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1. 发明授权

US5045357A Process for preparing a membranous gas separator 失效
标题翻译：膜状气体分离器的制备方法
公开(公告)号：US5045357A
公开(公告)日：1991-09-03
申请号：US509298
申请日：1990-04-16
申请人： Akira Motonaga , Kensuke Kamada , Jun Kamo , Hiroshi Hosokawa
发明人： Akira Motonaga , Kensuke Kamada , Jun Kamo , Hiroshi Hosokawa
IPC分类号： B01D69/12 , B01D69/14 , B01D71/72 , C04B41/48 , C04B41/83 , C08G61/12
CPC分类号： C04B41/009 , B01D69/125 , B01D69/141 , B01D71/72 , C04B41/488 , C04B41/83 , C08G61/123 , C04B2111/00801 , Y10T428/249954 , Y10T428/249978
摘要： Disclosed is a process for preparing a membranous gas separator comprising (a) a porous substrate having an average pore diameter of not greater than 100 .ANG. and (b) a .pi.-electron conjugated conducting polymer retained within at least a part of the pores of the porous substrate in such a way that the pores are not blocked, characterized in that retaining the .pi.-electron conjugated conducting polymer within the pore is carried out by a chemical oxidative polymerization.
摘要翻译：公开了一种制备膜状气体分离器的方法，其包括（a）平均孔径不大于100的多孔基材和（b）保留在所述孔的至少一部分中的π-电子共轭导电聚合物多孔基材，使得孔不被阻塞，其特征在于，通过化学氧化聚合进行保持孔内的π-电子共轭导电性聚合物。

2. 发明授权

US4713292A Multilayer composite hollow fibers and method of making same 失效
标题翻译：多层复合中空纤维及其制造方法
公开(公告)号：US4713292A
公开(公告)日：1987-12-15
申请号：US878678
申请日：1986-06-26
申请人： Tohru Takemura , Hajime Itoh , Jun Kamo , Haruhiko Yoshida
发明人： Tohru Takemura , Hajime Itoh , Jun Kamo , Haruhiko Yoshida
IPC分类号： B01D53/22 , B01D67/00 , B01D69/08 , B01D69/12 , C01B13/02 , D01D5/24 , D01D5/247 , D01F6/00 , D01F6/04 , D01F8/02 , D01F8/04 , D01F8/06 , D01F8/10 , D01F8/14 , D01F8/16 , D02G3/00
CPC分类号： D01D5/24 , B01D67/0027 , B01D69/08 , B01D69/12 , B01D2323/08 , Y10T428/2929 , Y10T428/2935 , Y10T428/2973 , Y10T428/2975
摘要： Disclosed are a multilayer composite hollow fiber comprising at least one nonporous separating membrane layer (A) performing a separating function and two or more porous layers (B) performing a reinforcing function, the layer (A) and the layers (B) being alternately laminated so as to give a structure having internal and external surfaces formed by the porous layers (B), as well as a method of making such a hollow fiber.In this multilayer composite hollow fiber, the separating membrane can be formed as an ultrathin, homogeneous membrane. Moreover, the separating membrane is not liable to get damaged owing to the unique structure of the hollow fiber. Furthermore, such hollow fibers can be readily and stably produced on an industrial scale.
摘要翻译：公开了一种多层复合中空纤维，其包含至少一个执行分离功能的无孔分离膜层（A）和执行增强功能的两个或多个多孔层（B），所述层（A）和层（B）交替层压从而得到具有由多孔层（B）形成的内表面和外表面的结构以及制造这种中空纤维的方法。在这种多层复合中空纤维中，分离膜可以形成为超薄均匀的膜。此外，由于中空纤维的独特结构，分离膜不容易损坏。此外，这种中空纤维可以以工业规模容易且稳定地制造。

3. 发明授权

US4639353A Blood oxygenator using a hollow-fiber membrane 失效
标题翻译：使用中空纤维膜的血液充氧器
公开(公告)号：US4639353A
公开(公告)日：1987-01-27
申请号：US726391
申请日：1985-04-23
申请人： Tohru Takemura , Atushi Nakashima , Haruhiko Yoshida , Jun Kamo , Eiichi Hamada
发明人： Tohru Takemura , Atushi Nakashima , Haruhiko Yoshida , Jun Kamo , Eiichi Hamada
IPC分类号： A61M1/16 , B01D63/02 , B01D63/04 , A61M1/14 , B01D13/01
CPC分类号： A61M1/1698 , A61M1/1625 , A61M1/1629 , B01D63/02 , B01D63/04 , B01D2313/08 , B01D2313/38 , B01D2319/06 , Y10S128/03
摘要： A blood oxygenator of the outside perfusion type using hollow fibers as the gas exchange membrane. In this blood oxygenator, a plurality of contact chambers each containing a bundle or bundles of hollow fibers for gas exchange use and communicating with a blood inlet and a blood outlet are disposed to make blood flow in multiple paths within a housing, and each bundle of hollow fibers is arranged so as to be substantially perpendicular to the direction of blood flow. In spite of its compact construction, this blood oxygenator has high oxygen and carbon dioxide exchange rates per unit of membrane even when used in the gas exchange of blood having high flow rate, exhibits only a small pressure loss, and causes little channeling of the blood and gas. Moreover, it is easy to manufacture because of its relatively simple structure.
摘要翻译：使用中空纤维作为气体交换膜的外部灌注型的血液充氧器。在该血液充氧器中，设置多个接触室，每个接触室包含一束或用于气体交换的中空纤维束，其使用并与血液入口和血液出口连通，以使血液在壳体内的多条路径中流动，中空纤维被布置成基本上垂直于血液流动的方向。尽管其紧凑的构造，该血液氧合器即使在用于具有高流速的血液的气体交换中也具有高的每单位膜的氧气和二氧化碳交换率，仅显示出小的压力损失，并且导致血液的很少的通道和气体。此外，由于其结构相对简单，容易制造。

4. 发明授权

US4388256A Process for manufacturing regenerated cellulose hollow fiber 失效
标题翻译：制造再生纤维素中空纤维的方法
公开(公告)号：US4388256A
公开(公告)日：1983-06-14
申请号：US70651
申请日：1979-08-28
申请人： Masamichi Ishida , Jun Kamo , Toru Takemura , Shunsuke Minami , Kensuke Kamada
发明人： Masamichi Ishida , Jun Kamo , Toru Takemura , Shunsuke Minami , Kensuke Kamada
IPC分类号： D01D5/24 , B29D27/00
CPC分类号： B01D71/10 , B01D69/08 , D01D5/24 , Y10T428/2975
摘要： A regenerated cellulose hollow fiber exhibiting a good cellulose II crystalline structure and an exchanged wet strength/wet elongation ratio is prepared by a process wherein: a dope comprised of cellulose ester in a non-volatile organic solvent is extruded through a circular slit defined between inner and outer tubes of a spinning nozzle having a double tube structure, while a core liquid is forced through the inner tube of said nozzle; the hollow fibrous extrudate is coagulated in a coagulating bath; the coagulated hollow fibrous extrudate is drawn 1.05 to 2.00 times its original length; and then, the drawn hollow fiber still containing a core liquid in the hollow is treated with an aqueous caustic alkali solution containing at least 0.5% by weight of a water soluble metal salt, thereby hydrolyzing the cellulose ester into cellulose.
摘要翻译：通过以下方法制备表现出良好的纤维素II结晶结构和交换的湿强度/湿伸长率的再生纤维素中空纤维，其中：由非挥发性有机溶剂中的纤维素酯组成的涂料通过限定在内部以及具有双管结构的纺丝喷嘴的外管，同时使芯液被迫通过所述喷嘴的内管; 中空纤维挤出物在凝固浴中凝结; 凝固的中空纤维挤出物的原始长度为1.05〜2.00倍; 然后，用含有至少0.5重量％的水溶性金属盐的苛性碱水溶液处理在中空体中仍含有核心液体的拉伸中空纤维，从而将纤维素酯水解成纤维素。

5. 发明授权

US5403483A Hydrophobic porous membranes and process for the manufacture thereof 失效
标题翻译：疏水多孔膜及其制造方法
公开(公告)号：US5403483A
公开(公告)日：1995-04-04
申请号：US94981
申请日：1993-07-22
申请人： Kazuaki Hayashida , Takao Miyamori , Jun Kamo
发明人： Kazuaki Hayashida , Takao Miyamori , Jun Kamo
IPC分类号： B01D39/08 , B01D67/00 , B01D29/00
CPC分类号： B01D67/0088 , B01D39/083 , B01D2239/04 , B01D2239/0428 , B01D2239/0464 , B01D2239/0471 , B01D2239/0618
摘要： Disclosed is a hydrophobic porous membrane with a polymer having fluorinated alkyl side chains held in physical contact with the surface of a polyolefin porous membrane in which the fluorinated alkyl side chains of the polymer are crystallized, as well as its manufacturing process. Also disclosed is a hydrophobic porous membrane with a fluorinated crosslinked polymer from a fluorinated monomer with a fluorinated alkyl side chain and a crosslinking monomer held in physical contact with the surface of a polyolefin porous membrane, in which the fluorinated alkyl side chains of the fluorinated crosslinked polymer are crystallized, as well as its manufacturing process. These porous membranes use polyolefin porous membranes having a higher mechanical strength and lower costs than the fluorinated polymer porous membranes and still provide superior hydrophobicity over polytetrafluoroethylene type membranes.
摘要翻译：公开了具有氟化烷基侧链与聚烯烃多孔膜的表面物理接触的聚合物的疏水性多孔膜，其中聚合物的氟化烷基侧链结晶，以及其制造方法。还公开了一种疏水多孔膜，其具有氟化单体与氟化烷基侧链的氟化交联聚合物，并且交联单体与聚烯烃多孔膜的表面保持物理接触，其中氟化交联的聚合物结晶，以及其制造过程。这些多孔膜使用的聚烯烃多孔膜具有比氟化聚合物多孔膜更高的机械强度和更低的成本，并且仍然优于聚四氟乙烯型膜的疏水性。

6. 发明授权

US5294338A Porous polyethylene hollow fiber membrane of large pore diameter, production process thereof, and hydrophilized porous polyethylene hollow fiber membranes 失效
标题翻译：孔径大的多孔聚乙烯中空纤维膜，其生产工艺和亲水化的多孔聚乙烯中空纤维膜
公开(公告)号：US5294338A
公开(公告)日：1994-03-15
申请号：US853777
申请日：1992-06-09
申请人： Jun Kamo , Takayuki Hirai , Hiroshi Takahashi , Kenji Kondo
发明人： Jun Kamo , Takayuki Hirai , Hiroshi Takahashi , Kenji Kondo
IPC分类号： B01D67/00 , B01D69/02 , B01D69/08 , B01D71/26 , B29C55/00 , D01D5/247
CPC分类号： B01D67/0088 , B01D67/0027 , B01D69/02 , B01D69/08 , B01D71/26 , B29C55/005 , D01D5/247 , B01D2323/02 , B01D2323/08 , B01D2325/021 , B01D2325/14 , B01D2325/20 , B29K2023/06
摘要： Disclosed is a porous polyethylene hollow fiber membrane of large pore diameter which have (a) rectangular pores formed by microfibrils that are oriented in the lengthwise direction of the fibers and joint portions that are composed of stacked lamellae, the pores being contiguous with each other from the inner wall surface to the outer wall surface of the hollow fiber membrane to form a stacked, multicellular structure, (b) an average pore diameter ranging from greater than 2 .mu.m up to 10 .mu.m as measured with a mercury porosimeter, (c) a porosity of 75 to 95%, and (d) an air permeability of not less than 8.times.10.sup.5 l/m.sup.2 .multidot.hr.multidot.0.5 atm. This hollow fiber membrane can be produced by melt-spinning polyethylene, annealing the resulting unstretched hollow fiber under specific conditions, and then cold-stretching and hot-stretching the annealed hollow fiber under specific conditions.
摘要翻译： PCT No.PCT / JP91 / 01638 Sec。 371日期：1992年6月9日 102（e）日期1992年6月9日PCT 1991年11月28日PCT公布。公开号WO92 / 09359 日期：1992年6月11日。公开的是大孔径的多孔聚乙烯中空纤维膜，其具有（a）由纤维长度方向取向的微原纤维形成的矩形孔，和由层叠薄片组成的接合部分孔从中空纤维膜的内壁表面到外壁表面彼此连续以形成堆叠的多细胞结构，（b）平均孔径范围从大于2（我）m到10（我的）m，（c）孔隙率为75〜95％，（d）透气度不小于8×10 5 l / m 2 * hr * 0.5atm。该中空纤维膜可以通过熔融纺丝聚乙烯制造，在特定条件下对所得未拉伸中空纤维进行退火，然后在特定条件下冷拉伸和热拉伸退火的中空纤维。

7. 发明授权

US06284137B1 Polysulfone porous membrane and a method of manufacturing the same 有权
标题翻译：聚砜多孔膜及其制造方法
公开(公告)号：US06284137B1
公开(公告)日：2001-09-04
申请号：US09249165
申请日：1999-02-12
申请人： Akira Hajikano , Kei Murase , Jun Kamo
发明人： Akira Hajikano , Kei Murase , Jun Kamo
IPC分类号： B01D7168
CPC分类号： B01D71/68 , B01D67/0011 , B01D69/02 , B01D69/08 , B01D2323/06 , B01D2323/08 , B01D2323/10 , B01D2323/12
摘要： The present invention relates to a polysufone porous membrane having a high water flux, an excellent resistance to moist heat and an excellent repercolation characteristic, and which comprises a mixed polymer having polyarylsulfone and polyethersulfone at a ratio of from 9/1-1/9 (by weight), the membrane being a graded porous membrane forming a cross-linked polymer network wherein a number of micropores being interconnected from one surface to the other surface, and the membrane comprising two layers wherein one layer being a dense layer having a number of pores with pore sizes in the range of 0.01-1 &mgr;m and thereby having a separation function, and the other layer being a graded type supporting layer supporting said dense layer and having a pore size distribution wherein the pores existing therein and having sizes of 1-100 &mgr;m increase continuously from the dense layer side toward the other surface side, wherein the separation particle size is not larger than 0.5 &mgr;m, and a method of manufacturing the same.
摘要翻译：本发明涉及一种具有高水通量，优异的耐湿热性和优异的再聚合特性的多分散多孔膜，其包含具有聚芳基砜和聚醚砜的混合聚合物，其比例为9 / 1-1 / 9（所述膜是形成交联聚合物网络的分级多孔膜，其中多个微孔从一个表面互连到另一个表面，并且所述膜包括两层，其中一层是致密层，其中多个孔径在0.01-1μm范围内并因此具有分离功能的孔，另一层是支撑所述致密层并具有孔尺寸分布的梯度型支撑层，其中存在于其中并具有1- 100μm从致密层侧向另一个表面侧连续增加，其中分离粒度不大于0.5μm，以及方法制造相同。

8. 发明授权

US5963701A Plastic optical fibers and optical fiber cables 失效
标题翻译：塑料光纤和光缆
公开(公告)号：US5963701A
公开(公告)日：1999-10-05
申请号：US945886
申请日：1997-11-14
申请人： Kazuki Nakamura , Jun Okumura , Kikue Irie , Makoto Muro , Jun Kamo , Katsuhiko Shimada
发明人： Kazuki Nakamura , Jun Okumura , Kikue Irie , Makoto Muro , Jun Kamo , Katsuhiko Shimada
IPC分类号： G02B6/00 , B29C47/00 , G02B1/04 , G02B6/44
CPC分类号： G02B6/02033 , G02B1/045 , G02B1/046 , G02B1/048 , B29C47/00 , B29C47/0014 , G02B6/4402 , Y10T428/2933 , Y10T428/2967
摘要： This invention relates to a plastic optical fiber having a three-layer structure comprising a core, a cladding and a protective layer wherein the core material is polymethyl methacrylate and the cladding material is a copolymer composed of 20 to 45% by weight of long-chain fluoroalkyl methacrylate units represented by the following formula (1), 54 to 79% by weight of methyl methacrylate units, and 0.05 to 2% by weight of methacrylic acid units. This invention also relates to a plastic optical fiber cable having a four-layer structure wherein the optical fiber cable is produced by covering the aforesaid optical fiber with a jacket layer.CH.sub.2 .dbd.C(CH.sub.3)--COO--(CH.sub.2).sub.2 (CF.sub.2).sub.7 CF.sub.3(1)
摘要翻译： PCT No.PCT / JP96 / 01270 Sec。 371日期：1997年11月14日 102（e）1997年11月14日日期PCT提交1996年5月15日PCT公布。 WO96 / 36894 PCT出版物日期：1996年11月21日本发明涉及一种具有三层结构的塑料光纤，其包括芯，包层和保护层，其中芯材为聚甲基丙烯酸甲酯，包覆材料为由20〜45％由下式（1）表示的长链氟烷基甲基丙烯酸酯单元，54〜79重量％的甲基丙烯酸甲酯单元和0.05〜2重量％的甲基丙烯酸单元的重量。本发明还涉及一种具有四层结构的塑料光纤电缆，其中通过用夹层覆盖上述光纤来制造光缆.CH 2 = C（CH 3）-COO-（CH 2）2（CF 2） 7CF3（1）

9. 发明授权

US5746916A Microporous membrane made of non-crystalline polymers and method of producing the same 失效
标题翻译：由非结晶聚合物制成的微孔膜及其制造方法
公开(公告)号：US5746916A
公开(公告)日：1998-05-05
申请号：US377706
申请日：1995-01-25
申请人： Jun Kamo , Seiya Koyanagi , Miho Kawai
发明人： Jun Kamo , Seiya Koyanagi , Miho Kawai
IPC分类号： B01D67/00 , B01D69/02 , B01D71/64 , B01D71/68 , B01D33/21 , B29C65/00
CPC分类号： B01D67/0088 , B01D67/0027 , B01D67/003 , B01D69/02 , B01D69/08 , B01D71/64 , B01D71/68 , B01D2323/12 , B01D2323/30 , B01D2325/36
摘要： A microporous membrane made of a non-crystalline polymer having, within its wall, microfibrils and slit-like micropores which are oriented in the lengthwise direction of the membrane, said slit-like micropores communicating from one surface to the other surface of the membrane, and forming a stacked construction. This membrane has a high flux value of AFR and WFR, excellent heat-, solvent-, and pressure-resistance, and a high mechanical strength, and does not contain any undesirable materials which eluate during use. This membrane is thus useful as a multi-purpose separation membrane, such as for medical uses, food industries, purification of water or air, and the separation of hot liquids.
摘要翻译：由非晶体聚合物构成的微多孔膜在其壁内具有在膜的长度方向上定向的微原纤维和狭缝状微孔，所述狭缝状微孔从膜的一个表面连通到另一个表面，并形成堆叠结构。该膜具有高的AFR和WFR通量值，具有优异的耐热性，耐溶剂性和耐压性，并且具有高机械强度，并且在使用过程中不含任何不希望的洗脱液。因此，该膜可用作多用途分离膜，例如用于医疗用途，食品工业，水或空气净化以及热液体的分离。

10. 发明授权

US5395525A Apparatus for exchanging substances 失效
标题翻译：交换物质的设备
公开(公告)号：US5395525A
公开(公告)日：1995-03-07
申请号：US81300
申请日：1993-10-29
申请人： Hisateru Takano , Haruhiko Akagi , Yoshiyuki Taenaka , Takanobu Aoyagi , Jun Kamo
发明人： Hisateru Takano , Haruhiko Akagi , Yoshiyuki Taenaka , Takanobu Aoyagi , Jun Kamo
IPC分类号： A61M1/18 , B01D61/28 , B01D63/02 , B01D65/08 , B01D63/00
CPC分类号： B01D63/02 , B01D61/28 , B01D65/08 , B01D2313/243 , B01D2321/00 , B01D2321/02
摘要： An apparatus for exchanging substances, such as artificial lung, in which, for raising exchange efficiency by feeding liquid to the outer wall of hollow fiber membranes efficiently without channeling and for reducing the size of the apparatus, an exchanging part comprising a multitude of hollow fiber membrane (3) disposed cylindrically or annularly to permit liquid to flow through the hollow parts is provided, and a pump (P) is disposed on the inner periphery of said exchanging part so that liquid may continuously be fed to the hollow membrane vertically with respect to the axial direction of said hollow fiber membrane (3).
摘要翻译： PCT No.PCT / JP92 / 01374 Sec。 371日期：1993年10月29日 102（e）日期1993年10月29日PCT提交1992年10月21日PCT公布。第WO98 / 07957号公报日本1994年4月29日。一种用于交换诸如人造肺的物质的装置，其中为了通过将液体高效地输送到中空纤维膜的外壁而提高交换效率而不需要通道并减小装置的尺寸，设置有多个中空纤维膜（3），其设置为圆柱形或环形以允许液体流过中空部分，并且泵（P）设置在所述交换部件的内周上，使得可以连续地供给液体相对于中空纤维膜（3）的轴向垂直地延伸到中空膜。

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