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    • 1. 发明授权
    • Method of in-situ leaching of ores
    • 矿石原位浸出方法
    • US4634187A
    • 1987-01-06
    • US674026
    • 1984-11-21
    • Ray V. HuffSteven G. AxenBaughman, David R.
    • Ray V. HuffSteven G. AxenBaughman, David R.
    • E21B43/28E21B43/30
    • E21B43/283E21B43/30
    • A method of in-situ leaching is disclosed in which the ore body is incapsulated by impermeable barriers. A grid of injection and production wells are drilled into the ore body. Horizontal barriers are formed at the top and bottom of the ore body by creating an overlapping pattern of horizontally-oriented fractures filled with polymer, above and below the ore body, radiating from each of the injection and production wells. A ring of boundary wells may also be drilled surrounding the ore body. The strata around each boundary well is fractured and a polymer is then injected to form a vertical barrier around the periphery of the ore body. The lixiviant is then introduced to extract the desired mineral values. In addition, water may be injected under pressure into guard wells between the ore body and the vertical and/or horizontal barrier wells to further reduce any migration of lixiviant into neighboring formations.
    • 公开了一种原位浸出的方法,其中矿体由不可渗透的障碍物堵塞。 一个注入井和生产井的网格被钻进矿体。 在矿体的顶部和底部形成水平的障碍物,通过在矿体的上方和下方形成由聚合物填充的横向取向的裂缝的重叠图案,从每个注入井和生产井射出。 也可以在矿体周围钻一圈边界井。 每个边界井附近的地层断裂,然后注入聚合物以在矿体周围形成垂直屏障。 然后引入浸出剂以提取所需的矿物质值。 此外,水可以在压力下注入到矿体和垂直和/或水平势垒井之间的保护井中,以进一步减少浸入到相邻地层中的任何迁移。
    • 2. 发明授权
    • Method of isolating contaminated geological formations, soils and
aquifers
    • 分离污染地质构造,土壤和含水层的方法
    • US5030036A
    • 1991-07-09
    • US200
    • 1987-01-05
    • Ray V. HuffSteven G. AxenDavid R. Baughman
    • Ray V. HuffSteven G. AxenDavid R. Baughman
    • E21B43/28E21B43/30
    • E21B43/283E21B43/30
    • A method of isolating a contaminated geological formation or aquifer is disclosed in which the formation is encapsulated by impermeable barriers. A grid of wells is drilled into the formation. A horizontal barrier is formed below the contaminated formation by creating an overlapping pattern of horizontally-oriented fractures filled with polymer radiating from each of these wells. A horizontal barrier may also be formed above the top surface of the contaminated formation if necessary. A ring of boundary wells may also be drilled surrounding the contaminated formation. The strata around each boundary well are fractured, and a polymer is then injected to form a vertical barrier around the periphery of the contaminated formation. In addition, water may be injected under pressure into guard wells between the contaminated formation and the vertical and/or horizontal barriers to further reduce any migration of pollutants into neighboring formations.
    • 公开了一种分离污染的地质构造或含水层的方法,其中地层被不可渗透的屏障包封。 一个井网钻入地层。 在污染地层下方形成水平屏障,通过产生填充有从这些井中的每一个辐射的聚合物的水平取向的裂缝的重叠图案。 如果需要,还可以在污染地层的顶表面上方形成水平屏障。 也可以在污染地层周围钻一圈边界井。 每个边界井附近的地层被破碎,然后注入聚合物以在污染地层的周围形成垂直屏障。 此外,水可以在压力下注入污染地层与垂直和/或水平屏障之间的保护井,以进一步减少任何污染物迁移到邻近地层中。
    • 3. 发明授权
    • Process for extracting metal values from ores
    • 从矿石提取金属价值的过程
    • US5169503A
    • 1992-12-08
    • US210986
    • 1988-06-24
    • David R. BaughmanRay V. HuffSteven G. Axen
    • David R. BaughmanRay V. HuffSteven G. Axen
    • C22B3/04C25C1/00
    • C22B3/04C25C1/00Y02P10/234
    • Metal values are solubilized from ore by a lixiviant having a pH from 5 to 8, comprising an aqueous solution of a chloride salt and a hypochlorite salt. Cyanuric acid may be added to retard decomposition of the lixiviant. In one alternative embodiment, any remaining hypochlorite ions are then eliminated by adding hydrogen peroxide or a reducing agent to the pregnant lixiviant. Metal values are recovered by reduction using carbon, electrowinning, or other conventional techniques. In an alternative embodiment for extraction of gold or silver, the steps are combined by using finely ground ore containing sulfides or carbonaceous material to both reduce any remaining hypochlorite ions and precipitate the metal values from the lixiviant. The lixiviant can then be regenerated either by electrolysis or addition of hypochlorite salt.
    • 金属值通过pH为5至8的浸提液从矿石中溶解,包括氯化物盐和次氯酸盐的水溶液。 可以加入氰尿酸以延缓浸泡液的分解。 在一个替代实施例中,然后通过向怀孕的浸液中加入过氧化氢或还原剂来除去任何剩余的次氯酸根离子。 通过使用碳,电解还原或其它常规技术的还原来回收金属值。 在用于提取金或银的替代实施方案中,通过使用含有硫化物或碳质材料的精细研磨的矿石来合并这些步骤,以减少任何剩余的次氯酸根离子并从浸取物中沉淀金属值。 然后可以通过电解或添加次氯酸盐来再生浸出液。
    • 4. 发明授权
    • Well repair for in situ leaching
    • 良好的原位浸出修复
    • US4386806A
    • 1983-06-07
    • US236843
    • 1981-02-23
    • Steven G. AxenRay V. HuffJerry R. Bergeson
    • Steven G. AxenRay V. HuffJerry R. Bergeson
    • C09K8/50E21B43/28
    • E21B43/28C09K8/50
    • A permeable region adjacent a well bore used in an acidic in situ leaching system can be repaired by introducing a non-acidic liquid for displacing acidic leach liquid from the permeable region, introducing into the well bore a basic composition including a polymeric material that gels under acidic conditions, and applying sufficient pressure to the well bore to displace at least a portion of the basic composition and polymeric material from the well bore into the permeable region adjacent the well bore. Liquid flow in the well bore is then discontinued for a sufficient time for acid remaining in the subterranean formation adjacent the well bore to contact such polymeric material and cause gelation of the polymeric material in the permeable region. The introduction of acidic leach liquid can then continue.
    • 在酸性原位浸出系统中使用的井眼附近的可渗透区域可以通过引入用于从可渗透区域排出酸性浸出液的非酸性液体来修复,将包含聚合物材料的基本组合物引入孔中, 并且向井眼施加足够的压力以将基本组合物和聚合物材料的至少一部分从井眼移入与井眼相邻的可渗透区域中。 然后,在井眼中的液体流动停止足够的时间,以使残留在邻近井眼的地下地层中的酸接触这种聚合物材料并引起聚合材料在可渗透区域中的凝胶化。 然后可以继续引入酸性浸出液。