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    • 2. 发明授权
    • Preparation method of polymeric rod and gradient-index rod lens using
free radical bulk polymerization with temperature gradient
    • 使用具有温度梯度的自由基本体聚合的聚合物棒和梯度指数棒状透镜的制备方法
    • US5863993A
    • 1999-01-26
    • US708545
    • 1996-09-05
    • Sang-Don Jung
    • Sang-Don Jung
    • B29C33/02B29C39/22B29C39/26B29C39/38B29L11/00C08F26/06G02B3/00
    • G02B3/0087B29C35/02B29D11/00355B29D11/00442B29C35/0266
    • A preparation method of polymerid rod using free radical bulk polymerization with temperature gradient, comprising the steps of, charging a mixture of monomer which can be subjected to a radical polymerization, polymerization initiator and cross linking agent into a reaction container of tube shape having a constant inner diameter and performing radical polymerization of the monomer, by passing the said reaction container in a constant dipping speed through a zone downwardly from upper part to lower part of the said zone, wherein the upper part of the zone is maintained at a relatively low temperature (TL) and the lower part of the zone is maintained at a relatively high temperature (TH) than that of the said upper part so that the medium part located between the upper part and lower part has a temperature gradient of (TH-TL)/L (wherein, L is defined as a vertical distance of the temperature-gradient zone). By the present method, it is possible to decrease a transmission loss of the obtained polymeric rod due to scattering. The obtained polymeric rod by the present method having nearly perfect outer shape can be used in preparing a polymeric gradient-index rod lens which is used as an optical component.
    • 使用具有温度梯度的自由基本体聚合的聚合物棒的制备方法,包括以下步骤:将可进行自由基聚合的单体的混合物,聚合引发剂和交联剂加入到具有常数的管状反应容器中 内径并进行单体的自由基聚合,通过使所述反应容器以恒定的浸渍速度通过从所述区域的上部到下部的区域向下的区域,其中该区域的上部保持在相对低的温度 (TL),并且该区域的下部保持在比所述上部的相对高的温度(TH),使得位于上部和下部之间的介质部分具有(TH-TL)的温度梯度, / L(其中,L被定义为温度梯度区的垂直距离)。 通过本方法,可以降低由于散射而导致的聚合物棒的传输损失。 通过本方法获得的具有几乎完美外形的聚合物棒可以用于制备用作光学部件的聚合物梯度折射率棒状透镜。
    • 4. 发明授权
    • Manufacturing method of a polymer GRIN lens using sulfonation
    • 使用磺化的聚合物GRIN透镜的制造方法
    • US5567363A
    • 1996-10-22
    • US352044
    • 1994-11-30
    • Sang-Don JungSeok-Ho Song
    • Sang-Don JungSeok-Ho Song
    • G02B1/04B29D11/00C08F2/18C08F8/36C08F12/00C08F212/00C08F212/02C08F212/36C08J7/00G02B3/00
    • B29D11/00355C08F8/36G02B3/0087
    • The present invention relates to a manufacturing method of a polymer GRIN lens which is used for focusing light in connections for example between two or more optical fibers and between an optical fiber and a light source in the optical communication field. The manufacturing method of a GRIN lens according to the present invention utilizes a characteristic of polystyrene that its refractive-index is decreased by sulfonation. The method includes polymerizing a sphere or rod made of a directional monomer that is capable of sulfonating like a styrene, together with a cross-linking agent, and a polymerization initiator; swelling the polymerized cross-linked polymer by using a predetermined solvent; and sulfonating the swollen cross-linked polymer using a sulfuric acid. Accordingly, the present method can be easily controlled to obtain the desired refractive-index distribution since the refractive-index distribution is determined by the diffusion of the sulfuric acid as a sulfonation.
    • 本发明涉及一种聚合物GRIN透镜的制造方法,其用于在光通信领域中将光聚焦在例如两根或多根光纤之间以及光纤与光源之间的连接中。 根据本发明的GRIN透镜的制造方法利用聚苯乙烯的特性,其折射率通过磺化而降低。 该方法包括使能够与苯乙烯一起磺化的定向单体制成的球或聚合物与交联剂和聚合引发剂一起聚合; 通过使用预定溶剂使聚合的交联聚合物溶胀; 并用硫酸磺化溶胀的交联聚合物。 因此,由于通过硫酸作为磺化的扩散来确定折射率分布,所以可以容易地控制本方法以获得所需的折射率分布。
    • 9. 发明授权
    • Encapsulation method of a polymer or organic light emitting device
    • 聚合物或有机发光装置的封装方法
    • US6150187A
    • 2000-11-21
    • US122755
    • 1998-07-27
    • Tae Hyoung ZyungDo Hoon HwangSang Don Jung
    • Tae Hyoung ZyungDo Hoon HwangSang Don Jung
    • H05B33/04H01L51/52H01L21/00H01L21/44H01L21/48H01L21/50
    • H01L51/5253
    • The present invention relates to the encapsulation for extending the lifetime of a flexible organic or polymer light emitting device and, more particularly, to encapsulation by sealing with multiple polymer films to prevent the penetration of oxygen and moisture into an organic or polymer light emitting device. Due to the encapsulation of polymer light emitting device with the multiple polymer films, exposure to moisture and oxygen are prevented, which are causes of device degradation. When using a plastic substrate whose the thermal endurance is high, simultaneously, it has a thermal endurance effect to the Joule heat during device operation. Accordingly, there can be fabricated an organic or polymer light emitting display whose lifetime is extended through the encapsulation of an organic of polymer light emitting device with multiple polymer films.
    • 本发明涉及用于延长柔性有机或聚合物发光器件的寿命的封装,更具体地说,涉及通过用多个聚合物膜密封以防止氧气和水分渗透到有机或聚合物发光器件中的封装。 由于聚合物发光器件与多个聚合物膜的封装,防止暴露于水分和氧气,这是器件劣化的原因。 当同时使用耐热性高的塑料基板时,在器件操作期间对焦耳热具有热耐久性。 因此,可以制造有机或聚合物发光显示器,其寿命通过具有多个聚合物膜的聚合物发光器件的有机物的封装而延伸。