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1. 发明授权

US5021573A Heterocyclic pigments and dyes 失效
标题翻译：杂环颜料和染料
公开(公告)号：US5021573A
公开(公告)日：1991-06-04
申请号：US340348
申请日：1989-04-19
申请人： Peter Bitterli , Bansi L. Kauh
发明人： Peter Bitterli , Bansi L. Kauh
IPC分类号： C08K5/3412 , C08K5/3417 , C09B57/00 , C09B57/08
CPC分类号： C09B57/00
摘要： A compound of formula I ##STR1## in which each R.sub.1 independently is selected from oxygen, .dbd.NH or .dbd.N--R.sub.2 where R.sub.2 is an aromatic or heteroaromatic group, provided not more than two groups R.sub.1 are selected from oxygen and .dbd.NH.
摘要翻译：式I的化合物，其中每个R 1独立地选自氧，= NH或= N-R 2，其中R 2是芳族或杂芳族基团，提供不多于两个基团，R 1选自氧和= NH。

2. 发明授权

US4866113A Compounds useful as pigments containing one or more 2,2,6,6-tetraalkylpiperidine groups 失效
标题翻译：可用作含有一个或多个2,2,6,6-四烷基哌啶基团的颜料的化合物
公开(公告)号：US4866113A
公开(公告)日：1989-09-12
申请号：US183117
申请日：1988-04-19
申请人： Peter Bitterli , Manfred Geisel , Jurgen Goldmann , Bansi L. Kaul
发明人： Peter Bitterli , Manfred Geisel , Jurgen Goldmann , Bansi L. Kaul
IPC分类号： C09B33/153 , C08J3/20 , C09B3/18 , C09B19/02 , C09B25/00 , C09B29/20 , C09B29/33 , C09B29/52 , C09B33/02 , C09B47/06 , C09B57/00 , C09B57/04 , C09B57/12 , C09B67/20 , C09B69/00
CPC分类号： C09B25/00 , C09B19/02 , C09B29/20 , C09B29/334 , C09B29/3673 , C09B3/18 , C09B33/02 , C09B47/062 , C09B57/00 , C09B57/04 , C09B57/12 , C09B69/00
摘要： A pigment, which retains a crystal or particulate structure throughout a process of coloration of a substrate, containing one or more 2,2,6,6-tetraalkylpiperidine groups.
摘要翻译：一种颜料，其在包含一个或多个2,2,6,6-四烷基哌啶基团的底物着色过程中保留晶体或颗粒结构。

3. 发明授权

US5283325A 1:2 chromium and cobalt complexes of monoazo compounds having further unsubstituted or substituted nitro-2-hydroxyphenyl diazo component radicals and 6- or 7-acyl-amino-1-hydroxy-3-sulfonaphthalene coupling component radicals 失效
标题翻译： 1：2具有进一步未取代或取代的硝基-2-羟基苯基重氮组分基团的单偶氮化合物的铬和钴络合物和6-或7-酰基 - 氨基-1-羟基-3-磺基萘偶联组分基团
公开(公告)号：US5283325A
公开(公告)日：1994-02-01
申请号：US801555
申请日：1991-12-02
申请人： Peter Bitterli
发明人： Peter Bitterli
IPC分类号： C09B45/14 , C23C22/26 , D06P1/10 , D06P3/24
CPC分类号： C09B45/14
摘要： 1:2 metal complexes of the formula ##STR1## wherein each of R.sub.1 and R.sub.3 is independently hydrogen or nitro, with the proviso that when a ring has two nitro groups, they are meta to each other,each of R.sub.2 and R.sub.4 is independently hydrogen, chloro or --SO.sub.3 M,each of R.sub.5 and R.sub.6 is independently hydrogen, --COR.sub.7, --CONHR.sub.8 or --SO.sub.2 R.sub.9,wherein R.sub.7 is C.sub.1-6 alkyl, C.sub.1-6 alkoxy, phenyl(C.sub.1-4 -alkyl) or phenyl(C.sub.1-4 -alkyl) the phenyl group of which is substituted by 1 or 2 substituents selected from halo, C.sub.1-4 -alkyl, C.sub.1-4 alkoxy, nitro, amino, --COOM, --SO.sub.3 M and acetamido,R.sub.8 is hydrogen, C.sub.1-6 alkyl; phenyl; phenyl substituted by 1 or 2 substituents selected from halo, C.sub.1-4 -alkyl, C.sub.1-4 alkoxy, nitro, amino, --COOM, --SO.sub.3 M and acetamido; naphthyl or naphthyl monosubstituted by chloro, amino, phenylamino, acetamido, benzamido or --SO.sub.3 M, andR.sub.9 is C.sub.1-6 alkyl, phenyl or phenyl substituted by 1 or 2 substituents selected from halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, nitro, amino, --COOM, --SO.sub.3 M and acetamido, andMe is chromium or cobalt,wherein each M and M.sup..sym. is independently hydrogen or a non-chromophoric cation, with the provisos that (1) when both R.sub.5 and R.sub.6 are hydrogen, both R.sub.1 and R.sub.3 are hydrogen and at least one of R.sub.2 and R.sub.4 is chloro, and (2) the --NHR.sub.5 group is in the 2- or 3-position of Ring A and the --NHR.sub.6 group is in the 2- or 3-position of Ring B, and mixtures thereof, useful as dyes for dyeing or printing various materials, such as natural and synthetic polyamides and particularly for dyeing artificially produced oxide layers on and aluminum alloys.
摘要翻译： 1：2的式“IMAGE”金属络合物，其中R 1和R 3各自独立地为氢或硝基，条件是当环具有两个硝基时，它们彼此间位，R 2和R 4各自独立地为氢，氯或-SO 3 M，R 5和R 6各自独立地是氢，-COR 7，-CONHR 8或-SO 2 R 9，其中R 7是C 1-6烷基，C 1-6烷氧基，苯基（C 1-4 - 烷基）或苯基（C 1-4 - 烷基），其苯基被1或2个选自卤素，C 1-4 - 烷基，C 1-4烷氧基，硝基，氨基，-COOM，-SO 3 M和乙酰氨基的取代基取代，R 8是氢，C 1-6烷基; 苯基; 被1或2个选自卤素，C 1-4 - 烷基，C 1-4烷氧基，硝基，氨基，-COOM，-SO 3 M和乙酰氨基的取代基取代的苯基; 被氯，氨基，苯基氨基，乙酰氨基，苯甲酰氨基或-SO 3 M单取代的萘基或萘基，R 9为C 1-6烷基，苯基或被1或2个选自卤素，C 1-4烷基，C 1-4烷氧基，硝基，氨基， -COOM，-SO 3 M和乙酰氨基，Me是铬或钴，其中每个M和M（+）独立地是氢或非发色阳离子，条件是（1）当R5和R6都是氢时，并且R 3是氢，并且R 2和R 4中的至少一个是氯，和（2）-NHR 5基团在环A的2-或3-位，并且-NHR 6基团在2- 环B及其混合物，可用作用于染色或印刷各种材料的染料，例如天然和合成聚酰胺，特别是用于人造生产的氧化物层和铝合金上的染色。

4. 发明授权

US4734515A 1:2 metal complexes of 2-nitroso-acetoacetic acid and benzoylacetic acid arylamides 失效
标题翻译： 1：2的2-亚硝基乙酰乙酸和苯甲酰基乙酰基芳基酰胺的金属络合物
公开(公告)号：US4734515A
公开(公告)日：1988-03-29
申请号：US894401
申请日：1986-08-08
申请人： Peter Bitterli , Jurgen Goldmann , Bansi L. Kaul
发明人： Peter Bitterli , Jurgen Goldmann , Bansi L. Kaul
IPC分类号： C09B57/10 , C07F1/08 , C07F3/06 , C07F15/04 , C07F15/06
CPC分类号： C09B57/10
摘要： Complexes of the formula ##STR1## wherein each R.sub.1 is independently a monocyclic or fused ring aromatic or heteroaromatic group free of water-solubilizing groups,each R.sub.2 is independently is phenyl or methyl, andMe is Ni, Cu, Co or Zn, are useful as pigments for, for example, the mass pigmenting of synthetic plastics and resins, surface coatings and inks, pigment printing, textile coating and pigmenting paper in the mass.
摘要翻译：其中每个R 1独立地是不含水溶性基团的单环或稠环芳族或杂芳族基团，每个R 2独立地是苯基或甲基，Me是Ni，Cu，Co或Zn是有用的作为用于例如合成塑料和树脂，表面涂料和油墨，颜料印刷，纺织品涂料和着色纸的质量着色的颜料。

5. 发明授权

US4494955A Mass dyeing of polyester with pyrrocoline dye of his thermal stability 失效
标题翻译：大量染色聚酯与吡咯啉染料的热稳定性
公开(公告)号：US4494955A
公开(公告)日：1985-01-22
申请号：US549076
申请日：1983-11-07
申请人： Peter Bitterli , Bansi L. Kaul
发明人： Peter Bitterli , Bansi L. Kaul
IPC分类号： C08L67/00 , C08K5/34 , C08K5/3432 , C08J3/20 , C08L67/02 , C09B57/00
CPC分类号： C08K5/3432 , Y10S8/922
摘要： Disclosed is mass-dyed polyester comprising, as dyestuff, a compound or mixture of compounds of formula I ##STR1## wherein R.sub.1 is a direct bond, --CONH-- or --NHCO--, R.sub.2 is alkyl, phenyl or naphthyl, optionally substituted or cyano, provided that R.sub.1 is a direct bond when R.sub.2 is cyano, and R.sub.3 is hydrogen, methyl, ethyl, alkoxy-C.sub.1-3 -carbonyl or --CH.dbd.CH--CH.dbd.CH-- bound in the 1,2-position.
摘要翻译：公开了包含作为染料作为染料的式I化合物或其混合物的化合物的批量染料，其中R 1是直接键，-CONH-或-NHCO-，R 2是烷基，苯基或萘基，任选被取代或氰基，条件是当R 2是氰基时R 1是直接键，并且R 3是氢，甲基，乙基，烷氧基-C 3-3 - 羰基或-CH = CH-CH = CH-键合在1,2位上。

6. 发明授权

US5123930A 1:2 chromium and cobalt complexes of monoazo compounds for drying porous oxide layers on aluminum and aluminum alloy substrates 失效
标题翻译： 1：2用于在铝和铝合金基底上干燥多孔氧化物层的单偶氮化合物的铬和钴复合物
公开(公告)号：US5123930A
公开(公告)日：1992-06-23
申请号：US570940
申请日：1990-08-21
申请人： Peter Bitterli
发明人： Peter Bitterli
IPC分类号： C09B45/14 , C09B45/16 , C09B45/20 , C23C22/84
CPC分类号： C09B45/14
摘要： 1:2 metal complexes of the formula ##STR1## wherein each of R.sub.1 and R.sub.3 is independently hydrogen or nitro, with the proviso that when a ring has two nitro groups, they are meta to each other,each of R.sub.2 and R.sub.4 is independently hydrogen, chloro or --SO.sub.3 M,each of R.sub.5 and R.sub.6 is independently hydrogen, --COR.sub.7, --CONHR.sub.8 or --SO.sub.2 R.sub.9,whereinR.sub.7 is C.sub.1-6 alkyl, C.sub.1-6 alkoxy, phenyl(C.sub.1-4 -alkyl) or phenyl (C.sub.1-4 alkyl) the phenyl group of which is substituted by 1 or 2 substituents selected from halo, C.sub.1-4 -alkyl, C.sub.1-4 alkoxy, nitro, amino, --COOM, --SO.sub.3 M and acetamido,R.sub.8 is hydrogen; C.sub.1-6 alkyl; phenyl; phenyl substituted by 1 or 2 substituents selected from halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, nitro, amino, --COOM, --SO.sub.3 M and acetamido; naphthyl or naphthyl monosubstituted by chloro, amino, phenylamino, acetamido, benzamido or --SO.sub.3 M, andR.sub.9 is C.sub.1-6 alkyl, phenyl or phenyl substituted by 1 or 2 substituents selected from halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, nitro, amino, --COOM, --SO.sub.3 M and acetamido, andMe is chromium or cobalt, wherein each M and M.sup..sym. is independently hydrogen or a non-chromophoric cation,with the provisos that (1) when both R.sub.5 and R.sub.6 are hydrogen, both R.sub.1 and R.sub.3 are hydrogen and at least one of R.sub.2 and R.sub.4 is chloro, and (2) the --NHR.sub.5 group is in the 2- or 3-position of Ring A and the --NHR.sub.6 group is in the 2- or 3-position of Ring B, and mixtures thereof, are useful as dyes for dyeing or printing various materials, such as natural and synthetic polyamides and particularly for dyeing artificially produced oxide layers on aluminum or aluminum alloys.
摘要翻译： 1：2的式“IMAGE”金属络合物，其中R 1和R 3各自独立地为氢或硝基，条件是当环具有两个硝基时，它们彼此间位，R 2和R 4各自独立地为氢，氯或-SO 3 M，R 5和R 6各自独立地是氢，-COR 7，-CONHR 8或-SO 2 R 9，其中R 7是C 1-6烷基，C 1-6烷氧基，苯基（C 1-4 - 烷基）或苯基（C 1-4烷基）其苯基被1或2个选自卤素，C 1-4 - 烷基，C 1-4烷氧基，硝基，氨基，-COOM，-SO 3 M和乙酰氨基的取代基取代，R 8为氢; C 1-6烷基; 苯基; 被1或2个选自卤素，C 1-4烷基，C 1-4烷氧基，硝基，氨基，-COOM，-SO 3 M和乙酰氨基的取代基取代的苯基; 被氯，氨基，苯基氨基，乙酰氨基，苯甲酰氨基或-SO 3 M单取代的萘基或萘基，R 9为C 1-6烷基，苯基或被1或2个选自卤素，C 1-4烷基，C 1-4烷氧基，硝基，氨基， -COOM，-SO 3 M和乙酰氨基，Me是铬或钴，其中每个M和M（+）独立地是氢或非发色阳离子，条件是（1）当R5和R6都是氢时，并且R 3是氢，并且R 2和R 4中的至少一个是氯，和（2）-NHR 5基团在环A的2-或3-位，并且-NHR 6基团在2- 环B及其混合物可用作染色或印刷各种材料的染料，例如天然和合成聚酰胺，特别是用于在铝或铝合金上人造生产的氧化物层进行染色。

7. 发明授权

US4838943A Compounds useful as pigments containing one or more 2,2,6,6-tetraalkylpiperidine groups 失效
标题翻译：可用作含有一个或多个2,2,6,6-四烷基哌啶基团的颜料的化合物
公开(公告)号：US4838943A
公开(公告)日：1989-06-13
申请号：US35954
申请日：1987-04-08
申请人： Peter Bitterli , Manfred Geisel , Jurgen Goldmann , Bansi L. Kaul
发明人： Peter Bitterli , Manfred Geisel , Jurgen Goldmann , Bansi L. Kaul
IPC分类号： C09B33/153 , C08J3/20 , C09B3/18 , C09B19/02 , C09B25/00 , C09B29/20 , C09B29/33 , C09B29/52 , C09B33/02 , C09B47/06 , C09B57/00 , C09B57/04 , C09B57/12 , C09B67/20 , C09B69/00
CPC分类号： C09B25/00 , C09B19/02 , C09B29/20 , C09B29/334 , C09B29/3673 , C09B3/18 , C09B33/02 , C09B47/062 , C09B57/00 , C09B57/04 , C09B57/12 , C09B69/00
摘要： A pigment, which retains a crystal or particulate structure throughout a process of coloration of a substrate, containing one or more 2,2,6,6-tetraalkylpiperidien groups.
摘要翻译：一种颜料，其在包含一个或多个2,2,6,6-四烷基哌啶基的基底着色过程中保留晶体或颗粒结构。

8. 发明授权

US5542975A .beta.-crystal form of 4,4'-Diamino-3,3'-Dibromo-1,1'-Dianthraquinonyl 失效
标题翻译： 4,4'-二氨基-3,3'-二溴-1,1'-二蒽醌的β-晶体形式
公开(公告)号：US5542975A
公开(公告)日：1996-08-06
申请号：US493080
申请日：1995-06-21
申请人： Peter Bitterli
发明人： Peter Bitterli
IPC分类号： C09B67/20 , C09B67/48 , C09B1/22 , C07C50/18 , C07C225/34
CPC分类号： C09B67/0025
摘要： The new .beta.-modification of the pigment 4,4'-diamino-3,3'-dibromo-1,1'-dianthraquinonyl, having characteristic lines in the X-ray diagram (Guinier/De Wolff, Cu K.alpha..sub.1 -radiation) according to the FIG. 1 has significant dyeing advantages over the known .alpha.-modification.
摘要翻译：颜料4,4'-二氨基-3,3'-二溴-1,1'-二蒽醌的新β-改性在X射线图（Guinier / De Wolff，CuKα1辐射）中具有特征线）。 1相对于已知的α-修饰具有显着的染色优点。

9. 发明授权

US4008097A Co-condensate mixtures of iminoisoindolinones 失效
标题翻译：亚氨基二吲哚啉酮的共缩合物混合物
公开(公告)号：US4008097A
公开(公告)日：1977-02-15
申请号：US637361
申请日：1975-12-03
申请人： Peter Bitterli , Fritz Kehrer
发明人： Peter Bitterli , Fritz Kehrer
IPC分类号： C07D209/50 , C09B57/04 , C09B67/22
CPC分类号： C09B67/0033 , C07D209/50 , C09B57/04
摘要： Disclosed are pigments, being co-condensate mixtures of compounds of formula I, ##STR1## wherein R.sub.1 is chlorine, bromine, fluorine, methyl, methoxy or ethoxy, preferably chlorine or methyl,R.sub.2 is hydrogen or has one of the significances of R.sub.1, preferably hydrogen, chlorine or methyl,At least two of the compounds in said mixture being present in an amount of at least 0.1 mol per mol of mixture.
摘要翻译：公开了颜料，即式I化合物的共缩合物混合物，其中R1是氯，溴，氟，甲基，甲氧基或乙氧基，优选氯或甲基，R2是氢或具有R1的意义之一，优选氢，氯或甲基，至少两个混合物中的化合物存在于至少0.1摩尔混合物中。

10. 发明授权

US4316032A Oximino-imino-isoindoline metal complexes useful as pigments 失效
标题翻译：用作颜料的肟基亚氨基 - 异二氢吲哚金属络合物
公开(公告)号：US4316032A
公开(公告)日：1982-02-16
申请号：US144382
申请日：1980-04-28
申请人： Peter Bitterli
发明人： Peter Bitterli
IPC分类号： C07D209/44 , C07D403/12 , C07D417/12 , C07D495/04 , C07F1/08 , C07F15/00 , C08K5/00 , C08K5/3412 , C08K5/3415 , C09B55/00 , C09B57/04 , C09B57/10 , C09D5/00 , C09D11/00 , C09D11/02
CPC分类号： C07D209/44 , C08K5/0041 , C08K5/0091 , C09B57/04 , C09B57/10
摘要： The present invention relates to the compounds of formula I ##STR1## and metal complexes thereof, in which both R.sub.1 's are hydrogen or halogen or form a condensed ring of the benzene series, or --S--CH.sub.2 CH.sub.2 --S--, andR.sub.3 is hydrogen, a mono- or dicyclic-aromatic group or is a divalent radical of the phenylene or naphthalene series linking one further compound of formula I, wherein R.sub.3 is a direct bond and the R.sub.1 groups are the same as or different from the R.sub.1 groups of the first compound of formula I,which metal complexes are either 1:1 metal complexes when R.sub.3 is a divalent linking radical, or 1:2 metal complexes of monomeric compounds of formula I such 1:2 complexes being symmetric or asymmetric and the metal is a divalent transition metal, the complexes are useful as pigments.
摘要翻译：本发明涉及式Ⅰ化合物及其金属配合物，其中R1均为氢或卤素或形成苯系稠环，或-S-CH2CH2-S-，R3为氢单环或二环芳族基团或者是连接一个另外的式I化合物的亚苯基或萘系的二价基团，其中R 3是直接键，并且R 1基团与R 1基团的R 1基团相同或不同式I的第一化合物，当R3是二价连接基团时，该金属络合物为1：1金属络合物，或式I单体化合物的1:2金属络合物，例如对称或不对称的1：2络合物，金属为二价过渡金属，该配合物可用作颜料。

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