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1. 发明授权

US08080671B2 Production of low color polyetherimides 有权
标题翻译：生产低色聚醚酰亚胺
公开(公告)号：US08080671B2
公开(公告)日：2011-12-20
申请号：US12196479
申请日：2008-08-22
申请人： Thomas L. Guggenheim , Roy Ray Odle , Karthik Venkataraman
发明人： Thomas L. Guggenheim , Roy Ray Odle , Karthik Venkataraman
IPC分类号： C07D209/48
CPC分类号： C07D209/48 , C08G73/1046 , C08G73/1071
摘要： The production of low color polyetherimides, including its intermediates, such as bisimides and diaryl diether dianhydrides, may be affected by producing an improved purity intermediate of 4-nitro-N-alkylphthalimide. A salt, such as alkali metal carbonate or alkali metal hydrogen carbonate, is added to an aqueous mixture of 4-nitro-N-alkylphthalimide and 3-nitro-N-alkylphthalimide to selectively hydrolyze the imide linkage of 3-nitro-N-alkylphthalimide forming a water-soluble acid-amide salt. An organic solvent is added to this salt mixture to phase separate 4-nitro-N-alkylphthalimide having dissolved in the organic solvent from acid-amide salt of 3-nitro-N-alkylphthalimide having dissolved in water.
摘要翻译：通过生产4-硝基-N-烷基邻苯二甲酰亚胺的改进的纯度中间体，可以影响低色度聚醚酰亚胺（包括其中间体，如双酰亚胺和二芳基二醚二酸酐）的生产。将诸如碱金属碳酸盐或碱金属碳酸氢盐的盐加入4-硝基-N-烷基邻苯二甲酰亚胺和3-硝基-N-烷基邻苯二甲酰亚胺的水性混合物中以选择性水解3-硝基-N-烷基邻苯二甲酰亚胺的酰亚胺键形成水溶性酸 - 酰胺盐。向该盐混合物中加入有机溶剂，将溶解在有机溶剂中的4-硝基-N-烷基邻苯二甲酰亚胺溶解在溶解于水中的3-硝基-N-烷基邻苯二甲酰亚胺的酰胺盐相。

2. 发明授权

US5936099A Process for preparing BIS(ether anhydrides) using alkylamine derived bisimides having low melting temperature 失效
标题翻译：使用具有低熔融温度的烷基胺衍生双酰亚胺制备BIS（醚酐）的方法
公开(公告)号：US5936099A
公开(公告)日：1999-08-10
申请号：US964032
申请日：1997-11-04
申请人： Brent Dellacoletta , Roy Ray Odle , Thomas L. Guggenheim , Ronald A. Greenberg , James P. Barren , Joseph A. King , Sunita Singh Baghel , Deborah A. Haitko , David G. Hawron
发明人： Brent Dellacoletta , Roy Ray Odle , Thomas L. Guggenheim , Ronald A. Greenberg , James P. Barren , Joseph A. King , Sunita Singh Baghel , Deborah A. Haitko , David G. Hawron
IPC分类号： C07D209/48 , C07D307/89 , C07D209/12
CPC分类号： C07D209/48 , C07D307/89
摘要： A process for making bis(ether anhydrides) employs alkylamines having low melting temperatures thus allowing for novel intermediate process steps for preparing bis(ether anhydrides). The alkylamines have alkyl groups which contain at least three carbon atoms and have boiling temperatures in the range of 48 to 250.degree. C. at atmospheric pressure. As a result of using these amines, liquid alkylamines now can be employed in the imidization process step. The N-alkyl nitrophthalimides prepared from the recovered imidization product according to this invention can now be purified using liquid/liquid extraction or vacuum distillation. The alkyl nitrophthalimides prepared according to this invention provide for displacement reactions which now can be run at a high solids level. Likewise, the exchange reaction can be run at a higher solids level, and thus achieves an efficiency level which is higher than conventional processes.
摘要翻译：制备双（醚酐）的方法使用具有低熔融温度的烷基胺，从而允许制备双（醚酐）的新的中间方法步骤。烷基胺具有含有至少三个碳原子的烷基，并且在大气压下具有在48至250℃范围内的沸点温度。作为使用这些胺的结果，液体烷基胺现在可用于酰亚胺化工艺步骤。从本发明回收的酰亚胺化产物制备的N-烷基硝基邻苯二酰亚胺现在可以使用液/液萃取或真空蒸馏来纯化。根据本发明制备的烷基硝基邻苯二酰亚胺提供了现在可以以高固体含量运行的置换反应。同样，交换反应可以在更高的固体含量下进行，从而达到高于常规方法的效率水平。

3. 再颁专利

USRE34431E Macrocyclic oligomers containing spiro(bis)indane moieties 失效
标题翻译：含有螺（双）二氢化茚部分的大环低聚物
公开(公告)号：USRE34431E
公开(公告)日：1993-11-02
申请号：US915381
申请日：1992-05-08
申请人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
发明人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
IPC分类号： C08G63/193 , C08G64/06 , C08G64/18 , C08G65/40 , C08G65/48 , C08G69/26 , C08G73/10 , C08G75/23 , C08G63/00 , C07D231/00 , C07F7/04 , C08G69/42
CPC分类号： C08G63/193 , C08G64/06 , C08G64/183 , C08G65/4081 , C08G65/48 , C08G69/26 , C08G73/10 , C08G75/23
摘要： Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.

4. 发明授权

US4945147A Aromatic polyester-siloxane block copolymers and method for making 失效
标题翻译：芳香族聚酯 - 硅氧烷嵌段共聚物及其制备方法
公开(公告)号：US4945147A
公开(公告)日：1990-07-31
申请号：US319027
申请日：1989-03-06
申请人： Peter P. Policastro , Pamela K. Hernandez , Sandra A. Swint , Gary C. Davis , Jonathan D. Rich , Philip J. McDermott , Thomas L. Guggenheim
发明人： Peter P. Policastro , Pamela K. Hernandez , Sandra A. Swint , Gary C. Davis , Jonathan D. Rich , Philip J. McDermott , Thomas L. Guggenheim
IPC分类号： C08G63/695 , C08G63/19 , C08G63/68 , C08G77/42 , C08G77/445 , C08L69/00
CPC分类号： C08G77/445 , C08G63/6956
摘要： There is provided by the present invention aromatic polyester-siloxane block copolymers which can be made by effecting the condensation between tetramethyldisiloxane bisbenzoic acid or acid chloride with a dihydric phenol such as bisphenol A or in combination with a mixture of such tetramethyldisiloxane bisbenzoic acid and aromatic acids, such as terephthalic acid or isophthalic acid. The aromatic polyester-siloxane block copolymers can be used as molding compounds, extruded films, in making composite matrix materials and as flame retardants for aromatic polycarbonates.

5. 发明授权

US6008374A Process for preparing bis (ether anhydrides) using alkylamine derived bisimides having low melting temperatures 有权
标题翻译：使用具有低熔点的烷基胺衍生双酰亚胺制备双（醚酐）的方法
公开(公告)号：US6008374A
公开(公告)日：1999-12-28
申请号：US268608
申请日：1999-03-15
申请人： Brent Dellacoletta , Roy Ray Odle , Thomas L. Guggenheim , Ronald A. Greenberg , James P. Barren , Joseph A. King , Sunita Singh Baghel , Deborah A. Haitko , David G. Hawron
发明人： Brent Dellacoletta , Roy Ray Odle , Thomas L. Guggenheim , Ronald A. Greenberg , James P. Barren , Joseph A. King , Sunita Singh Baghel , Deborah A. Haitko , David G. Hawron
IPC分类号： C07D209/48 , C07D307/89 , C07D403/12
CPC分类号： C07D209/48 , C07D307/89
摘要： A process for making bis(ether anhydrides) employs alkylamines having low melting temperatures thus allowing for novel intermediate process steps for preparing bis(ether anhydrides). The alkylamines have alkyl groups which contain at least three carbon atoms and have boiling temperatures in the range of 48 to 250.degree. C. at atmospheric pressure. As a result of using these amines, liquid alkylamines now can be employed in the imidization process step. The N-alkyl nitrophthalimides prepared from the recovered imidization product according to this invention can now be purified using liquid/liquid extraction or vacuum distillation. The alkyl nitrophthalimides prepared according to this invention provide for displacement reactions which now can be run at a high solids level. Likewise, the exchange reaction can be run at a higher solids level, and thus achieves an efficiency level which is higher than conventional processes.
摘要翻译：制备双（醚酐）的方法使用具有低熔融温度的烷基胺，从而允许制备双（醚酐）的新的中间方法步骤。烷基胺具有含有至少三个碳原子的烷基，并且在大气压下具有在48至250℃范围内的沸点温度。作为使用这些胺的结果，液体烷基胺现在可用于酰亚胺化工艺步骤。从本发明回收的酰亚胺化产物制备的N-烷基硝基邻苯二酰亚胺现在可以使用液/液萃取或真空蒸馏来纯化。根据本发明制备的烷基硝基邻苯二酰亚胺提供了现在可以以高固体含量运行的置换反应。同样，交换反应可以在更高的固体含量下进行，从而达到高于常规方法的效率水平。

6. 发明授权

US5589037A Method for removing tetranitromethane from nitric acid 失效
标题翻译：从硝酸中去除四硝基甲烷的方法
公开(公告)号：US5589037A
公开(公告)日：1996-12-31
申请号：US547516
申请日：1995-10-24
申请人： Thomas L. Guggenheim , Sharon M. Fukuyama , Gregory L. Warner
发明人： Thomas L. Guggenheim , Sharon M. Fukuyama , Gregory L. Warner
IPC分类号： C01B21/46 , C07C201/16 , B01D3/34
CPC分类号： C01B21/46 , C07C201/16 , Y10S159/19
摘要： Tetranitromethane and other polynitrated methanes can be effectively removed from otherwise substantially organic-free nitric acid streams through the addition of substantially organic-free concentrated sulfuric acid and by, optionally, performing secondary operations such as sparging the mixed acid stream with a gas such as nitric oxide or with an oil.
摘要翻译：通过添加基本上无机物的浓硫酸，并且任选地进行二次操作，例如用诸如硝酸的气体喷射混合酸流，可以有效地从另外基本上不含有机物的硝酸气流中除去四硝基甲烷和其它多晶甲烷氧化物或油。

7. 发明授权

US5006637A Method for preparing copolyestercarbonates from cyclic oligomers 失效
标题翻译：从环状低聚物制备共聚酯碳酸酯的方法
公开(公告)号：US5006637A
公开(公告)日：1991-04-09
申请号：US364387
申请日：1989-06-12
申请人： Thomas L. Guggenheim , James M. Fukuyama , John J. Kelly
发明人： Thomas L. Guggenheim , James M. Fukuyama , John J. Kelly
IPC分类号： C08G63/78 , C08G63/64
CPC分类号： C08G63/64
摘要： Copolyestercarbonates are prepared by the reaction of at least one cyclic polycarbonate oligomer with at least one cyclic polyester oligomer in the presence of a cyclic polycarbonate polymerization catalyst at temperatures in the range of about 280.degree.-375.degree. C. Mixtures of bisphenol A polycarbonate and bisphenol A isophthalate or terephthalate oligomers are preferably employed, and the preferred catalysts are tetraarylborate salts such as tetra-n-butylammonium tetraphenylborate.

8. 发明授权

US4950727A Spiro(bis)indane polyamide and polyimide copolysiloxanes and method of preparation 失效
标题翻译：螺（双）茚满聚酰胺和聚酰亚胺共聚硅氧烷及其制备方法
公开(公告)号：US4950727A
公开(公告)日：1990-08-21
申请号：US182020
申请日：1988-04-15
申请人： Thomas L. Guggenheim , James A. Cella , Sharon J. McCormick , Alice M. Colley , Jonathan D. Rich , Philip J. McDermott
发明人： Thomas L. Guggenheim , James A. Cella , Sharon J. McCormick , Alice M. Colley , Jonathan D. Rich , Philip J. McDermott
IPC分类号： C07C65/26 , C08G65/40
CPC分类号： C08G65/4081 , C07C65/26
摘要： Linear polyamide and polyimide copolysiloxane compositions are prepared by contacting a strongly acidic catalyst, basic catalyst or alkali metal fluoride with a macrocyclic spirobiindane polyamide or polyimide disiloxane, either alone or in combination with a cyclic polysiloxane such as octamethylcyclotetrasiloxane.
摘要翻译：线性聚酰胺和聚酰亚胺共聚硅氧烷组合物通过单独或与环状聚硅氧烷如八甲基环四硅氧烷组合使强酸性催化剂，碱性催化剂或碱金属氟化物与大环螺茚二酰胺聚酰胺或聚酰亚胺二硅氧烷接触来制备。

9. 发明授权

US4945148A Silicone-polycarbonate block copolymers 失效
标题翻译：硅酮 - 聚碳酸酯嵌段共聚物
公开(公告)号：US4945148A
公开(公告)日：1990-07-31
申请号：US319025
申请日：1989-03-06
申请人： Jonathan D. Rich , Philip J. McDermott , Gary C. Davis , Peter P. Policastro , Karen A. Regh , Pamela K. Hernandez , Thomas L. Guggenheim
发明人： Jonathan D. Rich , Philip J. McDermott , Gary C. Davis , Peter P. Policastro , Karen A. Regh , Pamela K. Hernandez , Thomas L. Guggenheim
IPC分类号： C07F7/10 , C07F7/08 , C08G64/00 , C08G64/18 , C08G77/42 , C08G77/448
CPC分类号： C08G64/186 , C08G77/448
摘要： Silicone-polycarbonate block copolymers are provided resulting from the reaction of certain siloxy aromatic imide siloxanes or hydroxyaromatic ester siloxanes which are made by effecting reaction between an organosiloxane having terminal aromatic anhydride groups or aromatic haloacyl groups which are each attached to silicon by silicon arylene linkages with an appropriate bishydroxyarylene compounds or hydroxyarylene amino compound. The aforementioned hydroxyaromatic imide siloxanes or hydroxyaromatic ester siloxanes are then phosgenated with a dihydric phenol or an aromatic bischloroformate. The silicone-polycarbonate block copolymers have been found to be flame retardant and useful as dielectric films and membranes, and as flame retardants in aromatic polycarbonates.

10. 发明授权

US4927904A Method for preparing cyclic polyarylate oligomers 失效
标题翻译：制备环状多芳基化合物低聚物的方法
公开(公告)号：US4927904A
公开(公告)日：1990-05-22
申请号：US364294
申请日：1989-06-12
申请人： Thomas L. Guggenheim , Sharon J. McCormick , Alice M. Colley
发明人： Thomas L. Guggenheim , Sharon J. McCormick , Alice M. Colley
IPC分类号： C08G63/181 , C07D321/00 , C07D323/00 , C08G63/19 , C08G63/195 , C08G63/79 , C08G63/87
CPC分类号： C08G63/195 , C08G63/87
摘要： Cyclic polyarylate oligomer compositions are prepared by the reaction of an aromatic dicarboxylic acid halide, such as isophthaloyl chloride or terephthaloyl chloride, with a water-soluble salt of a dihydroxyaromatic compound, such as bisphenol A disodium salt. Freshly prepared solutions of the halide in an organic liquid such as methylene chloride, and of the salt in water, are simultaneously introduced into an organic liquid containing a catalytic amount of at least one quaternary ammonium salt having a single alkyl group containing about 8-20 carbon atoms and having not more than 5 additional carbon atoms. The dihydroxyaromatic compound salt is employed in the amount of at least about 3% in excess of stoichiometric.

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