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    • 1. 发明授权
    • Curing of epoxy resin compositions comprising cyclic carbonates using mixtures of amino hardeners and catalysts
    • 使用氨基硬化剂和催化剂的混合物固化包含环状碳酸酯的环氧树脂组合物
    • US08877837B2
    • 2014-11-04
    • US13611604
    • 2012-09-12
    • Miran YuRainer Klopsch
    • Miran YuRainer Klopsch
    • C08L63/00C08G59/50C09D163/00C09J163/00C08K5/1565C08K5/109C08K5/17
    • C09D163/00C08K5/109C08K5/1565C08K5/17C09J163/00C08L63/00
    • A process for curing epoxy resins which comprises curing epoxy resin compositions comprising a) epoxy resins and b) a compound of the general formula I in which R1 and R2 independently of one another are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R1 and R2 together are a C3-C11-alkylene group; R3 and R4 independently of one another are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R3 and R4 together are a C4-C6-alkylene group; by adding amino hardeners, and the curing takes place in the presence of a compound of the following formula II in which at least one of the radicals R11, R12 and R13 is a hydrocarbon group having 1 to 10 C atoms, which is substituted with a hydroxyl group and optionally remaining radicals R11 to R13 are an unsubstituted hydrocarbon group having 1 to 10 C atoms.
    • 一种用于固化环氧树脂的方法,其包括固化环氧树脂组合物,其包含a)环氧树脂和b)通式I的化合物,其中R 1和R 2彼此独立地是氢,C 1 -C 6 - 烷基,C 1 -C 4 - 烷氧基 C 1 -C 4 - 烷基,C 5 -C 6 - 环烷基,苯基,C 1 -C 4 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基,或者R 1和R 2一起是C 3 -C 11亚烷基; R 3和R 4彼此独立地是氢,C 1 -C 6 - 烷基,C 1 -C 4 - 烷氧基-C 1 -C 4 - 烷基,C 5 -C 6 - 环烷基,苯基,苯基-C 1 -C 4烷基,C 2 -C 6 - 烯基或 C2-C6-炔基或R3和R4一起是C4-C6-亚烷基; 通过加入氨基硬化剂,并且在下式II化合物存在下进行固化,其中R 11,R 12和R 13中的至少一个是具有1至10个C原子的烃基,其被 羟基和任选的残基R11至R13是具有1至10个C原子的未取代的烃基。
    • 2. 发明授权
    • Curing of epoxy resin compositions comprising cyclic carbonates using mixtures of amino hardeners
    • 使用氨基硬化剂的混合物固化包含环状碳酸酯的环氧树脂组合物
    • US08586653B2
    • 2013-11-19
    • US13614092
    • 2012-09-13
    • Rainer KlopschMiran Yu
    • Rainer KlopschMiran Yu
    • C08L63/00
    • C08L63/00C08G59/4007C08G59/56
    • A process for curing an epoxy resin composition containing an epoxy resin and a compound of the general formula I: where R1 and R2 independently are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R1 and R2 together are a C3-C11-alkylene group; and where R3 and R4 independently are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R3 and R4 together are a C4-C6-alkylene group. The process includes adding amino hardeners, where 0.1% to 50% by weight of the amino hardeners are aliphatic, cycloaliphatic or aromatic amine compounds having 1 to 4 primary amino groups and optionally further functional groups, selected from secondary amino groups, tertiary amino groups, and hydroxyl groups. In the case of the cycloaliphatic and aromatic amine compounds, the primary amino groups are attached as aminomethylene groups (H2N—CH2—) to the cycloaliphatic or aromatic ring system (referred to below for short as co-hardeners).
    • 一种固化含有环氧树脂和通式I化合物的环氧树脂组合物的方法,其中R1和R2独立地为氢,C1-C6-烷基,C1-C4-烷氧基-C1-C4-烷基,C5-C6 环烷基,苯基,苯基-C 1 -C 4 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基,或者R 1和R 2一起是C 3 -C 11 - 亚烷基; 并且其中R 3和R 4独立地是氢,C 1 -C 6 - 烷基,C 1 -C 4 - 烷氧基-C 1 -C 4 - 烷基,C 5 -C 6 - 环烷基,苯基,苯基-C 1 -C 4烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基或R 3和R 4一起是C 4 -C 6亚烷基。 该方法包括加入氨基硬化剂,其中0.1%至50%重量的氨基硬化剂是具有1至4个伯氨基的脂族,脂环族或芳族胺化合物和任选的其它官能团,其选自仲氨基,叔氨基, 和羟基。 在脂环族和芳族胺化合物的情况下,伯氨基作为氨基亚甲基(H 2 N-CH 2 - )连接到脂环族或芳族环系统(简称为辅助硬化剂)。
    • 5. 发明申请
    • CURING OF EPOXY RESIN COMPOSITIONS COMPRISING CYCLIC CARBONATES USING MIXTURES OF AMINO HARDENERS
    • 使用氨基硬化剂的混合物固化环氧碳酸酯的环氧树脂组合物的固化
    • US20130079436A1
    • 2013-03-28
    • US13614092
    • 2012-09-13
    • Rainer KLOPSCHMiran YU
    • Rainer KLOPSCHMiran YU
    • C08L63/00
    • C08L63/00C08G59/4007C08G59/56
    • A process for curing an epoxy resin composition containing an epoxy resin and a compound of the general formula I: where R1 and R2 independently are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R1 and R2 together are a C3-C11-alkylene group; and where R3 and R4 independently are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R3 and R4 together are a C4-C6-alkylene group. The process includes adding amino hardeners, where 0.1% to 50% by weight of the amino hardeners are aliphatic, cycloaliphatic or aromatic amine compounds having 1 to 4 primary amino groups and optionally further functional groups, selected from secondary amino groups, tertiary amino groups, and hydroxyl groups. In the case of the cycloaliphatic and aromatic amine compounds, the primary amino groups are attached as aminomethylene groups (H2N—CH2—) to the cycloaliphatic or aromatic ring system (referred to below for short as co-hardeners).
    • 一种固化含有环氧树脂和通式I化合物的环氧树脂组合物的方法,其中R1和R2独立地是氢,C1-C6-烷基,C1-C4-烷氧基-C1-C4-烷基,C5-C6 环烷基,苯基,苯基-C 1 -C 4 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基,或者R 1和R 2一起是C 3 -C 11 - 亚烷基; 并且其中R 3和R 4独立地是氢,C 1 -C 6 - 烷基,C 1 -C 4 - 烷氧基-C 1 -C 4 - 烷基,C 5 -C 6 - 环烷基,苯基,苯基-C 1 -C 4烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基或R 3和R 4一起是C 4 -C 6亚烷基。 该方法包括加入氨基硬化剂,其中0.1%至50%重量的氨基硬化剂是具有1至4个伯氨基的脂族,脂环族或芳族胺化合物和任选的其它官能团,其选自仲氨基,叔氨基, 和羟基。 在脂环族和芳族胺化合物的情况下,伯氨基作为氨基亚甲基(H 2 N-CH 2 - )连接到脂环族或芳族环系统(简称为辅助硬化剂)。
    • 7. 发明授权
    • Use of cyclic carbonates in epoxy resin compositions
    • 在环氧树脂组合物中使用环状碳酸酯
    • US08741988B2
    • 2014-06-03
    • US13158841
    • 2011-06-13
    • Rainer KlopschAndreas LanverAchim KaffeeKlaus EbelMiran Yu
    • Rainer KlopschAndreas LanverAchim KaffeeKlaus EbelMiran Yu
    • C08L63/00C08G59/00
    • C08L63/00C08G59/00C08K5/04
    • The present invention relates to the use of cyclic carbonates of the formula I or a mixture thereof in epoxy resin compositions and also to epoxy resin compositions which comprise such cyclic carbonates. in which R1 and R2 independently of each other are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R1 and R2 together are a C3-C11-alkylene group; R3 and R4 independently of each other are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R3 and R4 together are a C4-C6-alkylene group; or mixtures thereof, as additives in epoxy resin compositions.
    • 本发明涉及式I的环状碳酸酯或其混合物在环氧树脂组合物中的用途,还涉及包含这种环状碳酸酯的环氧树脂组合物。 其中R1和R2彼此独立地是氢,C1-C6-烷基,C1-C4-烷氧基-C1-C4-烷基,C5-C6-环烷基,苯基,苯基-C1-C4-烷基,C2-C6- 烯基或C 2 -C 6炔基,或者R 1和R 2一起是C 3 -C 11 - 亚烷基; R 3和R 4彼此独立地是氢,C 1 -C 6 - 烷基,C 1 -C 4 - 烷氧基-C 1 -C 4 - 烷基,C 5 -C 6 - 环烷基,苯基,苯基-C 1 -C 4 - 烷基,C 2 -C 6 - 烯基或 C2-C6-炔基或R3和R4一起是C4-C6-亚烷基; 或其混合物,作为环氧树脂组合物中的添加剂。
    • 8. 发明申请
    • CURING OF EPOXY RESIN COMPOSITIONS COMPRISING CYCLIC CARBONATES USING MIXTURES OF AMINO HARDENERS AND CATALYSTS
    • 使用氨基硬化剂和催化剂的混合物固化环氧碳酸酯的环氧树脂组合物
    • US20130072595A1
    • 2013-03-21
    • US13611604
    • 2012-09-12
    • Miran YuRainer Klopsch
    • Miran YuRainer Klopsch
    • C08L63/02C09J163/02C09D163/02
    • C09D163/00C08K5/109C08K5/1565C08K5/17C09J163/00C08L63/00
    • A process for curing epoxy resins which comprises curing epoxy resin compositions comprising a) epoxy resins and b) a compound of the general formula I in which R1 and R2 independently of one another are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R1 and R2 together are a C3-C11-alkylene group; R3 and R4 independently of one another are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R3 and R4 together are a C4-C6-alkylene group; by adding amino hardeners, and the curing takes place in the presence of a compound of the following formula II in which at least one of the radicals R11, R12 and R13 is a hydrocarbon group having 1 to 10 C atoms, which is substituted with a hydroxyl group and optionally remaining radicals R11 to R13 are an unsubstituted hydrocarbon group having 1 to 10 C atoms.
    • 一种用于固化环氧树脂的方法,其包括固化环氧树脂组合物,其包含a)环氧树脂和b)通式I的化合物,其中R 1和R 2彼此独立地是氢,C 1 -C 6 - 烷基,C 1 -C 4 - 烷氧基 C 1 -C 4 - 烷基,C 5 -C 6 - 环烷基,苯基,C 1 -C 4 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基,或者R 1和R 2一起是C 3 -C 11亚烷基; R 3和R 4彼此独立地是氢,C 1 -C 6 - 烷基,C 1 -C 4 - 烷氧基-C 1 -C 4 - 烷基,C 5 -C 6 - 环烷基,苯基,苯基-C 1 -C 4烷基,C 2 -C 6 - 烯基或 C2-C6-炔基或R3和R4一起是C4-C6-亚烷基; 通过加入氨基硬化剂,并且在下式II化合物存在下进行固化,其中R 11,R 12和R 13中的至少一个是具有1至10个C原子的烃基,其被 羟基和任选的残基R11至R13是具有1至10个C原子的未取代的烃基。