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1. 发明授权

US07994330B2 Method for producing organic compound and method for decomposing compound having dicarboximide skeleton 失效
标题翻译：生产有机化合物的方法和分解具有二甲酰亚胺骨架的化合物的方法
公开(公告)号：US07994330B2
公开(公告)日：2011-08-09
申请号：US11885125
申请日：2006-03-22
申请人： Naruhisa Hirai , Jun Kuwana
发明人： Naruhisa Hirai , Jun Kuwana
IPC分类号： C07D211/22 , C07D233/40
CPC分类号： C07D251/32 , Y02P20/55
摘要： It is desirable to provide a method for easily removing catalyst-derived impurities from a product of a reaction by the catalysis of a compound having a dicarboximide skeleton and thereby efficiently yielding a target compound with high purity.Disclosed is a method for producing an organic compound through a reaction of a substrate in the presence of a catalyst, the catalyst including a compound having a dicarboximide skeleton represented by following Formula (i): wherein R represents hydrogen atom or a hydroxyl-protecting group. The method includes the step of treating a reaction product with hot water so as to decompose and remove an impurity derived from the catalyst. The temperature of the hot water is preferably 100° C. or higher.
摘要翻译：期望提供一种通过催化具有二羧酰亚胺骨架的化合物从反应产物中容易地除去催化剂衍生的杂质的方法，从而有效地产生高纯度的目标化合物。公开了一种在催化剂存在下通过底物的反应制备有机化合物的方法，所述催化剂包括具有由下式（i）表示的二羧酰亚胺骨架的化合物：其中R表示氢原子或羟基保护基。该方法包括用热水处理反应产物以分解和除去由催化剂衍生的杂质的步骤。热水的温度优选为100℃以上。

2. 发明申请

US20080269507A1 Methods for Oxidizing Organic Compounds 有权
标题翻译：氧化有机化合物的方法
公开(公告)号：US20080269507A1
公开(公告)日：2008-10-30
申请号：US11884203
申请日：2006-02-22
申请人： Yasuteru Kajikawa , Naruhisa Hirai , Jun Kuwana
发明人： Yasuteru Kajikawa , Naruhisa Hirai , Jun Kuwana
IPC分类号： C07D493/04 , C07C45/33 , C07C35/02 , C07C51/21 , C07C35/08 , C07C35/06 , C07C51/265 , C07D307/89
CPC分类号： C07C51/265 , B01J31/0247 , B01J31/04 , B01J31/28 , B01J31/40 , B01J2231/70 , C07C29/50 , C07C35/06 , C07C35/08 , C07C45/33 , C07C51/00 , C07C51/313 , C07C2601/08 , C07C2601/14 , C07C2601/20 , Y02P20/584 , C07C49/403 , C07C49/413 , C07C49/395 , C07C63/313 , C07C55/14 , C07C35/205
摘要： A method oxidizes an organic compound with oxygen in the presence of a catalyst, in which the catalyst contains a N-hydroxy- or N-(substituted oxy)-imide compound derivable from at least one selected from a target product, a reaction intermediate, and a reaction byproduct, and the catalyst is produced from at least one component selected from the target product, reaction intermediate, and reaction byproduct each formed as a result of the reaction and is used in the oxidation reaction so as to make up for a loss of the catalyst due to denaturation in the reaction. The method can easily and inexpensively make up for a loss of the catalyst denaturated in the course of reaction.
摘要翻译：一种方法是在催化剂存在下用氧气氧化有机化合物，其中催化剂含有可从选自目标产物，反应中间体中的至少一种的N-羟基或N-（取代的氧）酰亚胺化合物，和反应副产物，催化剂由选自反应产生的目标产物，反应中间体和反应副产物中的至少一种成分产生，并用于氧化反应中以弥补损失的催化剂，由于反应变性。该方法可以容易且廉价地补偿在反应过程中变性的催化剂的损失。

3. 发明申请

US20080171881A1 Method for Producing Organic Compound and Method for Decomposing Compound Having Dicarboximide Skeleton 失效
标题翻译：生产有机化合物的方法和分解具有二酰亚胺骨架的化合物的方法
公开(公告)号：US20080171881A1
公开(公告)日：2008-07-17
申请号：US11885125
申请日：2006-03-22
申请人： Naruhisa Hirai , Jun Kuwana
发明人： Naruhisa Hirai , Jun Kuwana
IPC分类号： C07D211/22 , C07C233/00 , C07D233/40 , C07D249/12
CPC分类号： C07D251/32 , Y02P20/55
摘要： It is desirable to provide a method for easily removing catalyst-derived impurities from a product of a reaction by the catalysis of a compound having a dicarboximide skeleton and thereby efficiently yielding a target compound with high purity.Disclosed is a method for producing an organic compound through a reaction of a substrate in the presence of a catalyst, the catalyst including a compound having a dicarboximide skeleton represented by following Formula (i): wherein R represents hydrogen atom or a hydroxyl-protecting group. The method includes the step of treating a reaction product with hot water so as to decompose and remove an impurity derived from the catalyst. The temperature of the hot water is preferably 100° C. or higher.
摘要翻译：期望提供一种通过催化具有二羧酰亚胺骨架的化合物从反应产物中容易地除去催化剂衍生的杂质的方法，从而有效地产生高纯度的目标化合物。公开了一种在催化剂存在下通过底物的反应制备有机化合物的方法，所述催化剂包括具有由下式（i）表示的二羧酰亚胺骨架的化合物：其中R表示氢原子或羟基保护基。该方法包括用热水处理反应产物以分解和除去由催化剂衍生的杂质的步骤。热水的温度优选为100℃以上。

4. 发明授权

US07910749B2 Methods for oxidizing organic compounds 有权
标题翻译：氧化有机化合物的方法
公开(公告)号：US07910749B2
公开(公告)日：2011-03-22
申请号：US11884203
申请日：2006-02-22
申请人： Yasuteru Kajikawa , Naruhisa Hirai , Jun Kuwana
发明人： Yasuteru Kajikawa , Naruhisa Hirai , Jun Kuwana
IPC分类号： C07D493/00 , C07D307/77 , C07C61/00 , C07C51/255 , C07C45/00 , C07C27/00 , C07C35/08 , C07C35/06
CPC分类号： C07C51/265 , B01J31/0247 , B01J31/04 , B01J31/28 , B01J31/40 , B01J2231/70 , C07C29/50 , C07C35/06 , C07C35/08 , C07C45/33 , C07C51/00 , C07C51/313 , C07C2601/08 , C07C2601/14 , C07C2601/20 , Y02P20/584 , C07C49/403 , C07C49/413 , C07C49/395 , C07C63/313 , C07C55/14 , C07C35/205
摘要： A method oxidizes an organic compound with oxygen in the presence of a catalyst, in which the catalyst contains a N-hydroxy- or N-(substituted oxy)-imide compound derivable from at least one selected from a target product, a reaction intermediate, and a reaction byproduct, and the catalyst is produced from at least one component selected from the target product, reaction intermediate, and reaction byproduct each formed as a result of the reaction and is used in the oxidation reaction so as to make up for a loss of the catalyst due to denaturation in the reaction. The method can easily and inexpensively make up for a loss of the catalyst denaturated in the course of reaction.
摘要翻译：一种方法是在催化剂存在下用氧气氧化有机化合物，其中催化剂含有可从选自目标产物，反应中间体中的至少一种的N-羟基或N-（取代的氧）酰亚胺化合物，和反应副产物，催化剂由选自反应产生的目标产物，反应中间体和反应副产物中的至少一种成分产生，并用于氧化反应中以弥补损失的催化剂，由于反应变性。该方法可以容易且廉价地补偿在反应过程中变性的催化剂的损失。

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