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    • 1. 发明授权
    • Modified carbon black, process for producing the modified carbon black, rubber composition and pneumatic tire
    • 改性炭黑,生产改性炭黑的方法,橡胶组合物和充气轮胎
    • US06444727B1
    • 2002-09-03
    • US09670716
    • 2000-09-28
    • Hiroshi YamadaTatsuhiko Ihara
    • Hiroshi YamadaTatsuhiko Ihara
    • C08K906
    • B60C1/0016C08K9/06Y10T428/2995C08L21/00
    • A rubber composition which comprises a rubber component comprising at least one rubber selected from natural rubber and synthetic diene rubbers and, per 100 parts by weight of the rubber component, 30 to 200 parts by weight of a modified carbon black having at a surface thereof an Si—O—C structure or an Si—C structure in which the carbon atom bonded directly to the Si atom is an aromatic carbon atom, and a pneumatic tire prepared by using the rubber composition. The modified carbon black can be obtained by bringing carbon black into contact with a silicon compound, such as a compound represented by a general formula: (R1O)mSiR24−m in a gas phase (in the formula, R1 represents an alkyl group having 1 to 3 carbon atoms, R2 represents an alkyl group having 1 to 3 carbon atoms or phenyl group and m represents an integer of 2 to 4). The rubber composition exhibits hysteresis loss increased selectively at a high temperature region. The modified carbon black can be advantageously used in the rubber composition. The pneumatic tire in which the rubber composition is used for a tread rubber is advantageously used as a high performance tire exhibiting a remarkably improved gripping property.
    • 一种橡胶组合物,其包含橡胶组分,所述橡胶组分包含至少一种选自天然橡胶和合成二烯橡胶的橡胶,并且相对于每100重量份的橡胶组分,具有30至200重量份的改性炭黑,其表面具有 Si-OC结构或其中直接与Si原子键合的碳原子是芳香族碳原子的Si-C结构,以及使用该橡胶组合物制备的充气轮胎。 改性炭黑可以通过使碳黑与硅化合物接触而获得,所述硅化合物例如由通式(R1O)mSiR24-m表示的化合物在气相中(式中,R1表示具有1个 3个碳原子,R 2表示碳原子数1〜3的烷基或苯基,m表示2〜4的整数)。橡胶组合物在高温区域选择性地显示滞后损失。 改性炭黑可有利地用于橡胶组合物中。 橡胶组合物用于胎面橡胶的充气轮胎有利地用作表现出显着提高的夹持性能的高性能轮胎。