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    • 3. 发明申请
    • METHOD FOR EVALUATING SECONDARY BATTERY
    • 评估二次电池的方法
    • US20110074430A1
    • 2011-03-31
    • US12893534
    • 2010-09-29
    • Sho TsurutaKatsunori Yanagida
    • Sho TsurutaKatsunori Yanagida
    • G01N27/416
    • H01M10/42H01M10/052H01M10/486
    • A method for evaluating a secondary battery includes repeatedly performing: an open circuit voltage measurement step of measuring the open circuit voltage of the secondary battery to be evaluated at each of a plurality of temperatures; a potential change measurement step of measuring, after the open circuit voltage measurement step, the potential change in the secondary battery while changing the state of charge of the secondary battery; and an equilibrium potential measurement step of measuring the equilibrium potential of the secondary battery after the potential change measurement step. An entropy variation in each of the different states of charge is calculated based on the open circuit voltages at the plurality of temperatures measured in the state of charge, and a chemical diffusion coefficient in each of the different states of charge is calculated based on the equilibrium potential of the secondary battery and the potential change in the secondary battery both measured in the state of charge. The secondary battery is evaluated based on the entropy variations and the chemical diffusion coefficients in the different states of charge.
    • 一种用于评估二次电池的方法包括重复执行:开路电压测量步骤,用于在多个温度中的每一个温度下测量待评估的二次电池的开路电压; 电位变化测量步骤,在所述开路电压测量步骤之后,在改变所述二次电池的充电状态的同时,测量所述二次电池的电位变化; 以及在电位变化测量步骤之后测量二次电池的平衡电位的平衡电位测量步骤。 基于在充电状态下测量的多个温度下的开路电压来计算各种不同的充电状态中的熵变,并且基于平衡来计算每种不同充电状态的化学扩散系数 二次电池的电位和二次电池的电位变化都是在充电状态下测量的。 基于不同充电状态下的熵变和化学扩散系数来评估二次电池。