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    • 2. 发明授权
    • Method of carbon nanotube separation, dispersion liquid and carbon nanotube obtained by the separation method
    • 通过分离方法得到的碳纳米管分离方法,分散液和碳纳米管
    • US07884300B2
    • 2011-02-08
    • US11659157
    • 2005-07-29
    • Takeshi AkasakaTakatsugu WakaharaYutaka Maeda
    • Takeshi AkasakaTakatsugu WakaharaYutaka Maeda
    • D01F9/12
    • B82Y30/00Y10S977/751Y10S977/842Y10S977/882Y10S977/895
    • A method of realizing selective separation of metallic single-walled carbon nanotubes and semiconducting carbon nanotubes from bundled carbon nanotubes; and obtaining of metallic single-walled carbon nanotubes separated at high purity through the above method. Metallic single-walled carbon nanotubes are dispersed one by one from bundled carbon nanotubes not only by the use of a difference in interaction with amine between metallic single-walled carbon nanotubes and semiconducting carbon nanotubes due to a difference in electrical properties between metallic single-walled carbon nanotubes and semiconducting carbon nanotubes but also by the use of the fact that an amine is an important factor in SWNTs separation. The thus dispersed carbon nanotubes are subjected to centrifugation, thereby attaining separation from non-dispersed semiconducting carbon nanotubes.
    • 实现金属单壁碳纳米管和半导体碳纳米管从束状碳纳米管的选择性分离的方法; 并通过上述方法获得以高纯度分离的金属单壁碳纳米管。 金属单壁碳纳米管不仅通过在金属单壁碳纳米管和半导体碳纳米管之间与胺的相互作用的差异,从捆扎的碳纳米管逐一分散,这是由于金属单壁碳纳米管之间的电性能差异 碳纳米管和半导体碳纳米管,而且还通过使用胺是SWNT分离中的重要因素的事实。 将这样分散的碳纳米管进行离心,从而获得与非分散的半导体碳纳米管的分离。