S430/146 , Y10S430/165
摘要： A novel near-infrared sensitive phthalocyanine-polymer composition comprises a substituted aluminum phthalocyanine and a polymer wherein substituted aluminum phthalocyanine dimers and/or dimer aggregates which are responsible to the near-infrared sensitivity, are included.The near-infrared sensitive phthalocyanine-polymer composition has useful characteristics:(A) when the near-infrared sensitive phthalocynaine-polymer composition is heated above the T.sub.g (Glass Transition Temperature) of the polymer either by direct heating and by absorbing irradiated light energy, optical properties of said near-infrared sensitive phthalocyanine-polymer composition; absorbance and/or reflectivity, are capable of being changed,(B) the thermal change of optical properties of the near-infrared sensitive phthalocyanine-polymer composition can be fixed by further heating above the T.sub.f (Thermal Fixation Temperature) higher than the T.sub.g of the polymer,(C) said near-infrared sensitive phthalocyanine-polymer composition is capable of being insolubilized to a solvent by heating above the T.sub.f,(D) said near-infrared sensitive phthalocyanine-polymer compositions both of unheated and heated above the T.sub.f are very stable and of long life.
摘要翻译：一种新型近红外敏感性酞菁 - 聚合物组合物包括取代的铝酞菁和其中负责近红外灵敏度的取代的铝酞菁二聚体和/或二聚体聚集体的聚合物。近红外线敏感性酞菁聚合物组合物具有以下特征：（A）当通过直接加热和吸收照射的光能将近红外线敏感的酞儿素 - 聚合物组合物加热到高于聚合物的Tg（玻璃化转变温度）时，所述近红外敏感性酞菁 - 聚合物组合物的光学性质; 吸光度和/或反射率能够改变，（B）近红外敏感性酞菁 - 聚合物组合物的光学性质的热变化可以通过进一步加热而高于Tf（热固定温度）高于Tg 所述聚合物（C）所述近红外敏感性酞菁 - 聚合物组合物能够通过在Tf上方加热而不溶于溶剂，（D）在Tf以上未加热和加热的所述近红外敏感性酞菁 - 聚合物组合物非常稳定，寿命长。

3. 发明授权

US5368782A Method of operating third-order nonlinear optical element 失效
标题翻译：操作三阶非线性光学元件的方法
公开(公告)号：US5368782A
公开(公告)日：1994-11-29
申请号：US860124
申请日：1992-03-31
申请人： Tetsuya Gotoh , Tosiyuki Kondoh , Keiichi Egawa , Ken-ichi Kubodera
发明人： Tetsuya Gotoh , Tosiyuki Kondoh , Keiichi Egawa , Ken-ichi Kubodera
IPC分类号： C30B7/00 , G02F1/361 , F21V9/04 , F21V9/06 , F21V9/00
CPC分类号： G02F1/361 , C30B29/54 , C30B7/00
摘要： A third-order nonlinear optical element showing wide employable wave-length range of input light, high speed operation and low light intensity of input light is disclosed. The third-order nonlinear optical element of the present invention has at least two substantially optically smooth surfaces and comprise a charge-transfer complex consisting essentially of (i) at least one electron-accepting component selected from the group consisting of cyano compounds, quinones, nitro compounds, acid anhydride, halogenes, and halogenated carbons; and (ii) at least one electron-donating component selected from the group consisting of unsaturated cyclic hydrocarbon compounds, unsaturated heterocyclic compounds, chalcogen-containing compounds, quarternary unsaturated heterocyclic compounds and metals. The charge-transfer complex of nonlinear optical element of the present invention is formed of said at least one electron-accepting component and said at least one electron-donating component in the ground state and at least one of said components is an organic compound having .pi.-conjugated system.
摘要翻译：公开了一种三阶非线性光学元件，其显示出输入光的宽可用波长范围，高速操作和低光强度的输入光。本发明的三阶非线性光学元件具有至少两个基本上光学平滑的表面，并且包含电荷转移络合物，其基本上由（i）至少一种选自氰基化合物，醌类，硝基化合物，酸酐，卤素和卤代碳; 和（ii）至少一种选自不饱和环烃化合物，不饱和杂环化合物，含硫属化合物，季铵不饱和杂环化合物和金属的给电子成分。本发明的非线性光学元件的电荷转移络合物由所述至少一种电子接受组分和所述至少一种基态给电子组分形成，所述组分中的至少一种是具有π 共轭系统

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