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    • 2. 发明授权
    • Aqueous urethane dispersants
    • 水性聚氨酯分散剂
    • US08664331B2
    • 2014-03-04
    • US10496389
    • 2002-11-01
    • Stuart Nicholas Richards
    • Stuart Nicholas Richards
    • B41J2/00B41J2/01B41J2/175C08G18/00C08G18/08C08G18/28C08J3/00C08J3/20C08L75/00
    • C08G18/4833B01F17/005C08G18/0823
    • A polyurethane polymer comprising from 35% to 90% (w/w) of a poly (C2-4-alkylene oxide) based on the total weight of the polymer wherein not less than 60% by weight of the poly (C2-4-alkylene oxide) is polyethylene oxide and wherein at least 5% of the poly (C2-4-alkylene oxide) based on the total weight of the polymer is incorporated in lateral chains and which contains 10 to 180 milliequivalents of add groups for each 100 gm polymer when the polyurethane contains from 35 to 45% by weight poly (C2-4-alkylene oxide), e.g. a polymer made by reacting dimethylolpropionic acid, cyclohexane dimethanol, polypropylene glycol (1000), N-methyl pyrrolidone and an α,α-diydroxy polyethylene glycol obtainable from 2,4-toluene diisocyanate, methoxy polyethylene glycol (750) and diethanolamine.
    • 聚氨酯聚合物,其包含基于聚合物总重量的35%至90%(w / w)的聚(C 2-4 - 烯化氧),其中不少于60重量%的聚(C 2-4 - 环氧烷)是聚环氧乙烷,并且其中基于聚合物总重量的至少5%的聚(C 2-4 - 烯化氧)被并入侧链中,并且对于每100克包含10至180毫当量的加成基团 当聚氨酯含有35至45重量%的聚(C 2-4 - 氧化烯)时, 由二羟甲基丙酸,环己烷二甲醇,聚丙二醇(1000),N-甲基吡咯烷酮和由2,4-甲苯二异氰酸酯得到的α,α-二羟基聚乙二醇,甲氧基聚乙二醇(750)和二乙醇胺制成的聚合物。
    • 4. 发明授权
    • Free radical polymerisation process
    • 自由基聚合过程
    • US5962609A
    • 1999-10-05
    • US836378
    • 1997-07-15
    • David Mark HaddletonAndrew Victor Graham MuirStephen William LeemingJohn Patrick O'DonnellStuart Nicholas Richards
    • David Mark HaddletonAndrew Victor Graham MuirStephen William LeemingJohn Patrick O'DonnellStuart Nicholas Richards
    • C07F15/06C07F5/02C08F2/38C08F20/00C08F283/00C09D7/12C09D201/00C09J201/00
    • C08F2/38C07F5/022
    • Process for the free-radical polymerisation of olefinically unsaturated monomer(s) using a free-radical initiator, the polymerisation being performed in the presence of a compound for effecting molecular weight control, wherein the molecular weight control compound is a Co Il chelate of the following formula I ##STR1## wherein each group X, independently in each ring and in different rings, is a substituent selected from alkyl of 1 to 14 carbon atoms and cycloalkyl of 6 to 14 carbon atoms; n, independently in each ring, is 0 to 5 provided that in at least one ring, n is 1 to 5; Z, independently on each boron atom, is selected from F, Cl, Br, OH, alkoxy of 1 to 12 carbon atoms, aryloxy of 6 to 12 carbon atoms, alkyl of 1 to 12 carbon atoms, and aryl of 6 to 12 carbon atoms; or two Z groups taken together provide on one or both boron atoms a group --O--(Q)--O-- where Q is a divalent aryl or alicyclic linking group or an alkylene linking group, or two Z groups taken together on one or both boron atoms provide a 1,5-cyclooctanediyl linking group; or being a Co III analogue of said Co II chelate of formula I in which the Co atom is additionally covalently bonded, in a direction at right angles to the macrocyclic chelate ring system, to H, halide or other anion, or a homolytically dissociable organic group; and wherein optionally at least one further ligand is coordinated to the CoII or CoIII atom, being a ligand which does not alter the Co valency state. Also the Co chelates used in the polymerisation process, a process for their production, and the use in various applications of oligomers made using the polymerisation process.
    • PCT No.PCT / GB95 / 02376 Sec。 371日期1997年7月15日 102(e)日期1997年7月15日PCT提交1995年10月9日PCT公布。 出版物WO96 / 日期1996年5月9日使用自由基引发剂对烯属不饱和单体进行自由基聚合的方法,该聚合在化合物存在下进行以进行分子量控制,其中分子量控制化合物是Co II螯合物,其中每个基团X独立地为每个环和不同的环,是选自1至14个碳原子的烷基和6至14个碳原子的环烷基的取代基; n在每个环中独立地为0至5,条件是在至少一个环中,n为1至5; Z独立地为每个硼原子,选自F,Cl,Br,OH,1至12个碳原子的烷氧基,6至12个碳原子的芳氧基,1至12个碳原子的烷基和6至12个碳的芳基 原子 或两个Z基团在一个或两个硼原子上提供基团-O-(Q)-O-,其中Q是二价芳基或脂环族连接基团或亚烷基连接基团,或两个Z基团一起或一个在一个或两个上 硼原子提供1,5-环辛二基连接基团; 或者是所述式I的Co II螯合物的Co III类似物,其中Co原子在与大环螯合环体系成直角的方向上另外共价键合到H,卤化物或其它阴离子或均分离的有机物 组; 并且其中任选地至少一个另外的配体与CoII或CoIII原子配位,作为不改变Co价态的配体。 还有在聚合过程中使用的Co螯合物,它们的生产方法以及在使用聚合方法制备的低聚物的各种应用中的用途。