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1. 发明申请

US20080177004A1 ADHESIVE COMPOSITIONS FOR BONDING AND FILLING LARGE ASSEMBLIES 有权
标题翻译：用于粘合和填充大型组件的粘合剂组合物
公开(公告)号：US20080177004A1
公开(公告)日：2008-07-24
申请号：US12056342
申请日：2008-03-27
申请人： Samuel B. Osae , Paul C. Briggs
发明人： Samuel B. Osae , Paul C. Briggs
IPC分类号： C08L9/00
CPC分类号： C08F283/01 , C08F220/18 , C08F263/00 , C08F279/02 , C08F291/00 , C08L23/0869 , C08L23/286 , C08L33/08 , C08L45/00 , C08L51/00 , C08L55/02 , C08L101/00 , C08L2312/00 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C09J4/06 , C09J133/08 , C09J167/06 , C08F255/00 , C08F287/00 , C08F265/04
摘要： Adhesive composition for bonding and filling large assemblies, including a mixture of about 5 percent to about 75 percent by weight of a thermoplastic polymer, about 0.5 percent to about 35 percent by weight of a polyester resin or vinyl ester resin, and about 20 percent to about 80 percent by weight of an alkyl acrylate or methacrylate monomer.
摘要翻译：用于粘合和填充大组件的粘合剂组合物，包括约5重量％至约75重量％的热塑性聚合物，约0.5重量％至约35重量％的聚酯树脂或乙烯基酯树脂的混合物，和约20重量％约80重量％的丙烯酸烷基酯或甲基丙烯酸烷基酯单体。

2. 发明授权

US5112691A Adhesive for low temperature applications 失效
标题翻译：用于低温应用的粘合剂
公开(公告)号：US5112691A
公开(公告)日：1992-05-12
申请号：US547970
申请日：1990-07-05
申请人： Paul C. Briggs , Donald E. Gosiewski
发明人： Paul C. Briggs , Donald E. Gosiewski
IPC分类号： C09J4/02 , C09J4/06
CPC分类号： C09J4/06 , Y10T428/31507 , Y10T428/31692 , Y10T428/31696 , Y10T428/31931 , Y10T428/31935
摘要： Adhesive compositions are made from methacrylate ester monomers, elastomeric polymers having a Tg below -25.degree. C. and which are soluble in the monomers, core-shell polymers which swell in the monomers but do not dissolve therein, and free radical producing catalysts. These adhesive compositions when used in bonded assemblies exhibit a combination of high adhesive bond impact strength and high bulk tensile elongation.
摘要翻译：粘合剂组合物由甲基丙烯酸酯单体，Tg低于-25℃，可溶于单体的弹性体聚合物，在单体中溶胀但不溶解的核 - 壳聚合物和自由基生成催化剂制成。当粘合组合物使用时，这些粘合剂组合物表现出高的粘合剂粘合冲击强度和高体积拉伸伸长率的组合。

3. 发明授权

US4959405A Acid modified adhesive composition 失效
标题翻译：酸改性粘合剂组合物
公开(公告)号：US4959405A
公开(公告)日：1990-09-25
申请号：US361749
申请日：1989-06-02
申请人： Paul C. Briggs , Donald E. Gosiewski
发明人： Paul C. Briggs , Donald E. Gosiewski
IPC分类号： C08F255/02 , C09J4/06
CPC分类号： C08F255/023 , C09J4/06
摘要： It has been discovered that by adding one or more strong organic carboxylic acids to conventional acrylate and/or methacrylate based adhesive compositions, the bonding characteristics thereof change dramatically.Thermoplastic materials whose bondability is most dramatically enhanced by the compositions of the present invention are nylon and blends of nylon and nylon-like materials with other polymers.Thermoset materials which exhibit dramatically enhanced bondability comprise homogeneous materials such as epoxies, and composite materials such as polyesters, urethanes, and/or epoxies, containing glass, minerals, and the like, which are polar or have hydrogen bonding capability.The present invention thus utilizes acrylate and/or methacrylate based adhesive compositions as a base material. To this base material is added an effective amount of one or more strong organic carboxylic acids, e.g., acids having a relatively high dissociation constant (K.sub.d or K.sub.ld). It has further been discovered that, the addition of water to these acids can increase their effectiveness, apparently through partial or enhanced solubility, which is believed to aid in the dissociation thereof.
摘要翻译：已经发现，通过向常规的丙烯酸酯和/或甲基丙烯酸酯基粘合剂组合物中加入一种或多种强有机羧酸，其粘合特性显着变化。通过本发明的组合物最能显着提高其粘合性的热塑性材料是尼龙和尼龙和尼龙类材料与其它聚合物的共混物。显示出显着增强的粘合性的热固性材料包括均匀的材料，例如环氧树脂，以及包含玻璃，矿物等的具有极性或具有氢键能力的复合材料如聚酯，聚氨酯和/或环氧树脂。因此，本发明利用基于丙烯酸酯和/或甲基丙烯酸酯的粘合剂组合物作为基材。向该基础材料中加入有效量的一种或多种强有机羧酸，例如具有较高解离常数的酸（Kdor Kld）。进一步发现，向这些酸中加入水可以提高它们的有效性，显然是通过部分或增强的溶解度，这被认为有助于其解离。

4. 发明授权

US4714730A Acid modified adhesive compositions 失效
标题翻译：酸改性粘合剂组合物
公开(公告)号：US4714730A
公开(公告)日：1987-12-22
申请号：US870710
申请日：1986-06-04
申请人： Paul C. Briggs , Donald E. Gosiewski
发明人： Paul C. Briggs , Donald E. Gosiewski
IPC分类号： B29C65/52 , B32B7/12 , C08F2/44 , C08F20/12 , C08F255/02 , C08L23/34 , C08L51/00 , C09J4/02 , C09J4/06 , C08K5/09
CPC分类号： C09J4/06 , C08F255/023 , B29C66/7392 , B29C66/7394
摘要： It has been discovered that by adding one or more strong organic carboxylic acids to conventional acrylate and/or methacrylate based adhesive compositions, the bonding characteristics thereof change dramatically.Thermoplastic materials whose bondability is most dramatically enhanced by the compositions of the present invention are nylon and blends of nylon and nylon-like materials with other polymers.Thermoset materials which exhibit dramatically enhanced bondability comprise homogeneous materials such as epoxies, and composite materials such as polyesters, urethanes, and/or epoxies, containing glass, minerals, and the like, which are polar or have hydrogen bonding capability.The present invention thus utilizes acrylate and/or methacrylate based adhesive compositions as a base material. To this base material is added an effective amount of one or more strong organic carboxylic acids, e.g., acids having a relatively high dissociation constant (K.sub.d or K.sub.1d). It has further been discovered that, the addition of water to these acids can increase their effectiveness, apparently through partial or enhanced solubility, which is believed to aid in the dissociation thereof.
摘要翻译：已经发现，通过向常规的丙烯酸酯和/或甲基丙烯酸酯基粘合剂组合物中加入一种或多种强有机羧酸，其粘合特性显着变化。通过本发明的组合物最能显着提高其粘合性的热塑性材料是尼龙和尼龙和尼龙类材料与其它聚合物的共混物。显示出显着增强的粘合性的热固性材料包括均匀的材料，例如环氧树脂，以及包含玻璃，矿物等的具有极性或具有氢键能力的复合材料如聚酯，聚氨酯和/或环氧树脂。因此，本发明利用基于丙烯酸酯和/或甲基丙烯酸酯的粘合剂组合物作为基材。向该基材中加入有效量的一种或多种强有机羧酸，例如具有较高解离常数（Kd或K1d）的酸。进一步发现，向这些酸中加入水可以提高它们的有效性，显然是通过部分或增强的溶解度，这被认为有助于其解离。

5. 发明授权

US4182644A Polymer in monomer adhesive composition and method employing same 失效
标题翻译：单体粘合剂组合物中的聚合物及其使用方法
公开(公告)号：US4182644A
公开(公告)日：1980-01-08
申请号：US940618
申请日：1978-09-08
申请人： Paul C. Briggs, Jr. , Lawrence C. Muschiatti
发明人： Paul C. Briggs, Jr. , Lawrence C. Muschiatti
IPC分类号： C08F291/00 , C09J4/06 , C09J5/04 , B32B7/00 , C08L61/20
CPC分类号： C09J5/04 , C08F291/00 , C09J4/06
摘要： Adhesive compositions comprising a solution of polymer dissolved in acrylic monomers containing an organic sulfonyl chloride, a polymerization catalyst and an accelerator.
摘要翻译：包含溶解在含有有机磺酰氯的丙烯酸单体中的聚合物溶液，聚合催化剂和促进剂的粘合剂组合物。

6. 发明授权

US07795351B2 Adhesive compositions for bonding and filling large assemblies 有权
公开(公告)号：US07795351B2
公开(公告)日：2010-09-14
申请号：US11646664
申请日：2006-12-28
申请人： Samuel B. Osae , Paul C. Briggs
发明人： Samuel B. Osae , Paul C. Briggs
IPC分类号： C08L9/00 , C08L27/04 , C08L33/04 , C08L33/14 , C08L35/02 , C08L41/00
CPC分类号： C08F283/01 , C08F220/18 , C08F263/00 , C08F279/02 , C08F291/00 , C08L23/0869 , C08L23/286 , C08L33/08 , C08L45/00 , C08L51/00 , C08L55/02 , C08L101/00 , C08L2312/00 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C09J4/06 , C09J133/08 , C09J167/06 , C08F255/00 , C08F287/00 , C08F265/04
摘要： Adhesive composition for bonding and filling large assemblies, including a mixture of about 5 percent to about 75 percent by weight of a thermoplastic polymer, about 0.5 percent to about 35 percent by weight of a polyester resin or vinyl ester resin, and about 20 percent to about 80 percent by weight of an alkyl acrylate or methacrylate monomer.

7. 发明授权

US06602958B2 Adhesives for bonding composites 有权
标题翻译：用于粘接复合材料的粘合剂
公开(公告)号：US06602958B2
公开(公告)日：2003-08-05
申请号：US09902436
申请日：2001-07-10
申请人： Paul C. Briggs , Masaki Minato , Samuel B. Osae
发明人： Paul C. Briggs , Masaki Minato , Samuel B. Osae
IPC分类号： C08F800
CPC分类号： C09J4/06 , C08F265/04
摘要： Adhesive composition, including a mixture of about 1 percent to about 35 percent by weight of chlorinated polymer, about 1 percent to about 35 percent by weight of a nitrile elastomer, a rubber-modified acrylonitrile copolymer, or mixtures thereof, and about 25 percent to about 90 percent by weight of an alkyl acrylate or methacrylate monomer.
摘要翻译：粘合剂组合物，包括约1重量％至约35重量％的氯化聚合物，约1重量％至约35重量％的腈弹性体，橡胶改性的丙烯腈共聚物或其混合物的混合物，约25重量％约90重量％的丙烯酸烷基酯或甲基丙烯酸烷基酯单体。

8. 发明授权

US5945461A Foamed acrylic polymer compositions 失效
标题翻译：发泡丙烯酸类聚合物组合物
公开(公告)号：US5945461A
公开(公告)日：1999-08-31
申请号：US672961
申请日：1991-03-21
申请人： Donald E. Gosiewski , Paul C. Briggs
发明人： Donald E. Gosiewski , Paul C. Briggs
IPC分类号： C08F2/44 , C08F220/10 , C08F220/18 , C08J9/04 , C08J9/06 , C08J9/08 , C08J11/06
CPC分类号： C08J9/08 , C08J11/06 , C08J9/04 , C08J2351/04 , Y02W30/701
摘要： Foamed in place polymer compositions are made from monomer-in-polymer solutions containing free radical polymerization catalysts and foaming agents.
摘要翻译：发泡的聚合物组合物由含有自由基聚合催化剂和发泡剂的单体聚合物溶液制成。

9. 发明授权

US4426243A Room-temperature-curable, quick-setting acrylic/epoxy adhesives and methods of bonding 失效
标题翻译：室温可固化，速凝丙烯酸/环氧胶粘剂和粘合方法
公开(公告)号：US4426243A
公开(公告)日：1984-01-17
申请号：US326355
申请日：1981-12-01
申请人： Paul C. Briggs
发明人： Paul C. Briggs
IPC分类号： C08F299/02 , C08G59/40 , C09J4/00 , C09J4/02 , C09J163/10 , C09J5/02
CPC分类号： C09J163/10 , C08F299/026 , C08G59/40 , C09J4/00 , Y10S525/922 , Y10T428/31515 , Y10T428/31536
摘要： A polymerizable mixture for adhesive bonding is disclosed. The polymerizable mixture comprises a polymerizable acrylic-based material, a polymerizable epoxide-based material and a bifunctional molecular material reactable with said acrylic-based material and said epoxide-based material.
摘要翻译：公开了一种用于粘合剂的可聚合混合物。可聚合混合物包含可聚合丙烯酸类材料，可聚合环氧化物类材料和可与所述丙烯酸类材料和所述环氧化物类材料反应的双功能分子材料。

10. 发明授权

US07816453B2 Adhesive compositions for bonding and filling large assemblies 有权
标题翻译：用于粘合和填充大型组件的粘合剂组合物
公开(公告)号：US07816453B2
公开(公告)日：2010-10-19
申请号：US12056342
申请日：2008-03-27
申请人： Samuel B. Osae , Paul C. Briggs
发明人： Samuel B. Osae , Paul C. Briggs
IPC分类号： C08L23/00 , C08L23/04 , C08L27/04 , C08L33/00 , C08L33/02 , C08L33/14 , C08L41/00 , C08L45/00 , C08K5/00
CPC分类号： C08F283/01 , C08F220/18 , C08F263/00 , C08F279/02 , C08F291/00 , C08L23/0869 , C08L23/286 , C08L33/08 , C08L45/00 , C08L51/00 , C08L55/02 , C08L101/00 , C08L2312/00 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C09J4/06 , C09J133/08 , C09J167/06 , C08F255/00 , C08F287/00 , C08F265/04
摘要： Adhesive composition for bonding and filling large assemblies, including a mixture of about 5 percent to about 75 percent by weight of a thermoplastic polymer, about 0.5 percent to about 35 percent by weight of a polyester resin or vinyl ester resin, and about 20 percent to about 80 percent by weight of an alkyl acrylate or methacrylate monomer.
摘要翻译：用于粘合和填充大组件的粘合剂组合物，包括约5重量％至约75重量％的热塑性聚合物，约0.5重量％至约35重量％的聚酯树脂或乙烯基酯树脂的混合物，和约20重量％约80重量％的丙烯酸烷基酯或甲基丙烯酸烷基酯单体。

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