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1. 发明授权

US06667377B2 Polyvinylidene fluoride ionomers containing pendant fluoroalkylsulfonyl imide or fluoroalkylsulfonyl methide groups 有权
标题翻译：含有氟代烷基磺酰基酰亚胺或氟代烷基磺酰基甲基化基团的聚偏氟乙烯离聚物
公开(公告)号：US06667377B2
公开(公告)日：2003-12-23
申请号：US09852381
申请日：2001-05-10
申请人： Andrew Edward Feiring , Christopher Marc Doyle , Mark Gerrit Roelofs , William Brown Farnham , Paul Gregory Bekiarian , Hanne A. K. Blau
发明人： Andrew Edward Feiring , Christopher Marc Doyle , Mark Gerrit Roelofs , William Brown Farnham , Paul Gregory Bekiarian , Hanne A. K. Blau
IPC分类号： C08F1230
CPC分类号： C07C317/44 , C08F214/222
摘要： This invention concerns ionomers comprising monomer units of vinylidene fluoride and monomer units of perfluorovinyl ethers having pendant groups containing fluoroalkyl sulfonyl methide or fluoroalkyl sulfonyl imide derivatives and univalent metal salts thereof, and with the uses of said ionomers in eledrochemical applications, electrochemical capacitors and modified electrodes.
摘要翻译：本发明涉及包含偏二氟乙烯的单体单元和具有含氟烷基磺酰基甲基化物或氟代烷基磺酰亚胺衍生物和其一价金属盐的侧基的全氟乙烯基醚的单体单元的离聚物，以及所述离聚物在电化学应用中的用途，电化学电容器和改性电极。

2. 发明授权

US06602968B1 Free radical polymerization method for fluorinated copolymers 失效
标题翻译：氟化共聚物的自由基聚合方法
公开(公告)号：US06602968B1
公开(公告)日：2003-08-05
申请号：US09913057
申请日：2001-08-08
申请人： Paul Gregory Bekiarian , William Brown Farnham
发明人： Paul Gregory Bekiarian , William Brown Farnham
IPC分类号： C08F21422
CPC分类号： C08F2/24 , C08F214/222 , C08F214/262
摘要： This invention concerns a process for production of copolymers, especially functionalized, or, at least partially fluorinated copolymers by means of a polymerization process comprising: co-polymerizing, in aqueous emulsion, one or more monomers selected from the group consisting of tetrafluoroethylene, trifluoroethylene, vinylidene fluoride, vinyl fluoride, ethylene, chorotrifluoroethylene, hexafluoropropylene, perfluoromethyl vinyl ether, and perfluoroethyl vinyl ether with a fluorinated co-monomer having limited water solubility, said comonomer being dispersed in the form of droplets of certain sizes.
摘要翻译：本发明涉及通过聚合方法制备共聚物，特别是官能化的或至少部分氟化的共聚物的方法，包括：在水乳液中共聚一种或多种选自四氟乙烯，三氟乙烯，偏二氟乙烯，氟乙烯，乙烯，三氟乙烯，六氟丙烯，全氟甲基乙烯基醚和全氟乙基乙烯基醚与具有有限水溶性的氟化共聚单体，所述共聚单体以某种尺寸的液滴的形式分散。

3. 发明申请

US20100311868A1 LOW REFRACTIVE INDEX COMPOSITION, ABRASION RESISTANT ANTI-REFLECTIVE COATING, AND METHOD FOR FORMING ABRASION RESISTANT ANTI-REFLECTIVE COATING 审中-公开
标题翻译：低折射率组合物，耐磨抗反射涂层和形成耐磨抗反射涂层的方法
公开(公告)号：US20100311868A1
公开(公告)日：2010-12-09
申请号：US12744694
申请日：2008-11-24
申请人： Paul Gregory Bekiarian , Kostantinos Kourtakis
发明人： Paul Gregory Bekiarian , Kostantinos Kourtakis
IPC分类号： C08K5/541 , C08K7/26 , B05D3/02
CPC分类号： C09D127/16 , B82Y30/00 , C08K5/5425 , G02B1/105 , G02B1/111 , G02B1/14 , C08L27/12
摘要： A low refractive index composition is provided comprising the reaction product of: (i) a fluoroelastomer having at least one cure site; (ii) a multiolefinic crosslinker; (iii) a free radical polymerization initiator; (iv) a nanosilica composite comprising: (iv-a) a plurality of nanosilica particles, and (iv-b) at least one of a hydrolysis and condensation product of an oxysilane having a carbon-carbon double bond, wherein the at least one of a hydrolysis and condensation product is formed by contacting, in the presence of an organic acid and a lower alkyl alcohol, the oxysilane with from about 3 to about 9 moles of water per mole of hydrolyzable functional group bonded to the silicon of the oxysilane. The present invention further provides abrasion resistant anti-reflective coatings formed from these low refractive index compositions and methods for forming abrasion resistant anti-reflective coatings for optical display substrates from these low refractive index compositions.
摘要翻译：提供低折射率组合物，其包含以下反应产物：（i）具有至少一个固化位点的含氟弹性体; （ii）多烯烃交联剂; （iii）自由基聚合引发剂; （iv）纳米二氧化硅复合体，其包含：（iv-a）多个纳米二氧化硅颗粒，和（iv-b）具有碳 - 碳双键的氧化硅的水解和缩合产物中的至少一种，其中所述至少一种的水解和缩合产物是通过在有机酸和低级烷基醇的存在下，将羟基硅烷与约3至约9摩尔水/摩尔结合到氧化硅的硅上的可水解官能团相接触而形成的。本发明还提供了由这些低折射率组合物形成的耐磨抗反射涂层以及从这些低折射率组合物形成用于光学显示基板的耐磨抗反射涂层的方法。

4. 发明授权

US07625984B2 Low shrinkage, low optical absorbance, low refractive index adhesive composition 有权
$Low shrinkage, low optical absorbance, low refractive index adhesive composition$
标题翻译：低收缩率，低吸光度，低折射率粘合剂组成
公开(公告)号：US07625984B2
公开(公告)日：2009-12-01
申请号：US12030303
申请日：2008-02-13
申请人： Paul Gregory Bekiarian
发明人： Paul Gregory Bekiarian
IPC分类号： C08F283/06 , C08F290/06 , C08C4/00 , C08J3/24
CPC分类号： C09J4/06 , C08F222/18 , Y10T428/3154
摘要： This invention is directed to fluorinated acrylate compositions, which are suitable for use as low shrinkage, low absorbance refractive index matching adhesives for use in “pig-tailing” polymeric integrated waveguides to optical fiber bundles.
摘要翻译：本发明涉及氟化丙烯酸酯组合物，其适合用作用于“猪拖尾”的聚合物集成波导至光纤束的低收缩率，低吸收率折射率匹配粘合剂。

5. 发明授权

US07101938B2 Method for forming fluorinated ionomers 失效
公开(公告)号：US07101938B2
公开(公告)日：2006-09-05
申请号：US10478617
申请日：2002-07-09
申请人： Paul Gregory Bekiarian , William Brown Farnham
发明人： Paul Gregory Bekiarian , William Brown Farnham
IPC分类号： C08F14/18 , C08F16/24 , C08F8/34 , H01M4/60
CPC分类号： C08F214/18
摘要： This invention concerns a method for forming ionomers by treatment with ammonium carbonate of copolymers having a substantially fluorinated, but not perfluorinated, polyethylene backbone having pendant groups of fluoroalkoxy sulfonyl fluoride. Ionomers derived therefrom by ion exchange are useful in electrochemical applications such as batteries, fuel cells, electrolysis cells, ion exchange membranes, sensors, electrochemical capacitors, and modified electrodes.

6. 发明授权

US06777515B2 Functional fluorine-containing polymers and ionomers derived therefrom 失效
标题翻译：功能性含氟聚合物和衍生自其的离聚物
公开(公告)号：US06777515B2
公开(公告)日：2004-08-17
申请号：US10187555
申请日：2002-07-02
申请人： Paul Gregory Bekiarian , William Brown Farnham
发明人： Paul Gregory Bekiarian , William Brown Farnham
IPC分类号： C08F11418
CPC分类号： H01M10/0568 , C08F259/08 , H01M10/052 , C08F214/222
摘要： This invention concerns functional fluorine-containing copolymers compositions and ionomers derived therefrom. The ionomers formed are useful in electrochemical applications such as batteries, fuel cells, in exchange membranes, sensors and the like.
摘要翻译：本发明涉及功能性含氟共聚物组合物和衍生自其的离聚物。所形成的离聚物可用于电化学应用，例如电池，燃料电池，交换膜，传感器等。

7. 发明授权

US06713567B2 Method for forming fluorinated ionomers 失效
标题翻译：形成氟化离聚物的方法
公开(公告)号：US06713567B2
公开(公告)日：2004-03-30
申请号：US10187508
申请日：2002-07-01
申请人： Paul Gregory Bekiarian , William Brown Farnham
发明人： Paul Gregory Bekiarian , William Brown Farnham
IPC分类号： C08F830
CPC分类号： H01M8/1083 , C08F8/44 , C08J5/18 , C08J5/20 , H01M2/1653 , H01M8/1023 , H01M8/1039 , H01M8/1088 , Y02P70/56 , C08F214/18
摘要： This invention concerns a method for forming ionomers by treatment with ammonium carbonate of copolymers having a substantially fluorinated, but not perfluorinated, polyethylene backbone having pendant groups of fluoroalkoxy sulfonyl fluoride. Ionomers derived therefrom by ion exchange are useful in electrochemical applications such as batteries, fuel cells, electrolysis cells, ion exchange membranes, sensors, electrochemical capacitors, and modified electrodes.
摘要翻译：本发明涉及通过用含有具有氟烷氧基磺酰氟侧基的基本氟化但不是全氟化的聚乙烯主链的共聚物处理碳酸铵形成离聚物的方法。通过离子交换衍生的离聚物可用于电化学应用，例如电池，燃料电池，电解槽，离子交换膜，传感器，电化学电容器和改性电极。

8. 发明授权

US6040405A Base resistant fluorinated polymers 有权
标题翻译：耐碱氟化聚合物
公开(公告)号：US6040405A
公开(公告)日：2000-03-21
申请号：US178038
申请日：1998-10-23
申请人： Paul Gregory Bekiarian
发明人： Paul Gregory Bekiarian
IPC分类号： C08F214/26 , C08L27/10
CPC分类号： C08F214/262
摘要： Disclosed herein are copolymers of tetrafluoroethylene and n-alkyl trifluorovinyl ether which further contain either curesite repeat units and/or iodine. Such curesite repeat units, upon exposure to free radicals, may crosslink the copolymers. The iodine is introduced by carrying out free radical polymerization in the presence of an organic iodide chain transfer agent. The polymers according to the invention are especially useful as elastomers and/or as molding resins for articles or parts that may be exposed to a basic environment. The preparation of such polymers by aqueous emulsion polymerization is also disclosed.
摘要翻译：本文公开了进一步含有橄榄石重复单元和/或碘的四氟乙烯和正烷基三氟乙烯基醚的共聚物。暴露于自由基之后，这种橄榄石重复单元可以使共聚物交联。通过在有机碘化物链转移剂的存在下进行自由基聚合来引入碘。根据本发明的聚合物特别可用作用于可能暴露于基本环境的制品或部件的弹性体和/或模塑树脂。还公开了通过水乳液聚合制备这种聚合物。

9. 发明授权

US08987369B2 Acrylic acid polymer nanocomposites from aminosilane-modified colloidal silica 有权
标题翻译：丙烯酸聚合物纳米复合材料由氨基硅烷改性胶体二氧化硅
公开(公告)号：US08987369B2
公开(公告)日：2015-03-24
申请号：US14004705
申请日：2011-06-30
申请人： Paul Gregory Bekiarian , Gregory Scott Blackman , Gordon Mark Cohen
发明人： Paul Gregory Bekiarian , Gregory Scott Blackman , Gordon Mark Cohen
IPC分类号： C08L33/02 , B32B5/16 , C08K9/06 , C09C1/30
CPC分类号： C08K9/06 , C01P2004/64 , C09C1/3081 , Y10S977/778 , Y10S977/779 , Y10S977/783 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , C08L33/06
摘要： This invention relates to compositions comprising blends of acrylic add polymers and/or ethylene acrylic add copolymers and colloidal silica modified with certain aromatic aminosilanes, aromatic aminoalkylsilanes, alkenyl aminoalkylsilanes, secondary or tertiary aliphatic aminosilanes. These compositions can provide improved properties such loss modulus, storage modulus, creep resistance, and wear resistance, without sacrificing optical clarity.
摘要翻译：本发明涉及包含丙烯酸加成聚合物和/或乙烯丙烯酸加成共聚物和用某些芳族氨基硅烷，芳族氨基烷基硅烷，链烯基氨基烷基硅烷，仲或叔脂族氨基硅烷改性的胶体二氧化硅的共混物的组合物。这些组合物可以在不牺牲光学透明度的情况下提供改进的性能，例如损耗模量，储能模量，抗蠕变性和耐磨性。

10. 发明申请

US20140162916A1 SLURRY TECHNIQUE FOR PRODUCING FLUOROPOLYMER COMPOSITES 审中-公开
标题翻译：用于生产氟聚合物复合材料的浆料技术
公开(公告)号：US20140162916A1
公开(公告)日：2014-06-12
申请号：US14116887
申请日：2012-05-14
申请人： Christopher P. Junk , Paul Gregory Bekiarian , Mark David Wetzel
发明人： Christopher P. Junk , Paul Gregory Bekiarian , Mark David Wetzel
IPC分类号： C10M147/04 , C10M147/02 , C10M125/10
CPC分类号： C10M147/04 , C08J3/12 , C08J3/2053 , C08J2327/18 , C08K5/05 , C08K2003/2227 , C10M125/10 , C10M147/02
摘要： A fluoropolymer composite comprising at least one fluoropolymer and particulate filler material is formed using a slurry process, in which the particulate filler material is first dispersed in a polar organic liquid, which is then combined with a suitable particulate fluoropolymer. The combination is dried to form a composite powder material. The composite powder material, with optional addition of another fluoropolymer, is processed to form a fluoropolymer composite body. The process can be carried out with either melt-processible or non-melt-processible fluoropolymers.
摘要翻译：包含至少一种含氟聚合物和颗粒填料的含氟聚合物复合材料是使用浆料法形成的，其中颗粒状填料首先分散在极性有机液体中，然后将其与合适的颗粒状含氟聚合物混合。将组合物干燥以形成复合粉末材料。加工另外含氟聚合物的复合粉末材料被加工以形成含氟聚合物复合体。该方法可以用可熔融加工的或不可熔融加工的含氟聚合物进行。

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