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1. 发明授权

US09601708B2 Organic light emitting device and materials for use in same 有权
公开(公告)号：US09601708B2
公开(公告)日：2017-03-21
申请号：US13995319
申请日：2011-02-11
申请人： Hitoshi Yamamoto , Michael S. Weaver , Julia J. Brown , Kazuki Nishimura , Toshihiro Iwakuma , Tetsuya Inoue , Mitsunori Ito
发明人： Hitoshi Yamamoto , Michael S. Weaver , Julia J. Brown , Kazuki Nishimura , Toshihiro Iwakuma , Tetsuya Inoue , Mitsunori Ito
IPC分类号： H01L51/50 , H01L51/00
CPC分类号： H01L51/5028 , H01L51/0059 , H01L51/0072 , H01L51/0085 , H01L51/5016
摘要： The OLEDs of the present invention are characterized by providing an organic thin film layer comprising a single layer or plural layers between a cathode and an anode, wherein the organic thin film layer comprises at least one organic light emitting layer, wherein at least one light emitting layer comprises at least one host material and at least one phosphorescent emitter material, wherein the host material comprises a bis-carbazole derivative host material; and the phosphorescent emitter material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by one of the following partial chemical structures represented by the formula: LL′L″M wherein M is a metal that forms octahedral complexes, L, L′, L″ are equivalent or inequivalent bidentate ligands wherein each L comprises a substituted or unsubstituted phenylpyridine ligand coordinated to M through an sp2 hybridized carbon and N; and one of L, L′ and L″ is inequivalent to at least one of the other two.

2. 发明授权

US09266851B2 Fluorene-containing aromatic compound, material for organic electroluminescent element, and organic electroluminescent element using same 有权
标题翻译：含芴芳香族化合物，有机电致发光元件用材料和使用其的有机电致发光元件
公开(公告)号：US09266851B2
公开(公告)日：2016-02-23
申请号：US13386240
申请日：2010-10-14
申请人： Kei Yoshida , Kazuki Nishimura , Mitsunori Ito , Yuichiro Kawamura , Toshinari Ogiwara , Toshihiro Iwakuma
发明人： Kei Yoshida , Kazuki Nishimura , Mitsunori Ito , Yuichiro Kawamura , Toshinari Ogiwara , Toshihiro Iwakuma
IPC分类号： H01L51/50 , C07D307/91 , C07D209/86 , C07D401/10 , C07D401/14 , C07D403/10 , C07D403/14 , C07D405/14 , C07D409/12 , C07D409/14 , C07D471/04 , H01L51/00 , C09B57/00 , C09B57/10 , C09B69/00
CPC分类号： C07D307/91 , C07D209/86 , C07D401/10 , C07D401/14 , C07D403/10 , C07D403/14 , C07D405/14 , C07D409/12 , C07D409/14 , C07D471/04 , C09B57/00 , C09B57/008 , C09B57/10 , C09B69/008 , H01L51/0071 , H01L51/5016 , H01L51/5072
摘要： A fluorene-containing aromatic compound represented by a formula (1) below. In the formula (1): Nr1 represents a substituted or unsubstituted monocyclic nitrogen-containing aromatic ring having 2 to 5 ring carbon atoms, or a bicyclic nitrogen-containing aromatic ring having 2 to 9 ring carbon atoms; Ar represents an aromatic ring and the like; Fl1 and Fl2 represent a fluorenyl group; and Cz1 and Cz2 represent a carbazolyl group. A compound represented by a formula (2) below is omitted from the fluorene-containing aromatic compound represented by the formula (1).
摘要翻译：含下述式（1）表示的含芴芳香族化合物。式（1）中，Nr1表示取代或未取代的环碳原子数2〜5的单环含氮芳香环，或环碳原子数2〜9的双环含氮芳香环; Ar表示芳香环等; Fl1和Fl2代表芴基; Cz1和Cz2表示咔唑基。由式（1）表示的含芴芳香族化合物，省略了下述式（2）表示的化合物。

3. 发明申请

US20150243905A1 BISCARBAZOLE DERIVATIVE HOST MATERIALS AND GREEN EMITTER FOR OLED EMISSIVE REGION 有权
标题翻译：用于OLED电动区域的BISCARBAZOLE衍生主体材料和绿色发光体
公开(公告)号：US20150243905A1
公开(公告)日：2015-08-27
申请号：US14400801
申请日：2012-06-14
申请人： Hitoshi Yamamoto , Michael S. Weaver , Julia J. Brown , Kazuki Nishimura , Toshihiro Iwakuma
发明人： Hitoshi Yamamoto , Michael S. Weaver , Julia J. Brown , Kazuki Nishimura , Toshihiro Iwakuma
IPC分类号： H01L51/00 , C09K11/06
CPC分类号： H01L51/0072 , C07D403/14 , C07D405/14 , C09B57/00 , C09B57/008 , C09B57/10 , C09K11/06 , C09K2211/1014 , C09K2211/1029 , C09K2211/1044 , C09K2211/1048 , C09K2211/1059 , C09K2211/1074 , C09K2211/1088 , C09K2211/185 , H01L51/0052 , H01L51/0067 , H01L51/0073 , H01L51/0085 , H01L51/0094 , H01L51/5016 , H01L51/5056 , H01L51/5072 , H01L51/5088 , H01L51/5206 , H01L51/5221 , H01L2251/301 , H01L2251/308 , H01L2251/5384
摘要： An organic electroluminescence device utilizes a novel combination comprising one or more biscarbazole derivative compounds as the phosphorescent host material in combination with a green phosphorescent dopant material in the light emitting region of the device, where the biscarbazole derivative compounds are represented by a formula (1A) or (1B) below; where A1 represents a substituted or unsubstituted nitrogen-containing heterocyclic group having 1 to 30 ring carbon atoms; A2 represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or substituted or unsubstituted nitrogen-containing heterocyclic group having 1 to 30 ring carbon atoms; X1 and X2 each are a linking group; Y1 to Y4 each represent a substituent; p and q represent an integer of 1 to 4; and r and s represent an integer of 1 to 3; and the green phosphorescent dopant material is a phosphorescent organometallic complex having a chemical structure represented by LL′L″M wherein M is a metal that forms octahedral complexes, L, L′, and L″ are equivalent or inequivalent bidentate ligands wherein each L comprises a substituted or unsubstituted phenylpyridine ligand coordinated to M through an sp2 hybridized carbon and N; and, one of L, L′ and L″ is different from at least one of the other two.
摘要翻译：一种有机电致发光器件利用包含一种或多种双咔唑衍生物化合物作为磷光主体材料的新型组合，与装置的发光区域中的绿色磷光掺杂剂材料组合，其中双咔唑衍生物化合物由式（1A）表示，或（1B）其中A1表示取代或未取代的含有1至30个环碳原子的含氮杂环基; A2表示取代或未取代的碳原子数为6〜30的芳香族烃基或取代或未取代的碳原子数为1〜30的含氮杂环基， X1和X2各自是连接基团; Y1至Y4各自表示取代基; p和q表示1〜4的整数。并且r和s表示1〜3的整数。并且绿色磷光掺杂剂材料是具有由LL'L“M表示的化学结构的磷光有机金属络合物，其中M是形成八面体复合物的金属，L，L'和L”是相当于或不等价的双齿配体，其中每个L包括通过sp2杂化的碳和N配位于M的取代或未取代的苯基吡啶配体; 并且L，L'和L“中的一个与另外两个中的至少一个不同。

4. 发明申请

US20140299865A1 ORGANIC ELECTROLUMINESCENCE ELEMENT AND MATERIAL FOR ORGANIC ELECTROLUMINESCENCE ELEMENT 审中-公开
标题翻译：有机电致发光元件的有机电致发光元件和材料
公开(公告)号：US20140299865A1
公开(公告)日：2014-10-09
申请号：US14353128
申请日：2012-10-18
申请人： Kazuki Nishimura , Mitsuru Eida , Mitsunori Ito
发明人： Kazuki Nishimura , Mitsuru Eida , Mitsunori Ito
IPC分类号： H01L51/00 , H01L51/50
CPC分类号： H01L51/0058 , C07D401/10 , C07D401/14 , C07D403/10 , C07D403/14 , C07D471/04 , H01L51/0059 , H01L51/006 , H01L51/0067 , H01L51/0071 , H01L51/0072 , H01L51/0073 , H01L51/0074 , H01L51/0085 , H01L51/0094 , H01L51/5016 , H01L51/5028 , H01L2251/308 , H01L2251/5384
摘要： An organic electroluminescence device includes an anode, a cathode and at least an emitting layer interposed between the anode and the cathode. The emitting layer contains a first host material, a second host material and a phosphorescent dopant material. The first host material is a compound represented by the following formula (1). The second host material is a compound represented by the following formula (3).
摘要翻译：有机电致发光器件包括阳极，阴极和至少一个置于阳极和阴极之间的发光层。发光层包含第一主体材料，第二主体材料和磷光掺杂剂材料。第一主体材料是由下式（1）表示的化合物。第二主体材料是由下式（3）表示的化合物。

5. 发明申请

US20140191225A1 BISCARBAZOLE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE ELEMENT USING SAME 审中-公开
标题翻译： BISCARBAZOLE DERIVATIVE和有机电致发光元件
公开(公告)号：US20140191225A1
公开(公告)日：2014-07-10
申请号：US14237887
申请日：2012-08-15
申请人： Tetsuya Inoue , Mitsunori Ito , Kazuki Nishimura , Kumiko Hibino
发明人： Tetsuya Inoue , Mitsunori Ito , Kazuki Nishimura , Kumiko Hibino
IPC分类号： H01L51/00
CPC分类号： H01L51/0067 , C07D403/14 , H01L51/0059 , H01L51/0061 , H01L51/0072 , H01L51/0085 , H01L2251/308
摘要： A biscarbazole derivative is represented by the following formula (1). A1 and A2 of the following formula (1) represent an aromatic hydrocarbon group having 6 to 30 ring carbon atoms or an aromatic heterocyclic group having 1 to 30 ring carbon atoms. However, at least one of A1 and A2 represents an aromatic heterocyclic group having 1 to 30 ring carbon atoms. Y1 to Y15 represent CR or a nitrogen atom. One of Y8 to Y11 is C (carbon atom) obtained by removing R from CR. The obtained C is bonded to L3. R each independently represents a hydrogen atom, an aromatic hydrocarbon group or the like. L1 to L3 represent a single bond or a divalent linking group. When L3 is a single bond and is bonded to Y11, L1 and L2 are divalent linking groups.
摘要翻译：双咔唑衍生物由下式（1）表示。下式（1）的A1和A2表示碳原子数为6〜30的芳香族烃基或环碳原子数为1〜30的芳香族杂环基。然而，A1和A2中的至少一个表示具有1至30个环碳原子的芳族杂环基。 Y1〜Y15表示CR或氮原子。 Y8〜Y11中的一个是通过从CR中除去R而得到的C（碳原子）。所得到的C键合到L3。 R各自独立地表示氢原子，芳香族烃基等。 L1至L3表示单键或二价连接基团。当L3是单键并且键合到Y11时，L1和L2是二价连接基团。

6. 发明申请

US20140151647A1 MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE AND ORGANIC ELECTROLUMINESCENCE DEVICE 审中-公开
标题翻译：有机电致发光器件和有机电致发光器件材料
公开(公告)号：US20140151647A1
公开(公告)日：2014-06-05
申请号：US13705686
申请日：2012-12-05
申请人： Yumiko MIZUKI , Mitsunori Ito , Tetsuya Inoue , Kumiko Hibino , Kazuki Nishimura
发明人： Yumiko MIZUKI , Mitsunori Ito , Tetsuya Inoue , Kumiko Hibino , Kazuki Nishimura
IPC分类号： H01L51/50
CPC分类号： H01L51/5028 , C07D209/86 , H01L51/0072 , H01L51/5012 , H01L51/5016 , H01L2251/5384 , H05B33/20
摘要： An organic electroluminescence device employing a specific biscarbazole derivative having a cyano group as a first host and a compound having both a carbazole structure and a nitrogen-containing aromatic heteroring as a second host. The organic electroluminescence device has a prolonged lifetime.
摘要翻译：使用具有氰基作为第一主体的特定二咔唑衍生物和具有咔唑结构和含氮芳香族杂环的化合物作为第二主体的有机电致发光器件。有机电致发光器件的寿命延长。

7. 发明申请

US20130306962A1 ORGANIC LIGHT EMITTING DEVICE AND MATERIALS FOR USE IN SAME 审中-公开
公开(公告)号：US20130306962A1
公开(公告)日：2013-11-21
申请号：US13995276
申请日：2011-02-11
申请人： Hitoshi Yamamoto , Michael S. Weaver , Julia J. Brown , Kazuki Nishimura , Toshihiro Iwakuma , Kei Yoshida
发明人： Hitoshi Yamamoto , Michael S. Weaver , Julia J. Brown , Kazuki Nishimura , Toshihiro Iwakuma , Kei Yoshida
IPC分类号： H01L51/50
CPC分类号： H01L51/5028 , H01L51/0067 , H01L51/0072 , H01L51/0085 , H01L51/5012
摘要： The OLEDs of the present invention are characterized by providing an organic thin film layer comprising a single layer or plural layers between a cathode and an anode, wherein the organic thin film layer comprises at least one organic light emitting layer, wherein at least one light emitting layer comprises at least one host material and at least one phosphorescent emitter material, wherein the host material comprises a substituted or unsubstituted hydrocarbon compound represented by the formula (1) or (2): (Cz-)nA (1) Cz(-A)m (2) wherein Cz represents a substituted or unsubstituted arylcarbazolyl group or carbazolylalkylene group, A represents a group represented by the following general formula (3): (M)p-(L)q-(M′)r (3) wherein M and M′ each independently represent a heteroaromatic ring having 2 to 40 carbon atoms and nitrogen atom and forming a substituted or unsubstituted ring, M and M′ may represent a same ring or different rings, L represents a single bond, a substituted or unsubstituted aryl group or arylene group having 6 to 30 carbon atoms, a substituted or unsubstituted cycloalkylene group having 5 to 30 carbon atoms or a substituted or unsubstituted heteroaromatic ring having 2 to 30 carbon atoms, p represents an integer of 0 to 2, q represents an integer of 1 or 2, r represents an integer of 0 to 2, and p+r represents an integer of 1 or greater; and n and m each represent an integer of 1 to 3; and the phosphorescent emitter material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by one of the following partial chemical structures represented by the formula: LL′L″M wherein M is a metal that forms octahedral complexes, L, L′, L″ are equivalent or inequivalent bidentate ligands wherein each L comprises a substituted or unsubstituted phenylpyridine ligand coordinated to M through an sp2 hybridized carbon and N; and one of L, L′ and L″ is inequivalent to at least one of the other two.

8. 发明申请

US20130240859A1 TANDEM ORGANIC ELECTROLUMINESCENCE DEVICE 审中-公开
标题翻译：有机电致发光器件
公开(公告)号：US20130240859A1
公开(公告)日：2013-09-19
申请号：US13880534
申请日：2011-10-20
申请人： Takashi Arakane , Kazuki Nishimura , Kenichi Fukuoka , Hitoshi Kuma , Yukitoshi Jinde
发明人： Takashi Arakane , Kazuki Nishimura , Kenichi Fukuoka , Hitoshi Kuma , Yukitoshi Jinde
IPC分类号： H01L51/50
CPC分类号： H01L51/504 , C09B1/00 , C09B3/02 , C09B3/14 , C09B3/78 , C09B6/00 , C09B57/00 , C09B57/001 , C09B57/008 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , H01L27/3209 , H01L51/5044 , H01L2251/5376 , H05B33/10
摘要： A tandem organic electroluminescence device including a first emitting unit (3), an intermediate unit (4) and a second emitting unit (5) being stacked between opposing electrodes (2) and (6) the first emitting unit (3) including a blue fluorescent dopant and a red fluorescent dopant and the second emitting unit (5) including a red phosphorescent dopant and a green phosphorescent dopant.
摘要翻译：一种串联有机电致发光器件，包括在相对电极（2）和（6）之间堆叠的第一发射单元（3），中间单元（4）和第二发射单元（5），所述第一发射单元（3）包括蓝色荧光掺杂剂和红色荧光掺杂剂，第二发光单元（5）包括红色磷光掺杂剂和绿色磷光掺杂剂。

9. 发明申请

US20120273766A1 AROMATIC HETEROCYCLIC DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME 审中-公开
标题翻译：芳香杂环衍生物和有机电致发光器件
公开(公告)号：US20120273766A1
公开(公告)日：2012-11-01
申请号：US13501423
申请日：2011-10-07
申请人： Tomoki Kato , Kazuki Nishimura
发明人： Tomoki Kato , Kazuki Nishimura
IPC分类号： C07D401/10 , H01L51/54
CPC分类号： C07D219/02 , C07D401/04 , C07D401/14 , C07D403/14 , C07D405/04 , C07D405/14 , C07D407/04 , C07D407/14 , C07D409/04 , C07D409/14 , C07D471/04 , C07F7/0816 , H01L51/0059 , H01L51/0072 , H01L51/0073 , H01L51/0085
摘要： An aromatic heterocyclic derivative represented by the following formula (1), a material for an organic electroluminescence device and an organic electroluminescence device including these:
摘要翻译：由下式（1）表示的芳香族杂环衍生物，有机电致发光元件用有机电致发光元件及其制造方法，

10. 发明授权

US08294142B2 Organic EL device 有权
标题翻译：有机EL器件
公开(公告)号：US08294142B2
公开(公告)日：2012-10-23
申请号：US12667939
申请日：2008-07-04
申请人： Kazuki Nishimura , Toshihiro Iwakuma , Masahiro Kawamura , Kenichi Fukuoka , Chishio Hosokawa , Masakazu Funahashi
发明人： Kazuki Nishimura , Toshihiro Iwakuma , Masahiro Kawamura , Kenichi Fukuoka , Chishio Hosokawa , Masakazu Funahashi
IPC分类号： H01L29/08 , H01J1/62
CPC分类号： H01L51/5016 , B82Y10/00 , C09B1/00 , C09B23/148 , C09B57/00 , C09B57/008 , C09K11/06 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1051 , C09K2211/1059 , C09K2211/107 , C09K2211/1092 , C09K2211/185 , H01L51/0045 , H01L51/005 , H01L51/0052 , H01L51/0059 , H01L51/0071 , H01L51/5004 , H01L51/5036 , H01L2251/552 , H05B33/14
摘要： An organic EL device includes: an anode; a cathode and an organic thin-film layer provided between the anode and the cathode. The organic thin-film layer includes: a fluorescent-emitting layer containing a fluorescent host and a fluorescent dopant; and a phosphorescent-emitting layer containing a first phosphorescent host and a first phosphorescent dopant. The first phosphorescent dopant emits light by receiving exited triplet energy transferred from the fluorescent host. The fluorescent host has a substituted or unsubstituted polycyclic fused aromatic skeleton and has an exited triplet energy gap of 2.10 eV to 3.00 eV.
摘要翻译：有机EL器件包括：阳极; 设置在阳极和阴极之间的阴极和有机薄膜层。有机薄膜层包括：荧光发射层，含有荧光主体和荧光掺杂剂; 以及包含第一磷光发光体和第一磷光掺杂剂的磷光发光层。第一个磷光掺杂剂通过接收从荧光主体转移的离子三重态能量而发光。荧光主体具有取代或未取代的多环稠合芳族骨架，并且具有2.10eV至3.00eV的退出三线态能隙。

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