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    • 2. 发明授权
    • Polyurethane bend stiffener
    • 聚氨酯弯曲加强筋
    • US09339948B2
    • 2016-05-17
    • US14427250
    • 2013-09-24
    • Robert M. MossIan Robert MycockGareth RobertsAndrew Martin Davies
    • Robert M. MossIan Robert MycockGareth RobertsAndrew Martin Davies
    • E21B17/01B29C31/10C08G18/48C08G18/76H02G9/02H02G9/12B29K75/00
    • B29C31/10B29K2075/00C08G18/4854C08G18/7671E21B17/017H02G9/02H02G9/12C08G18/10C08G18/3206
    • A bend stiffener comprises a (i) a flexible polymeric sleeve having an axial bore for receiving an elongated flexible member and (ii) attachment means for attaching the sleeve to a support. At least a portion of the flexible polymeric sleeve is a polyurethane elastomer produced in a reaction of an isocyanate-terminated prepolymer and a curing agent at an isocyanate index of 90 to 120. The isocyanate-terminated prepolymer has an isocyanate content of 7 to 15% by weight and is a reaction product of at least one aromatic polyisocyanate and at least one polyether polyol having a hydroxyl equivalent weight of 350 to 2000 and a nominal functionality of 2 to 2.3. The curing agent is one or more chain extenders having an equivalent weight per isocyanate-reactive group of up to 125 or a mixture of one or more such chain extenders and one or more polyether polyols having a hydroxyl equivalent weight of 350 to 2000 and a nominal functionality of 2 to 2.3. The hard segment content of the polyurethane elastomer is from 40 to 60% by weight.
    • 弯曲加强件包括(i)具有用于接收细长柔性构件的轴向孔的柔性聚合物套筒和(ii)用于将套筒附接到支撑件的附接装置。 柔性聚合物套管的至少一部分是在异氰酸酯封端的预聚物和固化剂在异氰酸酯指数为90至120的反应中制备的聚氨酯弹性体。异氰酸酯封端的预聚物的异氰酸酯含量为7-15% 并且是至少一种芳族多异氰酸酯和至少一种羟基当量重量为350至2000,标称官能度为2至2.3的聚醚多元醇的反应产物。 固化剂是一种或多种增链剂,其具有至多125个异氰酸酯反应性基团的当量重量,或一种或多种这种扩链剂和一种或多种羟基当量重量为350至2000的聚醚多元醇的混合物, 功能2到2.3。 聚氨酯弹性体的硬链段含量为40〜60重量%。