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    • 6. 发明申请
    • INK SET AND PRINTED MATERIAL
    • 油墨和印刷材料
    • US20150291819A1
    • 2015-10-15
    • US14437736
    • 2013-10-24
    • SAKATA INX CORP.
    • Shinya MizutaniTadashi HiroseTakuya Myose
    • C09D11/40C09D11/107
    • C09D11/40C09D11/101C09D11/107C09D11/322
    • The present invention aims to provide an ink set which has excellent curability under LED light, provides a printed material without coloration or fading due to a photoinitiator, prevents color mixing in image formation, has good adhesion to polyvinyl chloride-based sheets, sufficiently prevent cockling, and has very low viscosity as well as a high flash point and low skin irritation. An ink set including: at least two selected from the group consisting of a yellow ink composition, a magenta ink composition, a cyan ink composition, a black ink composition, a white ink composition, and a clear ink composition. Each ink composition has a flash point of 70° C. or higher and a viscosity at 25° C. of 5 mPa·s or less. The magenta, cyan, and clear ink compositions each contain 4 to 40% by mass of vinyloxyethoxyethyl acrylate, 10 to 65% by mass of benzyl acrylate, 5 to 35% by mass of N-vinylcaprolactam, and an acylphosphine oxide photoinitiator, and are each free of a thioxanthone photoinitiator. The yellow ink composition contains 4 to 40% by mass of vinyloxyethoxyethyl acrylate, 10 to 65% by mass of benzyl acrylate, 5 to 35% by mass of N-vinylcaprolactam, and an acylphosphine oxide photoinitiator. The black ink composition contains 4 to 40% by mass of vinyloxyethoxyethyl acrylate, 10 to 65% by mass of benzyl acrylate, 5 to 35% by mass of N-vinylcaprolactam, a thioxanthone photoinitiator, and an acylphosphine oxide photoinitiator. The white ink composition contains 4 to 40% by mass of vinyloxyethoxyethyl acrylate, 10 to 65% by mass of benzyl acrylate, and an acylphosphine oxide photoinitiator, and is free of a thioxanthone photoinitiator.
    • 本发明旨在提供一种在LED光下具有优异的固化性的油墨组,由于光引发剂而提供不着色或褪色的印刷材料,防止图像形成中的混色,对聚氯乙烯类片材具有良好的粘合性,足以防止起皱 ,并且具有非常低的粘度以及高闪点和低皮肤刺激性。 一种油墨组,包括:选自黄色油墨组合物,品红色油墨组合物,青色油墨组合物,黑色油墨组合物,白色油墨组合物和透明油墨组合物中的至少两种。 每种油墨组合物的闪点为70℃以上,25℃下的粘度为5mPa·s以下。 品红,青色和透明油墨组合物各自含有4〜40质量%的丙烯酸乙烯氧基乙氧基乙酯,10〜65质量%的丙烯酸苄酯,5〜35质量%的N-乙烯基己内酰胺和酰基氧化膦光引发剂,分别为 各自不含噻吨酮光引发剂。 黄色油墨组合物含有4〜40质量%的丙烯酸乙烯氧基乙氧基乙酯,10〜65质量%的丙烯酸苄酯,5〜35质量%的N-乙烯基己内酰胺和酰基氧化膦光引发剂。 黑色油墨组合物含有4〜40质量%的丙烯酸乙烯氧基乙氧基乙酯,10〜65质量%的丙烯酸苄酯,5〜35质量%的N-乙烯基己内酰胺,噻吨酮光引发剂和酰基氧化膦光引发剂。 白色油墨组合物含有4〜40质量%的丙烯酸乙烯氧基乙氧基乙酯,10〜65质量%的丙烯酸苄酯和酰基氧化膦光引发剂,不含噻吨酮光引发剂。
    • 10. 发明申请
    • ORGANIC SOLVENT-BASED CONCENTRATED INK COMPOSITION FOR GRAVURE PRINTING AND GRAVURE PRINTING METHOD
    • US20150090143A1
    • 2015-04-02
    • US14396307
    • 2013-04-26
    • SAKATA INX CORP.
    • Takahiko InoueToru OgawaJunichi Harada
    • C09D11/102C09D7/12B41F13/11
    • C09D11/102B41F13/11B41M1/10B41M1/30C09D7/63C09D11/033C09D11/037
    • The present invention provides an organic solvent-based concentrated ink composition for gravure printing which shows good print density, printability, and laminatability even in gravure printing using a shallow cylinder. The organic solvent-based concentrated ink composition for gravure printing mainly includes a pigment; binder resin; and an organic solvent. The pigment includes at least one of an organic pigment and an inorganic pigment. The binder resin includes polyurethane resin. A solution obtainable by dissolving 30 parts by mass of the polyurethane resin in 70 parts by mass of the organic solvent has a viscosity of 100 to 500 mPa·s/25° C. The concentrated ink composition has a viscosity of 10 to 1000 mPa·s/25° C. and has a viscosity in gravure printing of 12 to 23 s/25° C. in terms of the efflux time from a Zahn cup #3. The concentrated ink composition satisfies one of the following conditions 1 to 3:Condition 1: the pigment being an organic pigment; the amount of the organic pigment being 5 to 20% by mass and the amount of the polyurethane resin being 3 to 20% by mass each in the organic solvent-based concentrated ink composition for gravure printing; and the amount of the polyurethane resin being 60 to 200 parts by mass for 100 parts by mass of the organic pigment;Condition 2: the pigment being an inorganic pigment; the amount of the inorganic pigment being 5 to 70% by mass and the amount of the polyurethane resin being 3 to 20% by mass each in the organic solvent-based concentrated ink composition for gravure printing; and the amount of the polyurethane resin being 5 to 60 parts by mass for 100 parts by mass of the inorganic pigment; andCondition 3: the pigment including both an organic pigment and an inorganic pigment; the amount of the organic pigment being 5 to 20% by mass in the organic solvent-based concentrated ink composition for gravure printing; the ratio by mass ((mass of inorganic pigment)/(mass of organic pigment)) of the organic pigment to the inorganic pigment satisfying 0